DESULFURIZATION OF, AND REMOVAL OF CARBON DIOXIDE FROM, GAS MIXTURES

• US 20110150733A1
• Filed: 10/29/2010
• Published: 06/23/2011
• Est. Priority Date: 12/17/2009
• Status: Active Grant

• Current Assignee: General Electric Technology GmbH (GE Aerospace)
• Original Assignee: Alstom Technology Ltd. (Alstom SA)
• Inventors: Muraskin, David James, Dube, Sanjay Kumar
• Granted Patent: US 8,293,200 B2
• Time in Patent Office: Days
• US Class Current: 423/243.06
• CPC Class Codes: B01D 2251/2062 Ammonia
• CPC Class Codes: B01D 2251/404 of calcium
• CPC Class Codes: B01D 2257/302 Sulfur oxides
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/1456 Removing acid components
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: B01D 53/75 Multi-step processes
• CPC Class Codes: F23J 15/04 using washing fluids scrubbers for removing solids only F23J15/022
• CPC Class Codes: F23J 15/06 of coolers
• CPC Class Codes: F23J 2215/20 Sulfur; Compounds thereof
• CPC Class Codes: F23J 2215/50 Carbon dioxide
• CPC Class Codes: F23J 2217/50 by cleaning fluids (washers or scrubbers)
• CPC Class Codes: F23J 2219/40 Sorption with wet devices, e.g. scrubbers
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02E 20/30 Technologies for a more efficient combustion or heat usage
• CPC Class Codes: Y02E 20/32 Direct CO2 mitigation

Abstract

A method of heating a used absorption liquid resulting from a carbon dioxide absorption stage in which a CO₂ comprising gas stream is contacted with an absorption liquid comprising ammonia, wherein the used absorption liquid is subjected to heat exchange, in a heat exchanger, with a fluid of a desulfurization stage in which a SO₂ comprising flue gas is contacted with a reagent composition comprising an alkaline compound.

Claims

1. A process for desulfurization of, and removal of carbon dioxide from, gas mixtures, comprising the steps of:

(a) contacting in a desulfurization stage a flue gas comprising SO₂ with a scrubbing liquor comprising an alkaline compound and, optionally, with oxidation air, to remove SO₂ from the flue gas;

(b) contacting in a carbon dioxide absorption stage a second gas stream comprising CO₂ with an absorption liquid comprising ammonia, to remove CO₂ from the second gas stream;

(c) subjecting the scrubbing liquid, the flue gas or the oxidation air to heat exchange, in a heat exchanger, with used absorption liquid resulting from step (b), to heat the used absorption liquid; and

(d) regenerating the absorption liquid by releasing CO₂ from the heated used absorption liquid resulting from step (c).

2. The process according to claim 1, wherein in step (c) the scrubbing liquor is subjected to heat exchange, in a heat exchanger, with used absorption liquid resulting from step (b).

3. The process according to claim 2, wherein scrubbing liquor is withdrawn from the desulfurization stage of step (a) and solids formed during step (a) are removed from the withdrawn scrubbing liquid, before the withdrawn scrubbing liquor is subjected to the heat exchange of step (c).

4. The process according to claim 1, wherein in step (c) the flue gas is subjected to heat exchange, in a heat exchanger, with used absorption liquid resulting from step (b).

5. The process according to claim 1, wherein in step (a) the flue gas is contacted with the scrubbing liquor and with the oxidation air.

6. The process according to claim 5, wherein in step (c) the oxidation air is subjected to heat exchange, in a heat exchanger, with used absorption liquid resulting from step (b).

7. The process according to claim 1, wherein in step (b) the gas stream is essentially the SO₂ depleted flue gas resulting from step (a).

8. A system for desulfurization of, and removal of carbon dioxide from, gas mixtures, comprising a desulfurization system comprising

a desulfurization vessel for contacting a flue gas with a scrubbing liquor;

a withdrawal circuit arranged to withdraw scrubbing liquor from the desulfurization vessel,

a gas conduit arranged to supply the flue gas to the desulfurization vessel; and

optionally, an air conduit arranged to supply oxidation air to the desulfurization vessel;

and a carbon dioxide removal system comprising

a CO₂ absorber for contacting a second gas stream with an absorption liquid, the CO₂ absorber having an inlet for absorption liquid and an outlet for used absorption liquid; and

a regenerator for regenerating the absorption liquid by release of CO₂ from used absorption liquid, the regenerator having an inlet for used absorption liquid and an outlet for regenerated absorption liquid,

wherein the outlet for used absorption liquid of the CO₂ absorber and the inlet for used absorption liquid of the regenerator are operatively connected via a heat exchanger, the heat exchanger further being operatively arranged in the desulfurization system.

