SWOLLEN SILICONE COMPOSITION, PROCESS OF PRODUCING SAME AND PRODUCTS THEREOF
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Abstract
There is provided herein, in one specific embodiment, silicone composition(s) comprising unique combination(s) of silicone polymer and alkyltrisiloxane(s) which can produce silicone composition(s) with lower solids content than silicone compositions that use other than alkyltrisiloxane(s); while still maintaining a desirable viscosity.
76 Citations
90 Claims
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1-46. -46. (canceled)
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47. A first silicone composition comprising:
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a) a reaction product which is formed by at least one of the self-reaction of a silicone containing at least one silyl hydride moiety and at least one monovalent unsaturated hydrocarbon radical containing from 2 to 10 carbon atoms;
the reaction of an organohydrogenpolysiloxane and an olefinically unsaturated polysiloxane and/or an alkenyl resin;
addition product of silane functional silicones;
a silicone condensation product of at least one silicone and one of the following;
amino resin formed from urea monomer or melamine monomer and formaldehyde monomer, furan polymer produced by polymerizing furfuryl alcohol monomer, polyacetal polymer formed from diaklehyde monomer and dialcohol monomer, poly(alkylene sulfide) polymers formed from alkyl bromide monomer and potassium sulfide monomer, polyimide polymer formed from diacid monomer and diamine monomer, polyamine formed from diamine monomer and dihalide monomer, polyaminotriazole polymer formed from dihydride monomer and hydrazine monomer, polyanhydride formed from polymerization of diacid monomer, polycarbonate formed from diol monomer and phosgene monomer, polyhydrazide polymer formed from phenyl diester monomer and dihydrazine monomer, polyimide formed from tetraacid monomer and diamine monomer polyquinoxaline polymer formed from tetracarbonyl monomer and diamine monomer polysaccharide formed from polymerization of monosaccharide monomer polysulfide polymer formed from dihalide monomer and polysulfide monomer, polyurea (brined from diamine monomer and phosgene monomer protein polymer formed from polymerization of amino acid monomer, silicone formed from dihaloalkylsilane monomer and water, polyester formed from difunctional acid monomer and difunctional alcohol monomer;
step reaction polymerization of diisocyanato monomers and polyol monomers, as well as step reaction polymerization of the condensation polymerizations, and combinations thereof;
where the reaction product (a) does not result in a polymer containing a polyether crosslink; and
,b) a swelling amount of an ethyltrisiloxane wherein said reaction product (a) is swollen by said ethyltrisiloxane to form a first silicone composition and wherein said first silicone composition possesses a lower solids content than a solids content present in a second silicone composition comprising said reaction product (a) and a linear silicone fluid other than said ethyltrisiloxane, whereby second silicone composition and first silicone composition have equivalent viscosities. - View Dependent Claims (48, 49, 50, 51, 54, 64, 65, 66, 67, 68, 69, 90)
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52-53. -53. (canceled)
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55-62. -62. (canceled)
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63. A first silicone composition comprising:
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a) a reaction product which is formed by at least one of the self-reaction of a silicone containing at least one silyl hydride moiety and at least one monovalent unsaturated hydrocarbon radical containing from 2 to 10 carbon atoms;
the reaction of an organohydrogenpolysiloxane and an olefinically unsaturated polysiloxane and/or an alkenyl resin;
addition product of silane functional silicones;
a silicone condensation product of at least one silicone and one of the following;
