Techniques for Strengthening Glass Covers for Portable Electronic Devices

• US 20110019354A1
• Filed: 09/30/2010
• Published: 01/27/2011
• Est. Priority Date: 03/02/2009
• Status: Abandoned Application

• Current Assignee: Apple Inc.
• Original Assignee: Apple Inc.
• Inventors: Prest, Christopher, Zadesky, Stephen Paul
• Application Number:
  US12/895,393
• Publication Number:
  US 20110019354A1
• Time in Patent Office: Days
• US Class Current: 361/679.21
• CPC Class Codes: C03C 19/00 Surface treatment of glass, not in the form of fibres or filaments, by mechanical means sand-blasting, grinding, or polishing glass B24
• CPC Class Codes: C03C 21/002 to perform ion-exchange between alkali ions C03C21/005 takes precedence

Abstract

Apparatus, systems and methods for improving strength of a thin glass cover for an electronic device are disclosed. In one embodiment, the glass member can have improved strength by chemical strengthening in a series of stages. The stages can, for example, have a first ion exchange stage where larger ions are exchanged into the glass cover, and a second ion exchange stage where some of the larger ions are exchanged out from the glass cover. Optionally, in one embodiment, the glass cover can improve its strength by forming its edges with a predetermined geometry. Advantageously, the glass cover can be not only thin but also adequately strong to limit susceptibility to damage. In one embodiment, the glass member can pertain to a glass cover for a housing for an electronic device. The glass cover can be provided over or integrated with a display, such as a Liquid Crystal Display (LCD) display.

Claims

1. A method for producing a cover for an exposed surface of a consumer electronic product, the method comprising:

obtaining a glass cover for the exposed surface of the consumer electronic product; and

chemically strengthening the glass cover using a series of ion exchange stages.

2. A method as recited in claim 1, wherein the chemical strengthening forms a sub-surface compressive maximum slightly inward from the edges of the glass cover.

3. A method as recited in claim 2, wherein said chemically strengthening of the glass cover comprises:

placing the glass cover in a first heated solution for a first period of time to allow at least one component of the first heated solution to diffuse into the glass cover.

4. A method as recited in claim 3, wherein the first heated solution comprises Alkali metal ions.

5. A method as recited in claim 3, wherein the first heated solution is a potassium nitrate solution (KNO₃).

6. A method as recited in claim 3, wherein the heated solution comprises potassium.

7. A method as recited in claim 3, wherein the at least one component is potassium ions.

8. A method as recited in claim 3, wherein the at least one component is Alkali metal ions

9. A method as recited in claim 3, wherein the chemically strengthening of the glass cover further comprises:

placing the glass cover in a second heated solution for a second period of time to allow at least one component of the second heated solution to diffuse into the glass cover.

10. A method as recited in claim 9, wherein the at least one component is sodium ions.

11. A method as recited in claim 9, wherein the second period of time is less than or equal to 50% of the first period of time.

12. A method as recited in claim 1, wherein the series of ion exchange stages include a forward ion exchange stage, and a back ion exchange stage.

13. A method as recited in claim 12, wherein the forward ion exchange stage serves to exchange Alkali metal ions into the glass cover, and the back ion exchange serves to exchange Alkali metal ions from the glass cover.

14. A method for producing a glass cover for an exposed surface of a consumer electronic product, the method comprising:

obtaining a glass sheet;

singulating the glass sheet into a plurality of glass covers, each of the glass covers being suitably sized to be provided on the exposed surface of a consumer electronic product; and

chemically strengthening the glass covers by (i) placing the glass covers in a first heated solution for a first period of time to allow at least one component of the first heated solution to diffuse into the glass covers, and (ii) placing the glass covers in a second heated solution for a second period of time after removing the glass covers from the first heated solution.

15. The method as recited in claim 14, wherein the first heated solution includes at least one Alkali metal, and the second heated solution includes at least sodium.

16. A method as recited in claim 14, wherein the method further comprises:

thereafter attaching each of the glass covers to a corresponding consumer electronic product.

17. A method as recited in claim 16, wherein, after the glass cover is attached to the corresponding consumer electronic product, at least one of the edges of the glass cover remains exposed.

18. A method as recited in claim 16, the method does not couple a border or bezel around the at least one of the edges of the cover glass.

19. A method as recited in claim 16,

wherein, after the glass cover is attached to the corresponding consumer electronic product, the edges of the glass cover remains exposed, and

wherein the method does not couple a border or bezel around the at least one of the edges of the cover glass.

20. A method as recited in claim 14,

wherein the first heated solution is heated to a first temperature within range of approximately 370-430 degrees Celsius, and wherein the first period of time is between at least approximately 4 hours and at most approximately 25 hours, and

wherein the second solution being heated to a second temperature within range of approximately 370-430 degrees, and wherein the second period of time is between at least approximately 0.1 hours and at most approximately 2 hours.

21. A method as recited in claim 14, wherein the first heated solution is heated to a temperature of approximately 420 degrees Celsius, and wherein the period of time is at least approximately 6 hours.

22. A method as recited in claim 14, wherein the method further comprises:

manipulating the edges of each of the glass covers to correspond to a predetermined edge geometry prior to the placing the glass covers in the first heated solution, the predetermined edge geometry being selected to strengthen at least the edges of the glass covers.

23. A method as recited in claim 14, wherein the predetermined edge geometry has a predetermined curvature applied to the corners of the edges of the glass cover.

24. A method as recited in claim 14, wherein the predetermined edge geometry is one selected from the group including a rounded edge geometry.

25. A consumer electronic product, comprising:

a housing having a front surface, a back surface and side surfaces;

electrical components provided at least partially internal to the housing, the electrical components including at least a controller, a memory, and a display, the display being provided at or adjacent the front surface of the housing; and

a cover glass provided at or over the front surface of the housing such that it is provided over the display, the cover glass being strengthened chemically strengthening using a series of ion exchange stages.

26. A method as recited in claim 25, wherein the series of ion exchange stages include a forward ion exchange stage, and a back ion exchange stage.

27. A method as recited in claim 26, wherein the forward ion exchange stage serves to exchange Alkali metal ions into the glass cover, and the back ion exchange serves to exchange Alkali metal ions from the glass cover.

28. A consumer electronic product as recited in claim 25, wherein the cover glass extends to across at least a portion of the front surface of the housing to one or more edges between the front surface and one or more of the side surfaces.

29. A consumer electronic product as recited in claim 25, wherein edges of the glass cover correspond to a predetermined edge geometry, the predetermined edge geometry being selected to strengthen the edges of the cover glass.

30. A consumer electronic product as recited in claim 25, wherein the consumer electronic product is a handheld electronic device.

31. A consumer electronic product as recited in claim 25, wherein the thickness of the cover glass is less than 0.6 mm.

32. A consumer electronic product as recited in claim 25, wherein the depth of compressive layer resulting from the chemically strengthening of the glass cover is at least 10 microns.