WATER-ABSORBENT RESIN MANUFACTURING METHOD AND LIQUID PERMEABILITY IMPROVEMENT METHOD

• US 20110166300A1
• Filed: 09/11/2009
• Published: 07/07/2011
• Est. Priority Date: 09/16/2008
• Status: Active Grant

• Current Assignee: Nippon Shokubai Company Limited
• Original Assignee: Nippon Shokubai Company Limited
• Inventors: Dairoku, Yorimichi, Kanzaki, Syuji, Matsumoto, Koji, Ishizaki, Kunihiko, Mitsukami, Yoshiro, Nogi, Kozo
• Granted Patent: US 8,436,090 B2
• Time in Patent Office: Days
• US Class Current: 525/384
• CPC Class Codes: C08F 20/06 Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
• CPC Class Codes: C08F 220/06 Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
• CPC Class Codes: C08F 6/003 from polymer solutions, suspensions, dispersions or emulsions without recovery of the polymer therefrom
• CPC Class Codes: C08F 6/02 Neutralisation of the polymerisation mass, e.g. killing the catalyst short-stopping C08F2/42 also removal of catalyst residues
• CPC Class Codes: C08J 2300/14 Water soluble or water swellable polymers, e.g. aqueous gels
• CPC Class Codes: C08J 2333/02 Homopolymers or copolymers of acids; Metal or ammonium salts thereof
• CPC Class Codes: C08J 3/245 Differential crosslinking of one polymer with one crosslinking type, e.g. surface crosslinking
• CPC Class Codes: C08L 33/02 Homopolymers or copolymers of acids; Metal or ammonium salts thereof

Abstract

A method for the production of a water-absorbing resin is to be provided which permits enhancement and stabilization of property, for example, liquid permeability, of a water-absorbing resin by a simple and convenient method without requiring change of raw materials or expensive facility investment. The method comprises a polymerization step for polymerizing an aqueous solution of acrylic acid (or salt thereof) to obtain a hydrogel cross-linked polymer; a drying step for drying the hydrogel cross-linked polymer to obtain a water-absorbing resin powder; a classification step for classifying the water-absorbing resin powder; and a surface cross-linking step for surface cross-linking the water-absorbing resin powder before or after the classification step, wherein electricity is eliminated in the classification step.

Claims

1. A method for the production of a water-absorbing resin which comprises:

a polymerization step for polymerizing an aqueous solution of acrylic acid (or salt thereof) to obtain a hydrogel cross-linked polymer;

a drying step for drying said hydrogel cross-linked polymer to obtain a water-absorbing resin powder;

a classification step for classifying said water-absorbing resin powder; and

a surface cross-linking step for surface cross-linking said water-absorbing resin powder before or after the classification step;

wherein electricity is eliminated in the classification step.

2. The method according to claim 1, wherein the electricity is eliminated by at least one means selected from the group consisting of ionized air flow, antistatic brush and grounding.

3. The method according to claim 1, wherein the electricity is eliminated by grounding wherein earth resistance is equal to or lower than 100Ω

.

4. The method according to claim 1, wherein the classification step is performed under reduced pressure.

5. The method according to claim 1, wherein air flow is passed through the classification step, and dew point of the air flow is equal to or lower than 15°

C.

6. The method according to claim 1, wherein sieve classification is used in the classification step, and a temperature of a sieve to be used in the classification step is 40 to 80°

C.

7. The method according to claim 1, wherein sieves having at least three kinds of sieve mesh sizes are used in the classification step.

8. The method according to claim 1, wherein normal saline flow conductivity (SFC) of the water-absorbing resin subjected to the surface cross-linking step is equal to or higher than 10 (×

10<sup>−

7</sup>·

cm³·

s·

g<sup>−

1</sup>).

9. The method according to claim 1, wherein sieve classification is used in the classification step, and a surface roughness (Rz) of an inner surface of a sieve to be used in the classification step is equal to or smaller than 800 nm.

10. The method according to claim 1, wherein the water-absorbing resin is continuously produced in an amount of equal to or higher than 1 ton per 1 hour.

11. The method according to claim 1, wherein the water-absorbing resin is produced in the shape of an irregular particle by continuous kneader polymerization or continuous belt polymerization.

12. The method according to claim 1, wherein the water content of the water-absorbing resin is equal to or lower than 5% by weight.

13. The method according to claim 1, further comprising an iron removal step after the classification step.

14. The method according to claim 1, wherein the classification step is performed before and after the surface cross-linking step.

15. The method according to claim 1, further comprising a step for recycling fine powder of the water-absorbing resin after the classification step.

16. The method according to claim 1, wherein the water-absorbing resin before and after the classification step is pneumatically transported by air having a dew point of equal to or lower than 20°

C.

17. The method according to claim 1, wherein the electricity is eliminated for at least one of a classification apparatus, the water-absorbing resin and a sieve used in the sieve classification.

18. The method according to claim 1, wherein steps from the polymerization step prior to the classification step is arrayed in one line, and the classification step is divided into two or more lines.

19. The method according to claim 1, wherein the surface cross-linking step is divided into two or more lines per one line of the polymerization step.

20. The method according to claim 1, wherein all of the classification step and the surface cross-linking step are divided in two or more lines per one line of the polymerization step.

21. The method according to claim 1, wherein a covalent surface cross-linking agent and an ion binding surface cross-linking agent are used in combination in the surface cross-linking step.

22. A method for enhancing liquid permeability of a water-absorbing resin which comprises:

a polymerization step for polymerizing an aqueous solution of acrylic acid (or salt thereof) to obtain a hydrogel cross-linked polymer;

a drying step for drying said hydrogel cross-linked polymer to obtain a water-absorbing resin powder;

a classification step for classifying said water-absorbing resin powder; and

a surface cross-linking step for surface cross-linking said water-absorbing resin powder before or after the classification step;

wherein electricity is eliminated in the classification step.

23. The method according to claim 22, wherein normal saline flow conductivity (SFC) of the water-absorbing resin subjected to the surface cross-linking step is equal to or higher than 10 (×

10<sup>−

7</sup>·

cm³·

s·

g<sup>−

1</sup>).