Classified Catalyst Composition, Apparatus, and Method

• US 20110137003A1
• Filed: 04/30/2009
• Published: 06/09/2011
• Est. Priority Date: 08/19/2008
• Status: Active Grant

• Current Assignee: Dow Global Technologies LLC (Dow, Inc.)
• Original Assignee: Dow Global Technologies LLC (Dow, Inc.)
• Inventors: Gobbi, Gian C., Gallagher, Gina R., Robinson, Donald G. JR., Collins, Raymond M.
• Granted Patent: US 8,314,191 B2
• Time in Patent Office: Days
• US Class Current: 526/351
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 110/06 Propene
• CPC Class Codes: C08F 2/01 characterised by special features of the polymerisation apparatus used
• CPC Class Codes: C08F 2/34 Polymerisation in gaseous state
• CPC Class Codes: C08F 2500/24 Polymer with special particle form or size
• CPC Class Codes: C08F 4/654 with magnesium or compounds thereof

Abstract

The present disclosure is directed to an apparatus and process for producing a catalyst composition and a low-fines catalyst composition in particular. A crossflow classification device is used to separate large catalyst particles from catalyst fines, A slurry of a catalyst composition is introduced into the crossflow classification device. A classified catalyst composition is retrieved from a retentate produced as a result of subjecting the catalyst slurry to a crossflow classification process. The solids content of the pre-classified and/or post-classified catalyst slurry is determined by way of NMR spectroscopy. The solids content determination accounts for migration of wash liquid from the catalyst composition and into the slurry liquid phase, The classified catalyst composition has a low-fines content and produces a polyolefin composition with a low polymer fines content.

Claims

1. A process for producing a classified catalyst composition comprising:

introducing a slurry composed of a catalyst composition comprising catalyst particles and catalyst fines into a crossflow classification device;

removing the catalyst fines from the slurry to form a retentate; and

recovering, from the retentate, a classified catalyst composition.

2. The process of claim 1 comprising recovering a classified catalyst composition having an F10.5 value less than 1 weight %.

3. The process of claim 1 wherein the catalyst composition has an F10.5 value greater than 1 weight %, the process comprising recovering a classified catalyst composition having an F10.5 value from about 0.1 weight % to less than 1 weight %.

4. The process of claim 1 comprising polishing the catalyst particles.

5. The process of claim 1 comprising a crossflow filter device with a crossflow filter element, the process comprising moving the slurry at a tangential velocity from 0.2 m/second to 2.0 m/second along the crossflow filter element.

6. The process of claim 1 comprising a crossflow filter device with a crossflow filter element, the process comprising passing the slurry through a valveless pump.

7. The process of claim 1 comprising a crossflow filter device having a crossflow filter element, the process comprising passing the catalyst fines through the crossflow filter element.

8. The process of claim 1 comprising a dynamic filter device having a dynamic filter element, the process comprising moving the dynamic filter element;

and generating a relative tangential velocity from about 0.1 m/second to 10.0 m/second between the dynamic filter element and the slurry.

9. The process of claim 1 comprising a dynamic filter device having a dynamic filter element, the process comprising passing catalyst fines through the dynamic filter element.

10. A polymerization process comprising:

crossflow classifying a slurry of a catalyst composition to form a retentate;

recovering a classified catalyst composition from the retentate;

contacting the classified catalyst composition with an olefin under polymerization conditions; and

forming a polyolefin composition.

11. The polymerization process of claim 10 comprising recovering a classified catalyst composition having an F10.5 value less than 1 weight %.

12. The polymerization process of claim 10 comprising combining the classified catalyst composition with a member selected from the group consisting of a cocatalyst, a selectivity control agent, and combinations thereof.

13. The polymerization process of claim 10 comprising forming a polyolefin composition having an F250 value from about 0.1 weight % to about 2 weight %.

14. The polymerization process of claim 10 comprising subjecting the slurry to crossflow filtration.

15. The polymerization process of claim 10 comprising subjecting the slurry to dynamic filtration.

16. An apparatus comprising:

a crossflow classification device adapted to receive a slurry of a catalyst composition and retain a classified catalyst composition; and

a polymerization reactor adapted to receive the classified catalyst composition and an olefin and form a polyolefin.

17. The apparatus of claim 16 wherein the crossflow classification device is selected from the group consisting of a dynamic filtration device and a crossflow filtration device.

18. The apparatus of claim 16 comprising a dynamic filtration device having a dynamic filter element selected from the group consisting of a rotating dynamic filter element, an oscillating dynamic filter element, and a reciprocating dynamic filter element.

19. The apparatus of claim 16 wherein the polymerization reactor is a fluidized bed polymerization reactor.

20. The apparatus of claim 16 wherein the catalyst composition is selected from the group consisting of a Ziegler-Natta catalyst composition, a constrained-geometry catalyst composition, a metallocene catalyst composition, and combinations thereof.

21-26. -26. (canceled)