amino resin formed from urea monomer or melamine monomer and formaldehyde monomer, furan polymer produced by polymerizing furfuryl alcohol monomer, polyacetal polymer formed from dialdehyde monomer and dialcohol monomer, poly(alkylene sulfide) polymers formed from alkyl bromide monomer and potassium sulfide monomer, polyamide polymer formed from diacid monomer and diamine monomer, polyamine formed from diamine monomer and dihalide monomer, polyaminotriazole polymer formed from dihydride monomer and hydrazine monomer, polyanhydride formed from polymerization of diacid monomer, polycarbonate formed from diol monomer and phosgene monomer, polyhydrazide polymer formed from phenyl (nester monomer and dihydrazine monomer, polyimide formed from tetraacid monomer and diamine monomer, polyquinoxaline polymer formed from tetracarbonyl monomer and diamine monomer, polysaccharide formed from polymerization of monosaccharide monomer, polysulfide polymer formed from dihalide monomer and polysulfide monomer, polyurea formed from diamine monomer and phosgene monomer, protein polymer formed from polymerization of amino acid monomer, silicone formed from dihaloalkylsilane monomer and water, polyester formed from difunctional acid monomer and difunctional alcohol monomer;
step reaction polymerization of diisocyanato monomers and polyol monomers, as well as step reaction polymerization of the condensation polymerizations, and combinations thereof;
where the reaction product (a) does not result in a polymer containing a polyether crosslink; and
,b) a swelling amount of an ethyltrisiloxane wherein said reaction product (a) is swollen by said ethyltrisiloxane to form a first silicone composition and wherein said first silicone composition possesses a lower solids content than a solids content present in a second silicone composition comprising said reaction product (a) and a linear silicone fluid other than said ethyltrisiloxane, whereby second silicone composition and first silicone composition have equivalent viscosities, wherein the ethyltrisiloxane is selected from the group consisting of 1,1,1,3,5,5,5-heptamethyl-3-ethyltrisiloxane;
1,5-diethyl-1,1,3,3,5,5-hexamethyltrisiloxane;
3,3-diethyl-1,1,5,5,5-hexamethyltrisiloxane;
1-ethyl-1,1,3,3,5,5,5-heptamethyltrisiloxane;
1,1,1,5,5,5-hexaethyl-3,3-dimethyltrisiloxane; and
combinations thereof.
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70. A process for producing a first silicone composition comprising:
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combining (a) a reaction product which is formed by at least one of the self-reaction of a silicone containing at least one silyl hydride moiety and at least one monovalent unsaturated hydrocarbon radical containing from 2 to 10 carbon atoms;
the reaction of an organohydrogenpolysiloxane and an olefinically unsaturated polysiloxane and/or an alkenyl resin;
addition product of silane functional silicones;
a silicone condensation product of at least one silicone and one of the following;
amino resin formed from urea monomer or melamine monomer and formaldehyde monomer, furan polymer produced by polymerizing furfuryl alcohol monomer, polyacetal polymer formed from dialdehyde monomer and dialcohol monomer, poly(alkylene sulfide) polymers formed from alkyl bromide monomer and potassium sulfide monomer, polyamide polymer formed from diacid monomer and diamine monomer polyamine formed from diamine monomer and dihalide monomer, polyaminotriazole polymer formed from dihydride monomer and hydrazine monomer, polyanhydride formed from polymerization of diacid monomer, polycarbonate formed from diol monomer and phosgene monomer, polyhydrazide polymer formed from phenyl diester monomer and dihydrazine monomer, polyimide formed from tetraacid monomer and diamine monomer, polyquinoxaline polymer formed from tetracarbonyl monomer and diamine monomer, polysaccharide formed from polymerization of monosaccharide monomer polysulfide polymer formed from dihalide monomer and polysulfide monomer, polyurea formed from diamine monomer and phosgene monomer, protein polymer formed from polymerization of amino acid monomer, silicone formed from dihaloalkylsilane monomer and water, polyester formed from difunctional acid monomer and difunctional alcohol monomer;
step reaction polymerization of diisocyanato monomers and polyol monomers, as well as step reaction polymerization of the condensation polymerizations, and combinations thereof;
where the reaction product (a) does not result in a polymer containing a polyether crosslink; and
,b) a swelling amount of an ethyl trisiloxane;
wherein said reaction product (a) is swollen by said ethyltrisiloxane to form a first silicone composition and wherein said first silicone composition possesses a lower solids content than a solids content present in a second silicone composition comprising said reaction product (a) and a linear silicone fluid other than said ethyltrisiloxane, whereby second silicone composition and first silicone composition have equivalent viscosities. - View Dependent Claims (71, 72, 73, 74, 77, 86, 87, 88, 89)
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75-76. -76. (canceled)
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78-85. -85. (canceled)
Specification