POLYMERS CONTAINING BORANE OR CARBORANE CAGE COMPOUNDS AND RELATED APPLICATIONS
First Claim
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1. A polymer comprising:
- a plurality of residues of a borane and/or carborane cage compound monomer,wherein said cage compound monomer comprises at least one silyl substituent having the formula
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R6Si(OR7)nR83-nwherein R6 is a C0 to C20 alkylene or arylene group, oxygen, or —
OR9, wherein R9 is a C1 to C20 alkylene or arylene group;
wherein each R7 is independently any alkyl group;
wherein n is at least 2; and
wherein R8 is hydrogen, an alkyl group, an aryl group, an alkaryl group, or an aralkyl group,wherein said cage compound monomer comprises at least 7 cage atoms.
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Abstract
Polymers comprising residues of borane and/or carborane cage compound monomers having at least one polyalkoxy silyl substituent. Such polymers can further comprise one or more reactive matrices and/or co-monomers covalently bound with the cage compound monomer residues. Methods of making and applications for using such polymers are also disclosed.
24 Citations
30 Claims
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1. A polymer comprising:
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a plurality of residues of a borane and/or carborane cage compound monomer, wherein said cage compound monomer comprises at least one silyl substituent having the formula
—
R6Si(OR7)nR83-nwherein R6 is a C0 to C20 alkylene or arylene group, oxygen, or —
OR9, wherein R9 is a C1 to C20 alkylene or arylene group;
wherein each R7 is independently any alkyl group;
wherein n is at least 2; and
wherein R8 is hydrogen, an alkyl group, an aryl group, an alkaryl group, or an aralkyl group,wherein said cage compound monomer comprises at least 7 cage atoms. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15)
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16. A method of making a polymer, said method comprising:
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combining a borane and/or a carborane cage compound monomer with a reactive matrix and/or a co-monomer to thereby form a polymerization reaction medium; and subjecting said polymerization reaction medium to reaction conditions sufficient to polymerize at least a portion of said cage compound monomer with at least a portion of said reactive matrix and/or said co-monomer, wherein said cage compound monomer comprises at least one silyl substituent having the formula
—
R6Si(OR7)nR83-nwherein R6 is a C0 to C20 alkylene or arylene group, oxygen, or —
OR9, wherein R9 is a C1 to C20 alkylene or arylene group;
wherein each R7 is independently any alkyl group;
wherein n is at least 2; and
wherein R8 is hydrogen, an alkyl group, an aryl group, an alkaryl group, or an aralkyl group,wherein said reactive matrix and said co-monomer each comprise at least one type of functional group capable of forming a covalent bond with said silyl substituent, wherein said cage compound monomer comprises at least 7 cage atoms. - View Dependent Claims (17, 18, 19, 20, 21, 22)
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23. An article of manufacture comprising a polymer, said polymer comprising:
- a plurality of residues of a borane and/or a carborane cage compound monomer, wherein said cage compound monomer is selected from the group consisting of;
- View Dependent Claims (24, 25, 26, 27, 28, 29, 30)
- a plurality of residues of a borane and/or a carborane cage compound monomer, wherein said cage compound monomer is selected from the group consisting of;
Specification