CNT-INFUSED ARAMID FIBER MATERIALS AND PROCESS THEREFOR

• US 20110171469A1
• Filed: 11/02/2010
• Published: 07/14/2011
• Est. Priority Date: 11/02/2009
• Status: Abandoned Application

• Current Assignee: Applied NanoStructured Solutions, LLC (Cabot Corporation)
• Original Assignee: Applied NanoStructured Solutions, LLC (Cabot Corporation)
• Inventors: Malecki, Harry C., Gardner, Slade H., SHAH, Tushar K., Alberding, Mark R.
• Application Number:
  US12/938,328
• Publication Number:
  US 20110171469A1
• Time in Patent Office: Days
• US Class Current: 428/395
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: B82Y 40/00 Manufacture or treatment of nanostructures
• CPC Class Codes: C01B 2202/02 Single-walled nanotubes
• CPC Class Codes: C01B 2202/04 Nanotubes with a specific amount of walls
• CPC Class Codes: C01B 2202/06 Multi-walled nanotubes
• CPC Class Codes: C01B 2202/34 Length
• CPC Class Codes: C01B 32/162 characterised by catalysts
• CPC Class Codes: C01B 32/164 involving continuous processes
• CPC Class Codes: D01F 6/605 from aromatic polyamides
• CPC Class Codes: D01F 9/127 by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
• CPC Class Codes: D06M 11/74 with carbon or graphite; with carbides; with graphitic acids or their salts
• CPC Class Codes: D06M 2101/36 Aromatic polyamides
• CPC Class Codes: D06M 2400/01 Creating covalent bondings between the treating agent and the fibre
• CPC Class Codes: Y10T 428/2969 Polyamide, polyimide or polyester

Abstract

A composition includes a carbon nanotube (CNT)-infused aramid fiber material that includes an aramid fiber material of spoolable dimensions, a barrier coating conformally disposed about the aramid fiber material, and carbon nanotubes (CNTs) infused to the aramid fiber material. The infused CNTs are uniform in length and uniform in density. A continuous CNT infusion process includes:(a) disposing a barrier coating and a carbon nanotube (CNT)-forming catalyst on a surface of an aramid fiber material of spoolable dimensions; and (b) synthesizing carbon nanotubes on the aramid fiber material, thereby forming a carbon nanotube-infused aramid fiber material.

Claims

1. A composition comprising a carbon nanotube (CNT)-infused aramid fiber material comprising an aramid fiber material of spoolable dimensions, a barrier coating conformally disposed about the aramid fiber material and carbon nanotubes (CNTs) infused to the aramid fiber material, wherein said CNTs are uniform in length and uniform in distribution.

2. The composition of claim 1 further comprising transition metal nanoparticles used in the growth of said CNTs.

3. The composition of claim 1, wherein the infusion of CNTs to the aramid fiber material comprises a bonding motif selected from direct bonding of individual CNTs to the aramid fiber, indirect bonding via the transition metal nanoparticle disposed between the CNTs and the aramid fiber, indirect bonding via the transition metal and barrier coating disposed between the CNTs and the aramid fiber, indirect bonding via the barrier coating disposed between the CNTs and aramid fiber, and mixtures thereof.

4. The composition of claim 1, where said CNTs have a length of about 50 nm micron to about 500 microns.

5. The composition of claim 1, wherein said CNTs have a length from about 1 micron to about 10 microns.

6. The composition of claim 1, wherein said CNTs have a length from about 10 microns to about 100 microns.

7. The composition of claim 1, wherein said CNTs have a length from about 100 microns to about 500 microns.

8. The composition of claim 1, wherein said uniformity of distribution is characterized by a density up to about 15,000 nanotubes per micron squared (μ

m²).

9. The composition of claim 1, wherein said aramid fiber material is selected from a carbon filament, an aramid tow, an aramid yarn, an aramid tape, a unidirectional aramid tape, an aramid fiber-braid, a woven aramid fabric, a non-woven aramid fiber mat, and an aramid fiber ply.

10. The composition of claim 1, wherein said CNTs are selected from the group consisting of single-walled CNTs, double-walled CNTs, multi-walled CNTs, and mixtures thereof.

