GAS BARRIER FILM HAVING EXCELLENT WEATHER RESISTANCE

• US 20110045301A1
• Filed: 01/27/2009
• Published: 02/24/2011
• Est. Priority Date: 01/31/2008
• Status: Abandoned Application

• Current Assignee: Mitsubishi Plastics Incorporated (Mitsubishi Chemical Group Corp.)
• Original Assignee: Mitsubishi Plastics Incorporated (Mitsubishi Chemical Group Corp.)
• Inventors: Hachisuka, Tooru, Yoshida, Shigenobu, Okawara, Chiharu
• Application Number:
  US12/865,276
• Publication Number:
  US 20110045301A1
• Time in Patent Office: Days
• US Class Current: 428/412
• CPC Class Codes: C08J 2367/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds; C08J2367/06 takes precedence
• CPC Class Codes: C08J 7/0423 with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder
• CPC Class Codes: C08J 7/043 Improving the adhesiveness of the coatings per se, e.g. forming primers adhesives in the form of films or foils characterised by the primer layers between the polymer carriers and the adhesives C09J7/50
• CPC Class Codes: C08J 7/046 Forming abrasion-resistant coatings; Forming surface-hardening coatings
• CPC Class Codes: C08J 7/048 Forming gas barrier coatings
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/31511 Of epoxy ether
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]
• CPC Class Codes: Y10T 428/31935 Ester, halide or nitrile of addition polymer

Abstract

Provided is a weather-resistant gas barrier film capable of keeping a high delamination strength and an excellent gas barrier property in a high-temperature high-humidity environment and in a UV radiation environment.

The gas barrier film comprises a substrate film, a weather-resistant coating layer formed on at least one surface thereof, and an inorganic thin film layer formed on the surface of the coating layer, wherein the weather-resistant coating layer is selected from (1) a weather-resistant coating layer that contains an acrylic copolymer having at least one group selected from a UV-stabilizing group, a UV-absorbing group and a cycloalkyl group, (2) a weather-resistant coating layer formed by crosslinking a polycaprolactone-polyol and/or a polycarbonate-polyol as the essential ingredient, and (3) a weather-resistant coating layer formed by crosslinking a modified polyvinyl alcohol; and also provided is a method for producing the gas barrier film.

Claims

1. A gas barrier film comprising a substrate film, a weather-resistant coating layer formed on at least one surface thereof, and an inorganic thin film layer formed on the surface of the coating layer, wherein the weather-resistant coating layer is selected from (1) a weather-resistant coating layer that contains an acrylic copolymer having at least one group selected from a UV-stabilizing group, a UV-absorbing group and a cycloalkyl group, (2) a weather-resistant coating layer formed by crosslinking a polycaprolactone-polyol and/or a polycarbonate-polyol as the essential ingredient, and (3) a weather-resistant coating layer formed by crosslinking a modified polyvinyl alcohol.

2. The gas barrier film as claimed in claim 1, wherein the UV-stabilizing group in the weather-resistant coating layer (1) is a hindered amine group, and the UV-absorbing group therein is a benzotriazole group and/or a benzophenone group.

3. The gas barrier film as claimed in claim 1, wherein the acrylic copolymer in the weather-resistant coating layer (1) has a crosslinking functional group.

4. The gas barrier film as claimed in claim 1, wherein the acrylic copolymer in the weather-resistant coating layer (1) has at least a UV-absorbing group and a cycloalkyl group.

5. The gas barrier film as claimed in claim 1, wherein the acrylic copolymer in the weather-resistant coating layer (1) has at least a UV-stabilizing group, a UV-absorbing group and a cycloalkyl group.

6. The gas barrier film as claimed in claim 1, wherein the weather-resistant coating layer (1) is one formed by reacting the acrylic copolymer and a crosslinking compound.

7. The gas barrier film as claimed in claim 1, wherein the weather-resistant coating layer (1) is one formed by reacting an acrylic copolymer having at least one group selected from a hindered amine group, a benzotriazole group and/or a benzophenone group, and a cycloalkyl group, and also a hydroxyl group, with an isocyanate compound.

8. The gas barrier film as claimed in claim 1, wherein the acrylic copolymer in the weather-resistant coating layer (1) is one produced through copolymerization with at least one selected from a group consisting of at least a polymerizing UV-stabilizing monomer, a polymerizing UV-absorbing monomer and a cycloalkyl(meth)acrylate.

9. The gas barrier film as claimed in claim 1, wherein the weather-resistant coating layer (2) is one formed by crosslinking a polycaprolactone-polyol and/or a polycarbonate-polyol with an isocyanate compound and/or an epoxy compound.

10. The gas barrier film as claimed in claim 1, wherein the weather-resistant coating layer (3) is one formed by crosslinking polyvinyl butyral and/or polyvinyl acetal as the essential ingredient.

11. The gas barrier film as claimed in claim 1, wherein the weather-resistant coating layer (3) is one formed by crosslinking a modified polyvinyl alcohol with an isocyanate compound and/or an epoxy compound.

12. The gas barrier film as claimed in claim 1, wherein the weather-resistant coating layer (3) is one formed by crosslinking polyvinyl butyral and/or polyvinyl acetal with an isocyanate compound and/or an epoxy compound.

13. The gas barrier film as claimed in claim 1, wherein the inorganic thin film layer comprises an inorganic oxide.

14. The gas barrier film as claimed in claim 1, wherein the inorganic thin film layer is composed of at least two inorganic thin film layers.

15. The gas barrier film as claimed in claim 1, wherein the substrate film is a biaxially-oriented film containing polyethylene naphthalate.

16. A method for producing a gas barrier film comprising forming a weather-resistant coating layer on at least one surface of a substrate film followed by forming an inorganic thin film on the surface of the coating layer, wherein an acrylic copolymer produced through copolymerization with at least one selected from a group consisting of a polymerizing UV-stabilizing monomer, a polymerizing UV-absorbing monomer and a cycloalkyl(meth)acrylate is used for the weather-resistant coating layer.

17. The method for producing a gas barrier film as claimed in claim 16, wherein the weather-resistant layer is formed by reacting the acrylic copolymer having a crosslinking functional group with a crosslinking compound.

18. A method for enhancing the weather resistance of a gas barrier film comprising a substrate film, a coating layer formed on at least one surface thereof, and an inorganic thin film formed on the surface of the coating layer, wherein an acrylic copolymer having at least one group selected from a UV-stabilizing group, a UV-absorbing group and a cycloalkyl group is used for the coating layer.