AUTOMATED PHASE SEPARATION AND FUEL QUALITY SENSOR

• US 20100295565A1
• Filed: 01/08/2009
• Published: 11/25/2010
• Est. Priority Date: 01/09/2008
• Status: Abandoned Application

• Current Assignee: Diraction, LLC
• Original Assignee: Diraction, LLC
• Inventors: Drack, Earle David
• Application Number:
  US12/812,130
• Publication Number:
  US 20100295565A1
• Time in Patent Office: Days
• US Class Current: 324/693
• CPC Class Codes: G01F 22/00 Methods or apparatus for measuring volume of fluids or fluent solid material, not otherwise provided for
• CPC Class Codes: G01F 23/243 Schematic arrangements of probes combined with measuring circuits
• CPC Class Codes: G01F 23/263 by measuring variations in capacitance of capacitors
• CPC Class Codes: G01F 23/266 measuring circuits therefor
• CPC Class Codes: G01M 3/00 Investigating fluid-tightness of structures
• CPC Class Codes: G01M 3/3245 using a level monitoring device G01M3/3272 takes precedence
• CPC Class Codes: G01N 33/18 Water
• CPC Class Codes: G01N 33/22 Fuels, explosives liquid hydrocarbons G01N33/28

Abstract

A fluid characterization sensor comprising a plurality of sensor segments is disclosed. Each segment comprises two electrodes, spaced apart so the fluid in the corresponding interval of depth for that segment is positioned between them. Complex current or impedance is measured by exciting one electrode with an AC signal, and measuring the amplitude and phase of the current in the other electrode. After automatically measuring and accounting for pre-determined gain, offset, temperature, and other parasitic influences on the raw sensor signal, the complex electrical impedance of the fluid between the electrodes is calculated from the measured phase/amplitude and/or real/imaginary components of the received electrical current signal and/or the variation of the measured response with variation in excitation frequency. Comparison of measured results with results taken using known fluids identifies fluid properties. Alternatively, measured results are compared to predicted results using forward models describing expected results for different fluids or contaminants.

Claims

1. A system for characterization of fluid in a container, comprising:

at least one fluid sensor segment comprising a first and second electrode;

excitation circuitry connected to at least one of said electrodes; and

complex current or complex impedance measurement circuitry connected to at least one of said electrodes,

wherein said system characterizes the fluid by measuring complex current flowing between electrodes or the complex impedance of the fluid situated between the electrodes.

2. The system of claim 1 wherein said characterization is made by comparing said complex current or complex impedance to complex currents or complex impedances measured by the system using known fluids under known conditions.

3. The system of claim 1 wherein said characterization is made by determining electrical properties of the fluid, taking into account said complex current or complex impedance measurements, electrode geometry, and spacing, and then comparing said electrical properties to electrical properties for known fluids.

4. The system of claim 1, comprising a plurality of fluid sensor segments and wherein said first electrode for each fluid sensor segment is a common electrode for all fluid sensor segments.

5. The system of claim 4, wherein said second electrodes are arranged substantially vertically and are flat single single-sided, flat double-sided, or faces on a three dimensional surface.

6. The system of claim 5, wherein said common electrode comprises two elements, one on either side of said second double-sided electrodes.

7. The system of claim 4, wherein said common electrode substantially surrounds said second electrodes, and wherein said common electrode is adapted to allow said first and second electrodes to be immersed in and surrounded by the fluid.

8. The system of claim 1, wherein said excitation circuitry produces a signal selected from the group consisting of one or more of:

a fixed frequency signal;

a varying frequency signal;

a fixed waveform shape signal;

a varying waveform shape signal;

a fixed amplitude signal and a varying amplitude signal.

9. The system of claim 1, further comprising a controller and memory, said memory storing complex current or complex impedance data for known fluids and said controller comparing said measured complex current or complex impedance to said stored complex current or complex impedance data.

10. The system of claim 9, wherein said controller stores in said memory a plurality of said complex current or complex impedance measurements taken over time.

11. The system of claim 10, wherein said controller actuates an alert based on said measurements taken over time.

12. The system of claim 1, wherein said electrodes are coated.

13. The system of claim 1, further comprising a temperature sensor, and wherein said comparison of said measured complex current or complex impedance with said known complex currents or complex impedances includes a compensation for temperature if said measured complex impedance was made at a different temperature than the temperature at which said known complex impedances were measured.

14. The system of claim 1, wherein said complex current or complex impedance measurement circuitry further comprises an automatic gain control.

15. The system of claim 14, wherein said automatic gain control is adapted to adjust said excitation circuitry and said complex current or complex impedance measurement circuitry.

16. The system of claim 1, wherein said excitation circuitry and complex current or complex impedance circuitry are manufactured on a single printed circuit board and wherein said electrodes comprise circuit traces on said printed circuit board.

17. The system of claim 1, wherein said system is housed in a magnetostrictive fluid level probe.

18. The system of claim 5, wherein there is more than one fluid in the container and complex current or complex impedance measurements from said plurality of segments is used to determine at least one of the group consisting of:

an interface location between two fluids;

fluid types and fluid characteristics.

19. The system of claim 1 comprising a plurality of electrode segments, said segments arranged vertically so that segments are positioned at different depths in the container.

20. The system of claim 5 wherein at least some of said segments are spaced apart from other segments at unequal intervals, and/or are sized differently than other segments.

21. The system of claim 1, wherein said segments comprise redundant segments.

22. The system of claim 12, wherein said coating is comprised of one of the groups consisting of:

a hydrophobic coating;

a low surface energy coating.

23. The system of claim 1, wherein said system further determines whether the fluid has impurities, based on said complex current or complex impedance measurement.