11. The composition of claim 1, wherein said CNTs are multi-walled CNTs.

12. The composition of claim 1 further comprising a sizing agent selected from a surfactant, an anti-static agent, a lubricant, siloxanes, alkoxysilanes, aminosilanes, silanes, silanols, polyvinyl alcohol, starch, and mixtures thereof.

13. The composition of claim 1 further comprising a matrix material selected from an epoxy, a polyester, a vinylester, a polyetherimide, a polyetherketoneketone, a polyphthalamide, a polyetherketone, a polytheretherketone, a polyimide, a phenol-formaldehyde, and a bismaleimide.

14. The composition of claim 1, wherein the electrical resistivity of said carbon nanotube-infused aramid fiber is lower than the electrical resistivity of said aramid fiber.

15. A continuous CNT infusion process comprising:

(a) disposing a barrier coating and a carbon nanotube (CNT)-forming catalyst on a surface of an aramid fiber material of spoolable dimensions; and

(b) synthesizing carbon nanotubes on said aramid fiber material, thereby forming a carbon nanotube-infused aramid fiber material;

wherein said continuous CNT infusion process has a material residence time of between about 5 to about 600 seconds in a CNT growth chamber.

16. The process of claim 15, wherein a material residence time of about 5 to about 120 seconds produces CNTs having a length between about 1 micron to about 10 microns.

17. The process of claim 15, wherein a material residence time of about 120 to about 300 seconds produces CNTs having a length between about 10 microns to about 50 microns.

18. The process of claim 15, wherein a material residence time of about 300 to about 600 seconds produces CNTs having a length between about 50 microns to about 200 microns.

19. The process of claim 15, wherein more than one aramid material is run simultaneously through the process.

20. The process of claim 15 further comprising removing a sizing material from said aramid fiber material before disposing said barrier coating or catalyst on said aramid fiber.

21. The process of claim 15 wherein said CNT-forming catalyst is an iron-based nanoparticle catalyst.

22. The process of claim 15, wherein the operation of disposing said CNT-forming catalyst on said aramid fiber material comprises spraying, dip coating, or gas phase deposition onto said aramid fiber material with said solution.

23. The process of claim 15, wherein the operation of disposing said barrier coating is simultaneous with disposing said CNT-forming catalyst on said aramid fiber material.

24. The process of claim 15, wherein said barrier coating is conformally disposed on said aramid fiber material just prior to disposing said CNT-forming catalyst on said aramid fiber material.

25. The process of claim 24 further comprising partially curing said barrier coating prior to disposing said CNT-forming catalyst on said aramid fiber material.

26. The process of claim 25 further comprising curing the barrier coating after disposing said CNT-forming catalyst on said aramid fiber material.

27. The process of claim 15, wherein the step of synthesizing carbon nanotubes comprises CVD growth.

28. The process of claim 15 further comprising applying sizing to said carbon nanotube-infused aramid fiber material.

29. The process of claim 15 further comprising applying a matrix material to said carbon nanotube-infused aramid fiber.

30. The process of claim 15 further comprising:

a) synthesizing a first amount of a first type of carbon nanotube on said aramid fiber material, wherein said first type of carbon nanotube is selected to alter at least one first property of said aramid fiber material; and

b) synthesizing a second amount of a second type of carbon nanotube on said aramid fiber material, wherein said second type of carbon nanotube is selected to alter at least one second property of said aramid fiber material.

31. The process of claim 30, wherein said first amount and said second amount are different.

32. The process of claim 30, wherein said first amount and said second amount are the same.

33. The process of claim 30, wherein said first type of carbon nanotube and said second type of carbon nanotube are the same.

34. The process of claim 30, wherein said first type of carbon nanotube and said second type of nanotube are different.

35. The process of claim 30, wherein said first property and said second property are the same.

37. The process of claim 30, wherein said at least one first property and at least one second property are independently selected from the group consisting of tensile strength, Young'"'"'s Modulus, shear strength, shear modulus, toughness, compression strength, compression modulus, density, EM wave absorptivity/reflectivity, acoustic transmittance, electrical conductivity, and thermal conductivity.

36. The process of 30, wherein said first property and said second property are different.