INTEGRATED HYDROMETHANATION COMBINED CYCLE PROCESS

• US 20110062721A1
• Filed: 09/15/2010
• Published: 03/17/2011
• Est. Priority Date: 09/16/2009
• Status: Abandoned Application

• Current Assignee: Sure Champion Investments Limited
• Original Assignee: GreatPoint Energy, Inc.
• Inventors: Sirdeshpande, Avinash, Preston, William E.
• Application Number:
  US12/882,408
• Publication Number:
  US 20110062721A1
• Time in Patent Office: Days
• US Class Current: 290/1.R
• CPC Class Codes: C01B 2203/0288 containing two CO-shift steps
• CPC Class Codes: C01B 2203/0405 Purification by membrane separation
• CPC Class Codes: C01B 2203/0415 Purification by absorption in liquids
• CPC Class Codes: C01B 2203/043 Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
• CPC Class Codes: C01B 2203/0445 Selective methanation
• CPC Class Codes: C01B 2203/046 Purification by cryogenic separation
• CPC Class Codes: C01B 2203/047 the impurity being carbon monoxide
• CPC Class Codes: C01B 2203/0475 the impurity being carbon dioxide
• CPC Class Codes: C01B 2203/0485 the impurity being a sulfur compound
• CPC Class Codes: C01B 2203/0888 by evaporation of a fluid
• CPC Class Codes: C01B 2203/0894 Generation of steam
• CPC Class Codes: C01B 2203/1047 Group VIII metal catalysts
• CPC Class Codes: C01B 2203/147 Three or more purification steps in series
• CPC Class Codes: C01B 2203/148 involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
• CPC Class Codes: C01B 2203/84 Energy production
• CPC Class Codes: C01B 2203/86 Carbon dioxide sequestration
• CPC Class Codes: C01B 3/16 using catalysts
• CPC Class Codes: C10J 2300/093 Coal
• CPC Class Codes: C10J 2300/0956 Air or oxygen enriched air
• CPC Class Codes: C10J 2300/0959 Oxygen
• CPC Class Codes: C10J 2300/0976 : as steam
• CPC Class Codes: C10J 2300/0986 : Catalysts
• CPC Class Codes: C10J 2300/1653 : integrated in a gasification combined cycle [IGCC]
• CPC Class Codes: C10J 2300/1662 : to methane
• CPC Class Codes: C10J 2300/1671 : with the production of electricity
• CPC Class Codes: C10J 3/00 : Production of combustible gases containing carbon monoxide from solid carbonaceous fuels destructive distillation processes C10B
• CPC Class Codes: C10K 1/004 : Sulfur containing contaminants, e.g. hydrogen sulfide
• CPC Class Codes: C10K 1/005 : Carbon dioxide
• CPC Class Codes: C10K 3/04 : reducing the carbon monoxide content , e.g. water-gas shift [WGS]
• CPC Class Codes: C10L 3/08 : Production of synthetic natural gas
• CPC Class Codes: C10L 3/102 : of acid contaminants
• CPC Class Codes: F01K 23/067 : the combustion heat coming from a gasification or pyrolysis process, e.g. coal gasification gas turbines with fuel gasifiers F02C3/28
• CPC Class Codes: Y02E 20/18 : Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
• CPC Class Codes: Y02P 20/10 : Process efficiency
• CPC Class Codes: Y02P 20/129 : Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
• CPC Class Codes: Y02P 30/00 : Technologies relating to oil refining and petrochemical industry

Abstract

The present invention relates to an integrated process for preparing combustible gaseous products via the hydromethanation of carbonaceous feedstocks in the presence of steam, carbon monoxide, hydrogen, a hydromethanation catalyst and optionally oxygen, and generating electrical power from those combustible gaseous products as well as a hydrogen and/or methane by-product stream.

Claims

1. An integrated process for generating a plurality of gaseous products from a carbonaceous feedstock, and generating electric power, the process comprising the steps of:

(a) supplying to a hydromethanation reactor (1) a carbonaceous feedstock comprising a carbon content, (2) a hydromethanation catalyst, (3) a steam stream, and (4) an oxygen-rich gas stream;

(b) reacting a portion of the carbon content of the carbonaceous feedstock with oxygen in the hydromethanation reactor to generate carbon monoxide, hydrogen and heat energy;

(c) reacting the carbonaceous feedstock in the hydromethanation reactor in the presence of carbon monoxide, hydrogen, steam and hydromethanation catalyst to produce a methane-enriched raw product stream comprising methane, carbon monoxide, hydrogen, carbon dioxide, hydrogen sulfide and heat energy;

