FUEL CELLS

• US 20110039170A1
• Filed: 09/22/2008
• Published: 02/17/2011
• Est. Priority Date: 09/20/2007
• Status: Active Grant

• Current Assignee: ACAL Energy Ltd
• Original Assignee: ACAL Energy Ltd
• Inventors: Farndon, Emma, Creeth, Andrew Martin
• Granted Patent: US 8,603,684 B2
• Time in Patent Office: Days
• US Class Current: 429/417
• CPC Class Codes: H01M 4/8605 Porous electrodes
• CPC Class Codes: H01M 4/90 Selection of catalytic material
• CPC Class Codes: H01M 4/9008 Organic or organo-metallic compounds
• CPC Class Codes: H01M 4/9016 Oxides, hydroxides or oxygenated metallic salts
• CPC Class Codes: H01M 8/04126 Humidifying
• CPC Class Codes: H01M 8/04186 of liquid-charged or electrolyte-charged reactants
• CPC Class Codes: H01M 8/04197 Preventing means for fuel crossover
• CPC Class Codes: H01M 8/1009 with one of the reactants being liquid, solid or liquid-charged H01M8/12 takes precedence
• CPC Class Codes: H01M 8/1011 Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC]
• CPC Class Codes: H01M 8/1013 Other direct alcohol fuel cells [DAFC]
• CPC Class Codes: H01M 8/1023 having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
• CPC Class Codes: H01M 8/1025 having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
• CPC Class Codes: H01M 8/1027 having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
• CPC Class Codes: H01M 8/103 having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
• CPC Class Codes: H01M 8/1032 having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
• CPC Class Codes: H01M 8/1039 halogenated, e.g. sulfonated polyvinylidene fluorides
• CPC Class Codes: H01M 8/188 by recharging of redox couples containing fluids; Redox flow type batteries
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

The present invention concerns a fuel cell comprising a cathode in a cathode region of the cell and an anode in an anode region of the cell, the cathode being separated from the anode by an ion selective polymer electrolyte membrane, the cathode region of the cell being supplied in use thereof with an oxidant and a liquid low molecular weight fuel wherein at least some of the liquid low molecular weight fuel in use crosses the polymer electrolyte membrane to supply the anode region of the cell with liquid low molecular weight fuel, the cell being provided with means for generating an electrical circuit between the cathode and the anode.

Claims

1. A fuel cell comprising:

a cathode in a cathode region of the cell and an anode in an anode region of the cell, the cathode being separated from the anode by an ion selective polymer electrolyte membrane, the cathode region of the cell being supplied in use thereof with an oxidant and a liquid low molecular weight fuel;

wherein at least some of the liquid low molecular weight fuel in use crosses the polymer electrolyte membrane to supply the anode region of the cell with liquid low molecular weight fuel; and

an electrical circuit between the cathode and the anode.

2. A fuel cell according to claim 1, wherein the anode region of the cell is supplied with water.

3. A fuel cell according to claim 1, wherein the liquid low molecular weight fuel comprises at least one low molecular weight alcohol.

4. A fuel cell according to claim 3, wherein the low molecular weight fuel is selected from the group consisting of:

methanol, ethanol, propanol, isopropanol and butanol, dipropylene glycol and ethylene glycol, and mixtures of two or more thereof.

5. A fuel cell according to claim 1, wherein the operating temperature of the fuel cell is below 100°

C.

6. A fuel cell according to claim 1, wherein the cathode region of the cell comprises a non-volatile catholyte solution in flowing fluid communication with the cathode, the catholyte solution comprising a redox couple, wherein the redox couple is at least partially reduced at the cathode in operation of the cell, and at least partially re-generated by reaction with the oxidant after such reduction at the cathode.

7. A fuel cell according to claim 6, additionally comprising at least one of a redox catalyst, a redox mediator and the redox couple acting as at least one of a redox catalyst and a redox mediator in the cathode region of the cell.

8. A fuel cell according to claim 6, wherein at least one of the redox couple, the redox catalyst, and the redox mediator comprises at least one transition metal complex.

9. A fuel cell according to claim 8, wherein at least one of the redox couple-, the redox catalyst, and the redox mediator comprises a polyoxometallate species.

10. A fuel cell according to claim 8, wherein at least one of the redox couple, the redox catalyst, and the redox mediator comprises a modified ferrocene species.

11. A fuel cell according to claim 6, wherein the concentration of the redox couple in the catholyte solution is at least about 0.1 M.

12. A fuel cell according to claim 6, wherein the cathode region of the cell is provided with a reservoir for storing the catholyte solution.

13. A fuel cell according to claim 7, wherein the polyoxometallate is represented by the formula:

X_a[Z_bM_cO_d]

wherein;

X is selected from the group consisting of;

hydrogen, alkali metals, alkaline earth metals, ammonium, and combinations of two or more thereof;

Z is selected from the group consisting of;

B, P, S, As, Si, Ge, Ni, Rh, Sn, Al, Cu, I, Br, F, Fe, Co, Cr, Zn, H₂, Te, Mn, Se, and combinations of two or more thereof;

M is a metal selected from the group consisting of;

Mo, W, V, Nb, Ta, Mn, Fe, Co, Cr, Ni, Zn, Rh, Ru, Tl, Al, Ga, In, metals selected from the 1st, 2^nd, and 3rd transition metal series, metals selected from the lanthanide series, and combinations of two or more thereof;

a is a number of X necessary to charge balance the [M_cO_d] anion;

b is from 0 to 20;

c is from 1 to 40; and

d is from 1 to 180.

14. A fuel cell according to claim 13, wherein b is from 0 to 2.

15. A fuel cell according to claim 13, wherein M is selected from the group consisting of:

vanadium, molybdenum, and combinations thereof.

16. A fuel cell according to claim 13, wherein Z is phosphorus.

17. A fuel cell according to claim 13, wherein X comprises a combination of hydrogen with alkali metal ions and/or alkaline earth metal ions.

18. A fuel cell according to claim 9, wherein the polyoxometallate comprises one of molybdophosphoric acid (H₃PMo₁₂O₄₀) and molybdovanadophosphoric acid (H₅PMo₁₀V₂O₄₀).

19. A method of generating electricity by the fuel cell of claim 1, comprising:

supplying the alcoholic fuel to the anode region;

supplying the oxidant to the cathode region; and

generating electricity through the electrical circuit between the anode and the cathode.