SLURRY FOR PRODUCTION OF DENITRATION CATALYST, PROCESS FOR PRODUCING THE SLURRY, PROCESS FOR PRODUCING DENITRATION CATALYST USING THE SLURRY, AND DENITRATION CATALYST PRODUCED BY THE PROCESS

• US 20110028309A1
• Filed: 02/16/2009
• Published: 02/03/2011
• Est. Priority Date: 04/22/2008
• Status: Active Grant

• Current Assignee: Hitachi Zosen Corporation
• Original Assignee: Hitachi Zosen Corporation
• Inventors: Hikazudani, Susumu, Hino, Naoe
• Granted Patent: US 8,133,833 B2
• Time in Patent Office: Days
• US Class Current: 502/159
• CPC Class Codes: B01D 2251/2062 Ammonia
• CPC Class Codes: B01D 2255/20707 Titanium
• CPC Class Codes: B01D 2255/20723 Vanadium
• CPC Class Codes: B01D 2255/20776 Tungsten
• CPC Class Codes: B01D 2255/30 Silica
• CPC Class Codes: B01D 53/8628 Processes characterised by a specific catalyst
• CPC Class Codes: B01D 53/88 Handling or mounting catalysts
• CPC Class Codes: B01J 21/063 Titanium; Oxides or hydroxides thereof
• CPC Class Codes: B01J 23/002 Mixed oxides other than spinels, e.g. perovskite
• CPC Class Codes: B01J 23/30 Tungsten
• CPC Class Codes: B01J 2523/00 Constitutive chemical elements of heterogeneous catalysts
• CPC Class Codes: B01J 2523/41 Silicon
• CPC Class Codes: B01J 2523/47 Titanium
• CPC Class Codes: B01J 2523/55 Vanadium
• CPC Class Codes: B01J 2523/69 Tungsten
• CPC Class Codes: B01J 37/0219 the coating containing organic compounds

Abstract

Disclosed are a slurry for the production of a denitration catalyst, which allows a catalytically active component to be present in the inner region of a ceramic fiber sheet so as to achieve extension of the catalyst life and also allows the production process to be shortened so as to reduce the production cost; a process for producing the slurry; a process for producing a denitration catalyst using the slurry; and a denitration catalyst produced by the process. The slurry of the invention for producing a denitration catalyst comprises a silica sol, titania particles, metavanadic acid particles supported on the titania particles, metatungstic acid particles, and an organic acid ammonium salt.

Claims

1. A slurry for the production of a denitration catalyst, comprising a silica sol, titania particles, metavanadic acid particles supported on the titania particles, metatungstic acid particles, and an ammonium salt of an organic acid.

2. The slurry for the production of a denitration catalyst according to claim 1, having an aqueous ammonia solution added thereto to adjust the pH to 4 to 7.

3. The slurry for the production of a denitration catalyst according to claim 1, wherein the ammonium salt of an organic acid is present at a concentration of 25 to 125 mL/L of the total volume of the slurry.

4. The slurry for the production of a denitration catalyst according to claim 1, wherein the ammonium salt of an organic acid is ammonium polyacrylate.

9. A process for producing a denitration catalyst, comprising immersing a catalyst substrate in a slurry for the production of a denitration catalyst according to claim 1.

10. The process according to claim 9, wherein the catalyst substrate is a honeycomb substrate.

11. The process according to claim 10, wherein the honeycomb substrate is formed of an inorganic fiber sheet.

12. A denitration catalyst produced by a process according to claim 9.

5. A process for producing a slurry for the production of a denitration catalyst, comprising mixing a titania particle powder with a silica sol to form a suspension, adding an ammonium metavanadate powder to the suspension so that the metavanadic acid is supported on the surface of the titania particles, adding ammonium metatungstate to the suspension, and adding an ammonium salt of an organic acid to the suspension.

6. The process for producing a slurry for the production of a denitration catalyst according to claim 5, wherein after adding the ammonium metatungstate and before adding the ammonium salt of an organic acid, an aqueous ammonia solution is added to adjust the pH to a range from 4 to 7.

7. The process for producing a slurry for the production of a denitration catalyst according to claim 5, wherein the ammonium salt of an organic acid is present at a concentration of 25 to 125 mL/L of the total volume of the final slurry.

8. The process for producing a slurry for the production of a denitration catalyst according to claim 5, wherein the ammonium salt of an organic acid is ammonium polyacrylate.

13. A process for producing a denitration catalyst, comprising immersing a catalyst substrate in a slurry for the production of a denitration catalyst produced by the process according to claim 5.

14. A denitration catalyst produced by the process according to claim 13.

15. The process according to claim 13, wherein the catalyst substrate is a honeycomb substrate.

16. The process according to claim 13, wherein the honeycomb substrate is formed of an inorganic fiber sheet.