(d) withdrawing the methane-enriched raw product stream from the hydromethanation reactor;

(e) introducing the methane-enriched raw product stream into a first heat exchanger unit to remove heat energy from the methane-enriched raw product stream;

(f) sour shifting at least a predominant portion of the carbon monoxide in the methane-enriched raw product stream to produce a hydrogen-enriched raw product stream comprising hydrogen, methane, carbon dioxide, hydrogen sulfide and optionally carbon monoxide;

(g) removing a substantial portion of the carbon dioxide and a substantial portion of the hydrogen sulfide from the hydrogen-enriched raw product stream to produce a sweetened gas stream comprising a substantial portion of the hydrogen, methane and carbon monoxide (if present) from the hydrogen-enriched raw product stream;

(h) optionally separating at least a portion of the hydrogen from the sweetened gas stream to produce (1) a hydrogen product stream and (2) a hydrogen-depleted sweetened gas stream comprising methane, carbon monoxide (if present in the sweetened gas stream) and optionally hydrogen;

(i) optionally reacting carbon monoxide and hydrogen present in the sweetened gas stream (or the hydrogen-depleted sweetened gas stream if present) in a catalytic methanator to produce a methane-enriched sweetened gas stream;

(j) if the methane-enriched sweetened gas stream is present, optionally splitting the methane-enriched sweetened gas stream into a methane product stream and a methane-enriched split gas stream;

(k) supplying the sweetened gas stream (or the methane-enriched split gas stream if present) to a power generation block comprising a combustor; and

(l) combusting the sweetened gas stream (or the methane-enriched split gas stream if present) in the combustor to generate electrical power,

wherein

the reaction in step (c) has a syngas demand, and the reaction in step (b) is at least sufficient to generate enough carbon monoxide and hydrogen to at least meet the syngas demand of the reaction in step (c);

one or both of steps (h) and (i) are present; and

if step (i) is present and step (h) is not present, then step (j) is present.

2. The process of claim 1, wherein step (h) is present.

3. The process of claim 1, wherein step (h) is not present.

4. The process of claim 1, wherein step (i) is present.

5. The process of claim 4, wherein step (j) is present.

6. The process of claim 1, wherein step (i) is not present.

7. The process of claim 1, wherein the reaction in step (c) has a steam demand;

the carbonaceous feedstock optionally comprises a moisture content;

the oxygen-rich gas stream optionally comprises steam; and

the steam demand is substantially satisfied by the steam stream, steam contained in the feed gas stream, the moisture content (if present) of the carbonaceous feedstock, and steam (if present) in the first oxygen-rich gas stream.

8. The process of claim 1, wherein the reaction in step (c) has a heat demand, and the steam stream as fed into the hydromethanation reactor comprises heat energy that, in combination with the heat energy generated by the reaction of step (b), is sufficient to at least meet the heat demand of the reaction in step (c).

9. The process of claim 1, wherein the process is a continuous process, in which steps (a), (b), (c), (d), (e), (f), (g), (k) and (l) are operated in a continuous manner.

10. The process of claim 1, wherein step (h) is present, and operated in a continuous or discontinuous manner to result in a variable hydrogen product stream output.

11. The process of claim 1, wherein steps (i) and (j) are present, and step (i) is operated in a continuous manner, but step (j) is operated in a continuous or discontinuous manner to result in a variable methane product stream output.

12. The process of claim 1, wherein a char by-product is generated in step (b).

13. The process of claim 12, wherein the char by-product is periodically or continuously withdrawn from the hydromethanation reactor, and at least a portion of the withdrawn by-product char is provided to a catalyst recovery operation.

14. The process of claim 1, wherein the heat energy removed in step (e) is used at least in part to generate process steam.

15. The process of claim 14, wherein the steam stream is substantially made up from process steam.

16. The process of claim 1, wherein the power generation block comprises an expander, a combustor and a heat recovery steam generator.

17. The process of claim 1, wherein the hydromethanation catalyst comprises an alkali metal hydromethanation catalyst.

18. The process of claim 1, wherein the carbonaceous feedstock is loaded with a hydromethanation catalyst prior to introduction into the hydromethanation reactor.

19. The process of claim 18, wherein the carbonaceous feedstock is loaded with an amount of an alkali metal hydromethanation catalyst sufficient to provide a ratio of alkali metal atoms to carbon atoms ranging from about 0.01 to about 0.10.