ACTINICALLY-CROSSLINKABLE SILOXANE-CONTAINING COPOLYMERS
First Claim
1. An actinically crosslinkable prepolymer of formula (1) or (2)
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Accused Products
Abstract
The invention provide a class of actinically-crosslinkable silicone-containing prepolymers obtained by functionalizing an intermediary copolymer to have two or more thiol or ethylenically-unsaturated groups covalently attached thereto, wherein the intermediary copolymer is an atom-transfer radical polymerization (ATRP) product of a reactive mixture comprising a polysiloxane ATRP macroinitiator and at least one hydrophilic vinylic monomer. The present invention is also related to silicone hydrogel contact lenses made from a prepolymer of the invention and methods for making the contact lenses in a cost-effective way and with high consistency and high fidelity to the original lens design.
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Citations
14 Claims
- 1. An actinically crosslinkable prepolymer of formula (1) or (2)
- 10. A soft contact lens, comprising a silicone hydrogel material which is polymerization product of a lens-forming materia, wherein the lens-forming material comprises an actinically crosslinkable prepolymer of formula (1) or (2)
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14. A method for producing soft contact lenses, comprising the steps of:
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providing a mold for making a soft contact lens, wherein the mold has a first mold half with a first molding surface defining the anterior surface of a contact lens and a second mold half with a second molding surface defining the posterior surface of the contact lens, wherein said first and second mold halves are configured to receive each other such that a cavity is formed between said first and second molding surfaces; introduce a lens-forming material into the cavity, wherein the lens-forming material comprises an actinically crosslinkable prepolymer of formula (1) or (2)
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Specification