9. The system according to claim 8, wherein the heat exchanger further being operatively arranged in the desulfurization system is operatively arranged in the desulfurization vessel.

10. The system according to claim 8, wherein the heat exchanger further being operatively arranged in the desulfurization system is operatively arranged in the withdrawal circuit.

11. The system according to claim 8, wherein the heat exchanger further being operatively arranged in the desulfurization system is operatively arranged in the gas conduit.

13. The system according to claim 8, wherein the desulfurization system comprises the air conduit.

14. The system according to claim 13, wherein the heat exchanger further being operatively arranged in the desulfurization system is operatively arranged in the air conduit.

15. A process for desulfurization of, and removal of carbon dioxide from, gas mixtures, comprising the steps of:

(a) preparing a reagent mixture by combining lime and water, to obtain a solution of slaked lime, and mixing the solution of slaked lime with a particulate, to obtain a reagent mixture;

(b) contacting in a desulfurization stage a flue gas comprising SO₂ with the reagent mixture, to remove SO₂ from the flue gas;

(c) contacting in a carbon dioxide absorption stage a gas stream comprising CO₂ with an absorption liquid comprising ammonia, to remove CO₂ from the gas stream;

(d) subjecting the solution of slaked lime or the flue gas to heat exchange, in a heat exchanger, with used absorption liquid resulting from step (c), to heat the used absorption liquid; and

(e) regenerating the absorption liquid by releasing CO₂ from the heated used absorption liquid resulting from step (d).

16. The process according to claim 15, wherein in step (d) the solution of slaked lime is subjected to heat exchange, in a heat exchanger, with used absorption liquid resulting from step (c).

17. The process according to claim 15, wherein in step (d) the flue gas is subjected to heat exchange, in a heat exchanger, with used absorption liquid resulting from step (c).

18. The process according to claim 15, wherein in step (c) the gas stream is essentially the SO₂ depleted flue gas resulting from step (b).

19. A system for desulfurization of, and removal of carbon dioxide from, gas mixtures, comprising a desulfurization system comprising

a slaker adapted for preparation of slaked lime and arranged to receive lime and water;

a feed circuit adapted for storage and supply of slaked lime and arranged to receive slaked lime from the slaker;

a mixer adapted for preparation of a reagent mixture and arranged to receive slaked lime from the feed circuit;

a desulfurization vessel adapted for contacting a flue gas with a reagent mixture and arranged to receive a reagent mixture from the mixer; and

a gas conduit arranged to supply the flue gas to the desulfurization vessel, and a carbon dioxide removal system comprising

a CO₂ absorber for contacting a gas stream with an absorption liquid, the CO₂ absorber having an inlet for absorption liquid and an outlet for used absorption liquid; and

a regenerator for regenerating the absorption liquid by release of CO₂ from used absorption liquid, the regenerator having an inlet for used absorption liquid and an outlet for regenerated absorption liquid,

wherein the outlet for used absorption liquid of the CO₂ absorber and the inlet for used absorption liquid of the regenerator are operatively connected via a heat exchanger, the heat exchanger further being operatively arranged in the desulfurization system.

20. The system according to claim 19, wherein the heat exchanger further being operatively arranged in the desulfurization system is operatively arranged in the feed circuit.

21. The system according to claim 20, wherein the feed circuit comprises a tank and the heat exchanger is operatively arranged in the tank.

22. The system according to claim 19, wherein the heat exchanger further being operatively arranged in the desulfurization system is operatively arranged in the gas conduit.

23. A method of heating a used absorption liquid resulting from a carbon dioxide absorption stage in which a CO₂ comprising gas stream is contacted with an absorption liquid comprising ammonia, wherein the used absorption liquid is subjected to heat exchange, in a heat exchanger, with a fluid of a desulfurization stage in which a SO₂ comprising flue gas is contacted with a reagent composition comprising an alkaline compound.

24. The method according to claim 23, wherein the fluid is a scrubbing liquor comprising an alkaline compound.

25. The method according to claim 24, wherein solids formed during the desulfurization stage are removed from the scrubbing liquor before the scrubbing liquor is subjected to the heat exchange.

26. The method according to claim 23, wherein the fluid is the SO₂ comprising flue gas.

27. The method according to claim 23, wherein the fluid is oxidation air.

28. The method according to claim 23, wherein the fluid is a solution of slaked lime.

29. The process according to claim 23, wherein the CO₂ comprising gas stream is essentially the gas stream resulting from desulfurization of the SO₂ comprising flue gas.