Method of Operating a Furnace

• US 20110113993A1
• Filed: 11/19/2009
• Published: 05/19/2011
• Est. Priority Date: 11/19/2009
• Status: Active Grant

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Esmaili, Ali, Li, Xianming Jimmy, Smith, Oliver J. IV, Licht, William Robert
• Granted Patent: US 8,219,247 B2
• Time in Patent Office: Days
• US Class Current: 110/186
• CPC Class Codes: B01J 12/007 in the presence of catalytically active bodies, e.g. porous plates
• CPC Class Codes: B01J 19/0006 Controlling or regulating processes controlling or regulating in general G05
• CPC Class Codes: B01J 19/242 in series
• CPC Class Codes: B01J 2208/00026 Controlling or regulating the heat exchange system
• CPC Class Codes: B01J 2208/00061 of the reactants
• CPC Class Codes: B01J 2208/00504 by means of a burner
• CPC Class Codes: B01J 2219/00054 Controlling or regulating the heat exchange system
• CPC Class Codes: B01J 2219/00063 of the reactants
• CPC Class Codes: B01J 2219/00157 by means of a burner
• CPC Class Codes: B01J 2219/00162 controlling the pressure
• CPC Class Codes: B01J 2219/00198 at the reactor inlet
• CPC Class Codes: B01J 2219/002 inside the reactor
• CPC Class Codes: B01J 2219/00216 Parameter value calculated by equations
• CPC Class Codes: B01J 2219/00231 at the reactor inlet
• CPC Class Codes: B01J 8/001 Controlling catalytic processes B01J8/1809 takes precedence
• CPC Class Codes: B01J 8/062 being installed in a furnace
• CPC Class Codes: F23N 1/002 using electronic means F23N1/04 - F23N1/10 take precedence
• CPC Class Codes: F23N 2225/08 temperature
• CPC Class Codes: F23N 2229/20 Camera viewing
• CPC Class Codes: F23N 2237/02 two or more burners
• CPC Class Codes: F23N 5/082 : using electronic means
• CPC Class Codes: Y10T 436/207497 : Molecular oxygen
• CPC Class Codes: Y10T 436/218 : Total hydrocarbon, flammability, combustibility [e.g., air-fuel mixture, etc.]

Abstract

A method of operating a furnace having process tubes and multiple burners where it is desired to conform the temperatures of the process tubes to selected target temperature criterion. The present method provides a systematic and quantitative approach to determine how to adjust burner flow rates to result in desired tube wall temperatures, for example to minimize the temperature deviation between tube wall temperatures at a predetermined elevation in the furnace.

Claims

1. A method of operating a furnace having a plurality of burners, each of the plurality of burners having flow rates associated therewith, the furnace containing a plurality of process tubes, the method comprising:

(a) selecting target temperature criterion for the plurality of process tubes;

(b) measuring first temperature information comprising data for each of the plurality of process tubes at a first operating condition wherein the first temperature information for the plurality of process tubes is measured by;

capturing a first plurality of images of an interior area of the reformer furnace, at least some images of the first plurality of images being associated with different portions of the interior area of the reformer furnace, wherein each image of the first plurality of images comprises first pixel data associated with a portion of the plurality of process tubes; and

processing a portion of the first pixel data to obtain the first temperature information for the plurality of process tubes;

(c) providing an estimate of a mathematical function characterizing a relationship between burner flow rate changes for two or more of the plurality of burners and individual temperature changes for at least a portion of the plurality of process tubes;

(d) calculating a first target flow rate solution set having solutions for the two or more of the plurality of burners consistent with conforming temperatures of the plurality of process tubes to the target temperature criterion for the plurality of process tubes using the estimate of the mathematical function and the first temperature information for the plurality of process tubes; and

(e) adjusting a first valve upstream of at least one of the two or more of the plurality of burners to change at least one of the flow rates of the two or more of the plurality of burners in accordance with the first target flow rate solution set wherein the first valve is not upstream of all burners of the furnace.

2. The method of claim 1 further comprising:

measuring second temperature information for the plurality of process tubes at a second operating condition different from the first operating condition; and

wherein the estimate of the mathematical function provided in step (c) is calculated using the first temperature information and the second temperature information.

