ANTIMICROBIAL COMPOSITION FOR FINISHING TEXTILES

• US 20110065346A1
• Filed: 12/11/2007
• Published: 03/17/2011
• Est. Priority Date: 12/12/2006
• Status: Active Grant

• Current Assignee: Sanitized AG
• Original Assignee: Sanitized AG
• Inventors: Bender, Walter, Marte, Oliver, Marte, Walter
• Granted Patent: US 8,865,605 B2
• Time in Patent Office: Days
• US Class Current: 442/123
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 55/00 Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing organo-phosphorus compounds A01N57/00
• CPC Class Codes: C08K 5/0058 Biocides; macromolecular substances as carriers for biocide material A01N25/10
• CPC Class Codes: D06M 11/155 Halides of elements of Groups 2 or 12 of the Periodic Table
• CPC Class Codes: D06M 11/17 Halides of elements of Groups 3 or 13 of the Periodic Table
• CPC Class Codes: D06M 11/20 Halides of elements of Groups 4 or 14 of the Periodic Table, e.g. zirconyl chloride
• CPC Class Codes: D06M 11/28 Halides of elements of Groups 8, 9, 10 or 18 of the Periodic Table
• CPC Class Codes: D06M 15/643 containing silicon in the main chain
• CPC Class Codes: D06M 16/00 Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
• CPC Class Codes: D06M 2101/32 Polyesters
• CPC Class Codes: D06M 2101/34 Polyamides
• CPC Class Codes: Y10T 428/2962 Silane, silicone or siloxane in coating
• CPC Class Codes: Y10T 442/2525 Coating or impregnation functions biologically [e.g., insect repellent, antiseptic, insecticide, bactericide, etc.]

Abstract

An antimicrobial composition comprising an organic antimicrobial component (K) and at least one metal salt component (M) and also, where appropriate, a solvent (L) and further auxiliary components, which comprises as organic component (K) at least one compound of the general formula (I)

• • where the radicals independently have for example the following meanings:
  • R¹ is a branched or unbranched alkyl radical having 1 to 12 carbon atoms,
  • R² is a branched or unbranched alkyl radical having 1 to 12 carbon atoms,
  • R³ is a branched or unbranched alkyl radical having 1 to 12 carbon atoms,
  • R⁴ is a branched or unbranched alkyl radical having 1 to 18 carbon atoms,
  • R⁵ is a branched or unbranched alkyl radical having 1 to 18 carbon atoms,
  • R⁶ is a branched or unbranched alkyl radical having 8 to 18 carbon atoms;
  • n is an integer from 1 to 6,
  • and which comprises as metal salt component (M) at least one salt of a di- to pentavalent metal, is useful for durable finishing of textiles.

Claims

1. A composition comprising an organic antimicrobial component (K), at least one metal salt component (M), optionally a solvent (L) and, optionally auxiliary components, said organic component (K) comprising at least one compound of the general formula (I)

2. The composition as claimed in claim 1, characterized in that it comprises as solvent (L) water and as organic component (K) a compound of the general formula (I), where the radicals independently have the following meanings:

R¹ is an alkyl radical which has 1 to 6 carbon atoms and which may also be substituted by H—

((CH₂)_m—

O)_q, where m may be an integer from 1 to 3 and q is an integer from 1 to 4;

R² is an alkyl radical which has 1 to 6 carbon atoms and which may also be substituted by H—

((CH₂)_m—

O)_q, where m may be an integer from 1 to 3 and q is an integer from 1 to 4;

R³ is an alkyl radical which has 1 to 6 carbon atoms and which may also be substituted by H—

((CH₂)_m—

O)_q, where m may be an integer from 1 to 3 and q is an integer from 1 to 4;

R⁴ is an alkyl radical having 1 to 18 carbon atoms, a cycloalkyl radical having 3 to 7 carbon atoms, a phenyl radical, a benzyl radical optionally substituted by one or two halogen atoms, a pyridine radical, a pyrimidine radical, a pyrazine radical, a pyridazine radical, a pyrrole radical or an imidazole radical;

R⁵ is an alkyl radical having 1 to 18 carbon atoms, a cycloalkyl radical having 3 to 7 carbon atoms, a phenyl radical, a benzyl radical, a pyridine radical, a pyrimidine radical, a pyrazine radical, a pyridazine radical, a pyrrole radical or an imidazole radical;

R⁶ is an alkyl radical having 8 to 18 carbon atoms;

and n is an integer from 1 to 4.

