HYDRATE FORMATION FOR GAS SEPARATION OR TRANSPORT

• US 20110123432A1
• Filed: 02/08/2011
• Published: 05/26/2011
• Est. Priority Date: 12/30/1999
• Status: Abandoned Application

• Current Assignee: Marathon Oil Company (Marathon Oil Corporation)
• Original Assignee: Marathon Oil Company (Marathon Oil Corporation)
• Inventors: Waycuilis, John J.
• Application Number:
  US13/023,472
• Publication Number:
  US 20110123432A1
• Time in Patent Office: Days
• US Class Current: 423/648.1
• CPC Class Codes: B01D 2256/16 Hydrogen
• CPC Class Codes: B01D 2256/20 Carbon monoxide
• CPC Class Codes: B01D 2256/24 Hydrocarbons
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2259/80 Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
• CPC Class Codes: B01D 53/14 by absorption
• CPC Class Codes: Y02E 60/34 Hydrogen distribution

Abstract

A gas separation or gas transportation process forms a gas hydrate from an aqueous feed and a gas feed having a hydrate P-T stability envelope. While in the presence of the aqueous feed, the gas feed is initially pressurized to an operating pressure and cooled to an operating temperature which are inside the hydrate P-T stability envelope to form a gas hydrate from at least a portion of the gas feed and at least a portion of the aqueous feed. The resulting gas hydrate is readily separable from any remaining gas and stable for transport.

Claims

1. A gas separation process comprising:

entraining a solid particle medium in a fluidizable mixture to form a fluidized mixture, wherein said fluidizable mixture includes an aqueous liquid feed and a gas mixture feed including a first gas having a first hydrate P-T stability envelope and a second gas having a second hydrate P-T stability envelope different from said first hydrate P-T stability envelope;

conveying said fluidized mixture past a heat transfer surface while contacting said fluidized mixture with said heat transfer surface, wherein said heat transfer surface is cooler than said fluidized mixture;

cooling said fluidized mixture upon contact with said heat transfer surface to an operating temperature at an operating pressure, wherein said operating pressure and operating temperature are outside said first hydrate P-T stability envelope and inside said second hydrate P-T stability envelope;

converting at least a portion of said second gas and at least a portion of said aqueous liquid feed to a plurality of gas hydrate particles;

forming a gas hydrate slurry comprising said plurality of gas hydrate particles and a portion of said aqueous liquid feed; and

separating said gas hydrate slurry from said first gas.

2. The gas separation process of claim 1 further comprising heating said gas hydrate slurry after separating said gas hydrate slurry from said first gas to decompose said gas hydrate particles and produce a decomposition quantity of said second gas and said portion of said aqueous liquid feed.

3. The gas separation process of claim 1 further comprising recovering said first gas separated from said gas hydrate slurry to provide a first recovered quantity of said first gas as a purified gas product.

4. The gas separation process of claim 3, wherein said gas mixture feed is a first gas mixture feed and wherein said first recovered quantity is present in a second gas mixture feed with an unreacted portion of said second gas from said first gas mixture feed, said process further comprising repeating the steps of claim 1 on said second gas mixture feed.

5. The gas separation process of claim 4 further comprising recovering said first gas separated from said gas hydrate slurry in the repeating steps of claim 4 to provide a second recovered quantity of said first gas more concentrated than said first recovered quantity.

6. The gas separation process of claim 5, wherein said second recovered quantity is a purified gas product.

7. The gas separation process of claim 1 further comprising placing said gas hydrate slurry in heat transfer communication with said fluidized mixture to absorb latent heat of hydrate formation.

8. The gas separation process of claim 1 further comprising placing said gas hydrate slurry in heat transfer communication with said fluidized mixture to decompose said gas hydrate particles in said gas hydrate slurry.

9. The gas separation process of claim 1, wherein said solid particle medium is essentially inert in the presence of said fluidizable mixture.

20. The gas separation process of claim 19, wherein said gas mixture feed is a first gas mixture feed and wherein said first recovered quantity is present in a second gas mixture feed with an unreacted portion of said second gas from said first gas mixture feed, said process further comprising repeating the steps of claim 1 on said second gas mixture feed.

21. The gas separation process of claim 20 further comprising recovering said first gas separated from said gas hydrate particles in the repeating steps of claim 1 to provide a second recovered quantity of said first gas more concentrated than said first recovered quantity.

22. The gas separation process of claim 21, wherein said second recovered quantity is a purified gas product.

10. A gas separation process comprising:

fluidizing a solid particle medium, water, a first gas having a first hydrate P-T stability envelope and a second gas having a second hydrate P-T stability envelope different from said first hydrate P-T stability envelope to form a fluidized bed comprising said solid particle medium, said water, said first gas and said second gas;

cooling said first gas and said second gas to an operating temperature at an operating pressure, wherein said operating pressure and said operating temperature are outside said first hydrate P-T stability envelope and inside said second hydrate P-T stability envelope;

converting at least a portion of said second gas and at least a portion of said water to gas hydrate particles; and

separating said gas hydrate particles from said first gas.

11. The gas separation process of claim 10 further comprising heating said gas hydrate particles after separating said gas hydrate particles from said first gas to decompose said gas hydrate particles and produce a decomposition quantity of said second gas and said portion of said water.

12. The gas separation process of claim 10 further comprising recovering said first gas separated from said gas hydrate particles to provide a first recovered quantity of said first gas as a purified gas product.

13. The gas separation process of claim 12 further comprising recycling said first recovered quantity to said fluidized bed.

14. The gas separation process of claim 10 further comprising placing said gas hydrate particles in heat transfer communication with said fluidized mixture to absorb latent heat of hydrate formation.

15. The gas separation process of claim 10 further comprising placing said gas hydrate particles in heat transfer communication with said fluidized mixture to decompose said gas hydrate particles.

16. The gas separation process of claim 10, wherein said solid particle medium is essentially inert in the presence of said first gas and said second gas.

17. A gas separation process comprising:

entraining a solid particle medium in a fluidizable mixture to form a fluidized mixture, wherein said fluidizable mixture includes water, a first gas having a first hydrate P-T stability envelope and a second gas having a second hydrate P-T stability envelope different from said first hydrate P-T stability envelope;

conveying said fluidized mixture past a heat transfer surface while contacting said fluidized mixture with said heat transfer surface, wherein said heat transfer surface is cooler than said fluidized mixture;

cooling said fluidized mixture upon contact with said heat transfer surface to an operating temperature at an operating pressure, wherein said operating pressure and operating temperature are outside said first hydrate P-T stability envelope and inside said second hydrate P-T stability envelope;

converting at least a portion of said second gas and at least a portion of said water to gas hydrate particles; and

separating said gas hydrate particles from said first gas.

18. The gas separation process of claim 17 further comprising heating said gas hydrate particles after separating said gas hydrate particles from said first gas to decompose said gas hydrate particles and produce a decomposition quantity of said second gas and said portion of said water.

19. The gas separation process of claim 17 further comprising recovering said first gas separated from said gas hydrate particles to provide a first recovered quantity of said first gas as a purified gas product.

23. The gas separation process of claim 17 further comprising placing said gas hydrate particles in heat transfer communication with said fluidized mixture to absorb latent heat of hydrate formation.

24. The gas separation process of claim 17 further comprising placing said gas hydrate slurry in heat transfer communication with said fluidized mixture to decompose said gas hydrate particles.

25. The gas separation process of claim 17, wherein said solid particle medium is essentially inert in the presence of said fluidizable mixture.