3. The method of claim 2 wherein the second temperature information for the plurality of process tubes is measured by:

capturing a second plurality of images of the interior area of the reformer furnace, at least some images of the second plurality of images being associated with different portions of the interior area of the reformer furnace, wherein each image of the second plurality of images comprises second pixel data associated with a portion of the plurality of process tubes; and

processing a portion of the second pixel data to obtain the second temperature information for the plurality of process tubes.

4. The method of claim 3 wherein the first temperature information includes

uncertainty values and the second temperature information includes uncertainty values;

and

wherein the estimate of the mathematical function and/or the updated estimate of the mathematical function are calculated using the uncertainty values of the first temperature information and the uncertainty values of the second temperature information.

5. The method of claim 1 further comprising:

measuring second temperature information for the plurality of process tubes at a second operating condition different from the first operating condition and subsequent to the first operating condition;

calculating a second target flow rate solution set having solutions for the two or more of the plurality of burners consistent with conforming temperatures of the plurality of process tubes to the target temperature limitations using the estimate or an updated estimate of the mathematical function and using the second temperature information for the plurality of process tubes; and

adjusting the first valve or a second valve upstream of at least one of the two or more of the plurality of burners to change at least one of the flow rates of the two or more of the plurality of burners in accordance with the second target flow rate solution set wherein the second valve is not upstream of all burners of the reformer furnace.

6. The method of claim 5 wherein the second operating condition results from step (e).

7. The method of claim 5 further comprising:

updating the estimate of the mathematical function from the second temperature information for the plurality of process tubes thereby forming the updated estimate of the mathematical function; and

wherein the step of calculating the second target flow rate solution set uses the updated estimate of the mathematical function.

8. The method of claim 1 wherein the estimate of the mathematical function comprises calculated values from functional elements wherein each of the functional elements comprise a functional form comprising a first functional parameter, a second functional parameter and a geometric parameter characterizing distances between each of the plurality of process tubes and each of the plurality of burners;

wherein the first functional parameter of a first functional element of the functional elements has the same value as the first functional parameter of a second functional element of the functional elements; and

wherein the second functional parameter of a first functional element of the functional elements has the same value as the second functional parameter of a second functional element of the functional elements.

9. The method of claim 8 wherein the first functional parameter has a value that is the same for each of the functional elements and wherein the second functional parameter has a value that is the same for each of the functional elements.

10. The method of claim 1 wherein the plurality of burners comprises two or more rows of burners and wherein the first valve is upstream of a first row of burners, the method further comprising:

measuring second temperature information for the plurality of process tubes at a second operating condition different from the first operating condition and subsequent to the first operating condition;

calculating a second target flow rate solution set having solutions for the two or more of the plurality of burners consistent with conforming temperatures of the plurality of process tubes to the target temperature limitations using the estimate or an updated estimate of the mathematical function and using the second temperature information for the plurality of process tubes; and

adjusting a second valve upstream of a single burner of the two or more of the plurality of burners to change at least one of the flow rates of the single burner in accordance with the second target flow rate solution set wherein the second valve is not upstream of any burner other than the single burner.

11. The method of claim 1 wherein the first valve is upstream of a lone first burner of the two or more of the plurality of burners, the method further comprising:

measuring second temperature information for the plurality of process tubes at a second operating condition wherein the second operating condition results from step (e);

adjusting a second valve in accordance with the first target flow rate solution set wherein the second valve is upstream of a lone second burner of the two or more of the plurality of burners;

measuring third temperature information for the plurality of process tubes at a third operating condition wherein the third operating condition results from adjusting the second valve in accordance with the first target flow rate solution set;

updating the estimate of the mathematical function from the second temperature information and the third temperature information thereby forming the updated estimate of the mathematical function;

calculating a second target flow rate solution set having solutions for the two or more of the plurality of burners consistent with conforming temperatures of the plurality of process tubes to the target temperature limitations using the updated estimate of the mathematical function; and

adjusting at least one of the first valve, the second valve or a third valve upstream of the two or more of the plurality of burners to change at least one of the flow rates of the of the two or more of the plurality of burner in accordance with the second target flow rate solution set wherein the third valve is not upstream of all burners in the reformer furnace.

12. The method of claim 1 wherein the estimate of the mathematical function is represented as

Δ

T=GΔ

u

where Δ

T represents the individual temperature changes for the at least a portion of the plurality of process tubes, Δ

u represents burner flow rate changes for the two or more of the plurality of burners and G is a gain matrix.