METHODS OF SONICALLY ACTIVATING CEMENT COMPOSITIONS

• US 20110048711A1
• Filed: 08/25/2009
• Published: 03/03/2011
• Est. Priority Date: 08/25/2009
• Status: Active Grant

• Current Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Original Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Inventors: Lewis, Sam, Gupta, Vijay, Reyes, Priscilla T., Stoner, Brian R., Badalamenti, Anthony
• Granted Patent: US 8,047,282 B2
• Time in Patent Office: Days
• US Class Current: 166/286
• CPC Class Codes: C09K 8/467 containing additives for specific purposes
• CPC Class Codes: C09K 8/516 characterised by their form or by the form of their components, e.g. encapsulated material
• CPC Class Codes: E21B 27/02 Dump bailers, i.e. containers for depositing substances, e.g. cement or acids
• CPC Class Codes: E21B 33/14 for cementing casings into boreholes

Abstract

The present disclosure is directed to a system and method for sonically activating cement slurries. In some implementations, a method of treating a subterranean formation includes positioning a settable composition including a capsule in a wellbore. The capsule is used to increase a setting rate in response to at least sonic signals. A sonic signal is transmitted to at least a portion of the settable composition to release an activator from the capsule.

Claims

1. A method of treating a subterranean formation, comprising:

placing a settable composition including a capsule in a wellbore, wherein the capsule is used to increase a setting rate in response to a sonic signal; and

transmitting the sonic signal to at least a portion of the settable composition to release an activator from the capsule, wherein the activator is configured to increase setting rate of the settable composition.

2. The method of claim 1, wherein the capsule is sonically activated.

3. The method of claim 2, wherein the capsule comprises a shell enclosing one or more activators.

4. The method of claim 3, wherein the shell comprises a sonically responsive polymer.

5. The method of claim 1, wherein the capsule comprises a shell selected from the group consisting of a polystyrene, ethylene/vinyl acetate copolymer, polymethylmethacrylate, polyurethanes, polylactic acid, polyvinylalcohol, polyvinylacetate, hydrolyzed ethylene/vinyl acetate, and copolymers thereof.

6. The method of claim 1, wherein the settable composition sets in a range from about one minute to about 24 hours after reacting with the activator.

7. The method of claim 1, wherein the settable composition includes at least one of a cement composition, a resin composition, a settable mud, a conformance fluid, or a lost circulation composition.

8. A method of cementing in a subterranean formation, comprising:

placing a cement composition including a capsule in a wellbore, wherein the capsule encapsulates an activator configured to increase a setting rate of the cement composition; and

transmitting a sonic signal to at least a portion of the cement composition to release the activator from the encapsulating capsule.

9. The method of claim 8, wherein the capsule is sonically activated.

10. The method of claim 9, wherein the capsule comprises a shell encapulating one or more activators.

11. The method of claim 10, wherein the shell comprises a sonically responsive polymer.

12. The method of claim 8, wherein each of the plurality of capsules comprise a shell selected from the group consisting of a polystyrene, ethylene/vinyl acetate copolymer, polymethylmethacrylate, polyurethanes, polylactic acid, polyvinylalcohol, polyvinylacetate, hydrolyzed ethylene/vinyl acetate, and copolymers thereof.

13. The method of claim 8, wherein a plurality of capsules are mixed with the cement composition to an activator concentration from about 0.5% to about 30% by weight of cement.

14. The method of claim 8, wherein the cement composition comprises a hydraulic cement, a base fluid and a retarder.

15. The method of claim 8, wherein the cement composition is selected from the group consisting of Portland cement, pozzolanic cement, high aluminate cement, gypsum cement, silica cement, high alkalinity cement and sorel cement.

16. The method of claim 8, wherein the cement composition sets in a range from about one minute to about 24 hours after reacting with the activator.

17. The method of claim 8, wherein at least one dimension of the capsule is from about 10 nanometers to about 10,000 micrometers.

18. The method of claim 8, wherein the capsule comprises a spheroid with at least one dimension in a range from about 5 micrometers (μ

m) to about 20 μ

m.

19. The method of claim 8, wherein the sonic signal is transmitted at a frequency in a range from about 20 Hertz to about 2 megaHertz (MHz).

20. The method of claim 8, wherein the sonic signal comprises an ultrasonic signal.

21. The method of claim 20, wherein the ultrasonic signal substantially centered at frequency in a range from about 20 to about 2 MHz.

22. The method of claim 8, wherein the sonic signal comprises an acoustic signal.

23. The method of claim 22, wherein the acoustic signal is transmitted at a frequency in a range from about 20 Hertz to about 20 kHz.

24. The method of claim 8, wherein the activator is selected from a group consisting of sodium hydroxide, sodium carbonate, amine compounds, salts comprising calcium, sodium, magnesium, aluminum, and combinations thereof.

25. The method of claim 8, wherein the activator is selected from the group consisting of calcium chloride, calcium nitrite, calcium nitrate, sodium chloride, sodium aluminate, sodium silicate, magnesium chloride, and combinations thereof.

26. The method of claim 8, wherein the activator is selected from a group consisting of triethanol amine, tripropanol amine, tri-isopropanol amine, diethanol amine, and, and combinations thereof.

27. A method for setting a settable composition, comprising:

positioning the settable composition in a wellbore; and

transmitting a sonic signal in the settable composition to initiate setting using a mechanism directly responsive to the sonic signal.

28. The method of claim 27, wherein the settable composition comprises at least one of a cement composition, a resin composition, a settable mud, a conformance composition, or a lost circulation composition.

29. The method of claim 27, wherein the mechanism includes activation of an activator or deactivation of a set retarder, the activated activator configured to increase a setting rate of the settable composition.

30. The method of claim 27, wherein the settable composition comprises a free-radical dopant that releases autocatalytic free radicals in response to the sonic signal.

31. The method of claim 30, wherein the settable composition includes a polymeric additive, the released autocatalytic free radicals initiate polymerization of at least a portion of the settable composition.

32. The method of claim 27, wherein the mechanism includes decreasing a particulate size in the cement slurry.

33. The method of claim 27, wherein the mechanism includes increasing at least one of pressure or temperature of the settable composition.

34. The method of claim 27, wherein the sonic signal is transmitted at a frequency in a range from about 20 Hertz to about 2 MHz.

35. The method of claim 27, further comprising determining a frequency for transmitting the sonic signal based, at least in part, on an inhibitor chemistry of the settable composition.

36. The method of claim 27, wherein the sonic signal is an ultrasonic signal.

37. The method of claim 36, wherein the ultrasonic signal is transmitted at a frequency in the range of from about 20 to about 2 MHz.

38. The method of claim 27, wherein the sonic signal is an acoustic signal.

39. The method of claim 38, wherein the acoustic signal is transmitted at a frequency in the range of from about 20 Hertz to about 20 kiloHertz.