HIGH-TEMPERATURE, STEAM-SELECTIVE MEMBRANE

• US 20100319535A1
• Filed: 06/18/2010
• Published: 12/23/2010
• Est. Priority Date: 06/23/2009
• Status: Abandoned Application

• Current Assignee: Ceramatec, Inc.
• Original Assignee: Ceramatec, Inc.
• Inventors: Zhao, Feng, Joshi, Ashok V.
• Application Number:
  US12/818,673
• Publication Number:
  US 20100319535A1
• Time in Patent Office: Days
• US Class Current: 95/52
• CPC Class Codes: B01D 2313/42 Catalysts within the flow path
• CPC Class Codes: B01D 53/22 by diffusion manufacturing semi-permeable membranes B01D67/00; form, structure or properties of semi-permeable membranes B01D69/00; material for semi-permeable membranes B01D71/00
• CPC Class Codes: B01D 53/228 characterised by specific membranes
• CPC Class Codes: B01D 53/268 by diffusion
• CPC Class Codes: B01D 69/10 Supported membranes; Membrane supports
• CPC Class Codes: B01D 69/12 Composite membranes; Ultra-thin membranes
• CPC Class Codes: B01D 69/1213 Laminated layers
• CPC Class Codes: B01D 69/141 Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
• CPC Class Codes: B01D 71/024 Oxides
• CPC Class Codes: B01D 71/52 Polyethers
• CPC Class Codes: B01D 71/5222 Polyetherketone, polyetheretherketone, or polyaryletherketone
• CPC Class Codes: B01D 71/82 characterised by the presence of specified groups, e.g. introduced by chemical after-treatment

Abstract

A high-temperature, steam-selective membrane for adding steam to or removing steam from various types of chemical reactions is disclosed herein. In one embodiment, such a membrane includes a polymer layer (a Nafion or sulfonated PEEK polymer layer, for example) exhibiting high selectivity to the transport of steam relative to other gas species. The polymer layer is sandwiched between substantially rigid porous layers that are steam permeable. The rigid porous layers substantially immobilize the polymer layer and reduce the tendency of the polymer layer to shrink and/or expand in response to changes in temperature or humidity. The rigid porous layers may also retain water to keep the polymer layer moist. The physical support and moisture retention provided by the rigid porous layers enable the polymer layer to operate in a temperature range of about 100° C. to 500° C.

Claims

1. A high-temperature, steam-selective membrane, the steam-selective membrane comprising:

a polymer layer exhibiting a high selectivity to the transport of steam relative to other gas species, the polymer membrane sandwiched between substantially rigid porous layers that are steam permeable.

2. The steam-selective membrane of claim 1, wherein the polymer layer comprises Nafion.

3. The steam-selective membrane of claim 1, wherein the polymer layer comprises sulfonated polyether ether ketone (PEEK).

4. The steam-selective membrane of claim 1, wherein the substantially rigid porous layers are configured to keep the polymer layer moist.

5. The steam-selective membrane of claim 1, wherein the substantially rigid porous layers comprise one of porous ceramic layers and porous metal layers.

6. The steam-selective membrane of claim 1, wherein the polymer layer is configured to operate in the temperature range of about 100°

C. to about 500°

C.

7. The steam-selective membrane of claim 1, wherein the polymer layer is applied to at least one of the substantially rigid porous layers as one of a liquid and a paste, and then cured to form a substantially solid polymer layer.

8. The steam-selective membrane of claim 1, wherein the polymer layer is applied to at least one of the substantially rigid porous layers as a free-standing film.

9. The steam-selective membrane of claim 1, wherein the steam-selective membrane is cured to achieve bonding between the polymer layer and the substantially rigid porous layers.

10. The steam-selective membrane of claim 1, further comprising a clamping mechanism to clamp the polymer layer between the substantially rigid porous layers.

11. A method for removing steam from a steam-laden gas stream, the method comprising:

providing a steam-selective membrane comprising a steam-selective polymer layer sandwiched between rigid steam-permeable porous layers;

conveying a steam-laden gas stream to a first side of the steam-selective membrane;

transporting steam in the steam-laden gas stream through the steam-selective membrane from the first side to a second side of the steam-permeable membrane, thereby generating a steam-depleted gas stream at the first side; and

conveying the steam-depleted gas stream away from the first side.

12. The method of claim 11, further comprising conveying a sweep gas to the second side of the steam-selective membrane.

13. The method of claim 12, further comprising conveying the steam away from the second side with the sweep gas.

14. The method of claim 11, wherein the steam-selective polymer layer comprises at least one of Nafion and sulfonated polyether ether ketone (PEEK).

15. The method of claim 11, further comprising using the rigid steam-permeable porous layers to maintain moisture in the steam-selective polymer layer.

16. The method of claim 11, wherein the rigid steam-permeable porous layers comprise one of porous ceramic layers and porous metal layers.

17. The steam-permeable membrane of claim 11, wherein the temperature of the steam-laden gas stream ranges from about 100°

C. to about 500°

C.

18. A high-temperature, steam-selective membrane, the steam-selective membrane comprising:

a polymer layer exhibiting a high selectivity to the transport of steam relative to other gas species, the polymer layer being physically adhered to at least one substantially rigid steam-permeable porous layer.

19. The steam-selective membrane of claim 18, wherein the polymer layer comprises at least one of Nafion and sulfonated polyether ether ketone (PEEK).

20. The steam-selective membrane of claim 18, wherein the at least one substantially rigid steam-permeable porous layer is one of a porous ceramic layer and a porous metal layer.

21. The steam-selective membrane of claim 18, wherein the polymer layer operates in a temperature range of about 100°

C. to about 500°

C.

22. The steam-selective membrane of claim 18, wherein the polymer layer is applied to the at least one substantially rigid steam-permeable porous layer as one of a liquid and a paste, and then cured to form a substantially solid polymer layer.

23. The steam-selective membrane of claim 18, wherein the polymer layer is applied to the at least one substantially rigid steam-permeable porous layer as a free-standing film.

24. The steam-selective membrane of claim 18, wherein the steam-selective membrane is cured to achieve bonding between the polymer layer and the at least one substantially rigid steam-permeable porous layer.

25. A high-temperature, steam-selective membrane, the steam-selective membrane comprising:

a polymer layer exhibiting a high selectivity to the transport of steam relative to other gas species, the polymer layer being physically adhered to at least one substantially rigid steam-permeable porous layer comprising one of a porous ceramic layer and a porous metal layer;

wherein the polymer layer comprises at least one of Nafion and sulfonated polyether ether ketone (PEEK);

wherein the polymer layer operates in a temperature range of about 100°

C. to about 500°

C.; and

,

wherein the steam-selective membrane is cured to achieve bonding between the polymer layer and the at least one substantially rigid steam-permeable porous layer.

26. The steam-selective membrane of claim 25, wherein the polymer layer is applied to the at least one substantially rigid steam-permeable porous layer as one of a liquid and a paste, and then cured to form a substantially solid polymer layer.

27. The steam-selective membrane of claim 25, wherein the polymer layer is applied to the at least one substantially rigid steam-permeable porous layer as a free-standing film.