24. The system of claim 4 wherein some or all of the second electrodes of the sensor segments are electrically connected to each other using single, or combinations of, lumped or distributed electrical elements selected from the group consisting of resistors, capacitors, inductors, diodes and combinations of any of these elements.

25. The system of claim 24 wherein said complex current or complex impedance measurement circuitry is adapted to make a single complex current or complex impedance measurement of said electrically connected sensor segments to gather information about the corresponding fluid properties for all of said electrically connected segments.

26. The system of claim 24 wherein said complex current or complex impedance measurement circuitry is adapted to make a plurality measurements at different points to refine the accuracy and precision of the fluid properties corresponding to each segment.

27. The system of claim 24 wherein constraints are used when inverting the data to calculate the complex currents corresponding to each segment, such that known relationships of fluid locations (e.g. water cannot float on top of gasoline) to reduce the number of solutions and thus converge on the correct solution faster, using less memory, and to converge more accurately and reliably in the presence of electrical noise.

48. The system of claim 1 wherein said electrode, connected to said measurement circuitry, is completely or partially surrounded by a conductor.

49. The system of claim 1 further comprising:

a calibration impedance; and

a switch; and

wherein said switch connects said calibration impedance between said excitation circuitry and said complex current or complex impedance measurement circuitry and wherein said switch either disconnects said electrodes from either said excitation circuitry or from said complex current or complex impedance measurement circuitry, or disconnects said electrodes both from said excitation circuitry and from said complex current or complex impedance measurement circuitry, or disconnects said electrodes from neither said excitation circuitry nor from said complex current or complex impedance measurement circuitry.

51. The system of claim 19 wherein said plurality of electrode segments, connected to said measurement circuitry, is completely or partially surrounded by a conductor.

28. A method for detecting water or aqueous ethanol in a container holding a liquid product, comprising the steps of:

measuring the complex current or complex impedance of sensor segment electrodes, between which is disposed the fluid in the container, at a plurality of depths to acquire complex current or complex impedance measurements; and

characterizing the fluid at each of said plurality of depths based on said complex current or complex impedance measurements.

29. The method of claim 28, wherein said characterization is made by comparing said complex current or complex impedance measurements with known complex current or complex impedance values for water, aqueous ethanol, vapor, and the liquid product and

determining whether there is water or aqueous ethanol in the container based on said comparison.

30. The method of claim 28, wherein said characterization is made by calculating fluid properties from measured complex current or complex impedance and known sensor segment electrode geometry and

determining whether there is water or aqueous ethanol in the container based on said calculation.

31. The method of claim 29, further comprising determining the level of the water or aqueous ethanol, if present, based on data from the plurality of depths.

32. The method of claim 29, further comprising determining whether a phase separation has occurred based on said calculation or comparison.

34. The method of claim 28 wherein said measuring is made with at least one fluid sensor segment comprising a common electrode and a plurality of second electrodes, said second electrodes being electrically connected to each other using single, or combinations of, lumped or distributed electrical elements selected from the group consisting of resistors, capacitors, inductors, diodes and combinations of any of these elements.

35. The method of claim 34 further comprising:

performing a single complex current or complex impedance measurement of the coupled sensor segments to gather information about the corresponding fluid properties for all segments.

36. The method of claim 34, further comprising:

performing a plurality measurements at different points to further refine the accuracy and precision of the fluid properties corresponding to each segment.

37. The method of claim 34, further comprising:

inverting the data to calculate the complex currents corresponding to each segment;

applying constraints to said calculation.

38. The method in claim 34 wherein the measurement made is voltage or complex voltage.

39. The method in claim 35 wherein the measurement made is voltage or complex voltage.

40. The method in claim 36 wherein the measurement made is voltage or complex voltage.

41. The method of claim 28 wherein said measurement of the complex current or complex impedance is repeated a plurality of times to create trend data.

42. The method of claim 41 further comprising the step of analyzing said trend data to identify water ingress prior to phase separation.

50. The method of claim 28 further comprising:

connecting a calibration impedance between said excitation circuitry and said complex current or complex impedance measurement circuitry;

disconnecting said electrodes from either said excitation circuitry or from said complex current or complex impedance measurement circuitry, or disconnecting said electrodes both from said excitation circuitry and from said complex current or complex impedance measurement circuitry, or disconnecting said electrodes from neither said excitation circuitry nor from said complex current or complex impedance measurement circuitry; and

measuring a response with a system in one or more such configuration or configurations to determine precise values of excitation amplitude, and/or frequency, and/or phase that are used to enhance accuracy and precision of said characterization of the fluid.

33. A method of detecting leaks in a container holding fluids, including intentionally added fluids, said method comprising:

measuring the complex current or complex impedance of the fluids in the container at a plurality of depths to acquire complex current or complex impedance measurements;

comparing said complex current or complex impedance measurements to known complex current or complex impedance values for the intentionally added fluids;

determining whether unintentionally added fluids have entered the container the fuel based on said comparison; and

if unintentionally added fluids have entered the container, indicating the presence of a leak.

43. A method for leak detection of fluid that unintentionally enters a container, said method comprising:

analyzing fluid contents of the container; and

detecting fluids not intentionally added to the container.

44. The method of claim 43, wherein said fluid not intentionally added to the container is water and said analyzing comprises detecting water in said container.

45. The method of claim 43, wherein said detecting of water is made by characterizing the fluids in the container based on electrical or physical properties of the fluids.

46. The method of claim 45, wherein said characterizing is made by measuring the fluids with a device adapted to measure complex impedance or complex current while immersed in the fluids.

47. The method of claim 43, wherein said detecting comprises detecting a phase separation of fluids in the container.