3. The composition as claimed in claim 1, characterized in that it comprises as organic component (K) a quaternary ammonium compound of the general formula (I), where the radicals independently have the following meanings:

R¹, R² and R³ are each an alkyl radical which has 1 to 6 carbon atoms and which may also be substituted by H—

((CH₂)_m—

O)_q, where m may be an integer from 1 to 3 and q is an integer from 1 to 4;

R⁴ is an alkyl radical having 1 to 18 carbon atoms, a phenyl radical or a benzyl radical,

R⁵ is an alkyl radical having 1 to 18 carbon atoms;

R⁶ is an alkyl radical having 8 to 18 carbon atoms;

and n is an integer from 2 to 4.

4. The composition as claimed in claim 3, characterized in that it comprises as organic component (K) a quaternary ammonium compound of the general formula (I), where

R¹, R² and R³ are the same and are each a branched or unbranched alkyl radical having 1 to 4 carbon atoms,

n is an integer from 1 to 4

R⁴ is methyl,

R⁵ is alkyl having 1 to 12 carbon atoms, and

R⁶ is alkyl having 8 to 18 carbon atoms.

5. The composition as claimed in claim 1, characterized in that it comprises as metal salt component (M) at least one salt of a divalent, trivalent or tetravalent metal.

6. The composition as claimed in claim 5, characterized in that it comprises as metal salt component (M) at least one salt of a divalent, trivalent or tetravalent metal from the group consisting of Mg, Ca, Ba, Zn, Sn;

Al, Ga, Fe; and

Ti.

7. The composition as claimed in claim 6, characterized in that it comprises as metal salt component (M) a salt of a divalent metal from the group consisting of Mg, Ca, Ba, Zn and/or a salt of a trivalent metal from the group consisting of Al and Fe.

8. The composition as claimed in claim 1, characterized in that it comprises as organic component (K) of the general formula (I) a dimethyltetradecyl-(3-(trimethoxysilyl)-propyl)ammonium salt or a dimethyloctadecyl-(3(trimethoxysilyl)propyl)ammonium salt and as metal salt component (M) a salt of a divalent metal from the group consisting of Mg, Ca, Zn, Ba and/or a salt of a trivalent metal from the group consisting of Al and Fe.

9. The composition as claimed in any claim 1, characterized in that it represents an aqueous solution comprising 0.01% to 10% by weight, of the organic component (K) and 0.01% to 10% by weight of the metal salt component (M) and also 0% to 50% by weight of an organic solvent

10. The composition as claimed in claim 9, characterized in that it comprises 0.3% to 2.5% by weight of the organic component (K) and 0.2% to 2.0% by weight of the metal salt component (M), 70% to 99.5% by weight of the solvent water and also 0.1% to 30% by weight of auxiliary components.

11. The composition as claimed in claim 1, characterized in that it comprises as solvent water and also, optionally, an alcohol and optionally an auxiliary component, selected from the group consisting of pH buffers, softeners, hydrophobicizers, oleophobicizers, binders, crosslinkers, flame retardants, textile dyes, sewability improvers, soil repellents and combinations thereof.

12. The use of a composition as claimed in claim 1 for antimicrobial and/or antiviral finishing of textiles, fibers and yarns.

16. Textiles, fibers and yarns finished with an antimicrobial and/or antiviral composition as claimed in claim 1.

17. Textiles, fibers and yarns finished with an antimicrobial composition as claimed in claim 1.

18. A process for antimicrobial and/or antiviral finishing of textiles, fibers and yarns, which comprises applying to a textile, fiber or yarn at least one organic antimicrobial component (K) of the general formula (I) as set forth in claim 1 and at least one metal salt component (M) as set forth in claim 1, optionally a solvent (L) and, optionally an auxiliary component at the same time or at different times.

19. A process as claimed in claim 18, wherein the textile, fiber or yarn comprises a polyamide or a polyester.

20. A process as claimed in claim 18, wherein the application step is a padding process, a foam application, a spray process, a coating process, or an exhaust method.

13-15. -15. (canceled)