METHOD FOR REDUCING AEROSOL EMISSIONS IN A UREA GRANULATION PLANT

• US 20110064635A1
• Filed: 05/04/2009
• Published: 03/17/2011
• Est. Priority Date: 05/14/2008
• Status: Active Grant

• Current Assignee: Uhde Fertilizer Technology B.V. (Alfried Krupp Von Bohlen Und Halbach-Stiftung)
• Original Assignee: Uhde Fertilizer Technology B.V. (Alfried Krupp Von Bohlen Und Halbach-Stiftung)
• Inventors: Potthoff, Matthias, Monstrey, Roland, Franzrahe, Harald, Niehues, Paul
• Granted Patent: US 8,080,687 B2
• Time in Patent Office: Days
• US Class Current: 423/230
• CPC Class Codes: B01D 2251/50 Inorganic acids
• CPC Class Codes: B01D 53/58 Ammonia
• CPC Class Codes: B01D 53/77 Liquid phase processes
• CPC Class Codes: C05C 9/005 Post-treatment
• CPC Class Codes: C05G 5/12 Granules or flakes

Abstract

The invention relates to a process for the granulation of a concentrated urea solution whereas the granulation produces a urea granulate and a dust laden air, which is then fed into a dust scrubber which removes the coarser dust with a less concentrated urea solution and which releases a residual air comprising air with ammonia, carbon dioxide water and an aerosol comprising mainly ammonium isocyanate and a part of very fine urea sublimate, whereas the aerosol is then separated off and fed into a isomerisation unit which comprises a stripping where the ammonium isocyanate reacts with steam to form urea which is then redirected into the dust scrubber as a less concentrated urea solution, and the residual air is directed into an acidic scrubber which releases clean air into the atmosphere which finally leads to a recycling of the aerosol of ammonium isocyanate into urea. The invention also relates to a device for carrying out the related process.

Claims

1-13. -13. (canceled)

14. A method for reducing aerosol emissions from a urea granulation plant with the treatment of the resulting scrubber bleeds, comprising:

producing urea with a granulator from a concentrated urea solution and an evaporation of the included water, giving urea granulates and an exhaust of dust, ammonia and ammonium isocyanate;

subsequently scrubbing or removing the dust; and

releasing a first stream of an exhaust of air and ammonia, and a second stream of ammonium isocyanate and water in a following aerosol stage with a specially designed spray and collection pads;

wherein

the second stream of ammonium isocyanate and water is fed into a isomerisation unit where the fraction of ammonium isocyanate is isomerised back to urea, whereas the isomerisation of ammonium isocyanate to urea is carried out in a stripping column with the feeding of low pressure steam to the bottom of the column; and

the resulting urea in the stripping column is fed into a liquid phase, and the remaining ammonia and carbon dioxide are released to the head of the column.

15. The method for reducing aerosol emissions from a urea granulation plant with a recovery of the resulting scrubber bleeds according to claim 15, wherein the liquid phase with the urea from the stripping column is concentrated in a concentration step.

16. The method for reducing aerosol emissions from a urea granulation plant with a recovery of the resulting scrubber bleeds according to claim 15, wherein the liquid phase with the urea from the stripping column is recycled to the granulator, to the dust separation unit or used for non-process purposes.

17. The method for reducing aerosol emissions from a urea granulation plant with a recovery of the resulting scrubber bleeds according to claim 15, wherein the exhaust of ammonium isocyanate and water is fed into a heat exchanger before entering the isomerisation unit.

18. The method for reducing aerosol emissions from a urea granulation plant with a recovery of the resulting scrubber bleeds according to claim 15, the resulting gaseous phase of ammonia, carbon dioxide and water from the isomerisation unit is fed into a carbamate condenser, which condenses the carbamate into a liquid and returns this to the urea synthesis.

19. The method for reducing aerosol emissions from a urea granulation plant with a recovery of the resulting scrubber bleeds according to claim 15, wherein the stripping column uses low pressure steam for maintaining temperature and pressure in the isomerisation unit.

20. The method for reducing aerosol emissions from a urea granulation plant with a recovery of the resulting scrubber bleeds according to claim 15, wherein the gaseous exhaust from the aerosol stage is fed into an acidic scrubber where the gaseous exhaust is cleaned from dust and fine particles and residual ammonia.

21. The method for reducing aerosol emissions from a urea granulation plant with a recovery of the resulting scrubber bleeds according to claim 15, wherein the operating conditions in the stripping column are set to a temperature of 100 to 180°

C. and a pressure of 2.0 to 9.0 bar.

22. The method for reducing aerosol emissions from a urea granulation plant with a recovery of the resulting scrubber bleeds according to claim 15, wherein the granulator is fed with a concentrated urea solution with a concentration of 90 to 99 mass percent.

23. A device for producing urea granulates comprising:

a granulator for the granulation of urea solution;

a following scrubber for the removal of dust; and

a following aerosol stage for the removal of aerosol with a designed spray systems and collection pads;

wherein

the separated aerosol which consists essentially of ammonium isocyanate is feedable into a isomerisation unit; and

the isomerisation unit consists of a stripping column with an off-take for gases at the head of the column and an off-take for a liquid at the bottom of the column.

24. The device for producing urea granulates according to claim 23, wherein the device comprises a heat exchanger which is installed between the aerosol stage and the stripping column.

25. The device for producing urea granulates according to claim 23, wherein the isomerisation unit is connected to a low pressure steam supply which supplies low pressure steam to the stripping column of the isomerisation unit.

26. The device for producing urea granulates according to claim 23, wherein the device comprises a low pressure carbamate condenser where the gaseous exhaust from the isomerisation unit is collected and residual carbamate is condensed and disposed.