Forward Osmosis Separation Processes

• US 20110203994A1
• Filed: 06/22/2009
• Published: 08/25/2011
• Est. Priority Date: 06/20/2008
• Status: Abandoned Application

• Current Assignee: Yale University
• Original Assignee: Yale University
• Inventors: Elimelech, Menachem, McGinnis, Robert L.
• Application Number:
  US13/000,198
• Publication Number:
  US 20110203994A1
• Time in Patent Office: Days
• US Class Current: 210/650
• CPC Class Codes: B01D 61/002 Forward osmosis or direct osmosis
• CPC Class Codes: B01D 61/0022 Apparatus therefor
• CPC Class Codes: B01D 61/0023 Accessories; Auxiliary operations
• CPC Class Codes: B01D 61/005 Osmotic agents; Draw solutions
• CPC Class Codes: C02F 1/001 Processes for the treatment of water whereby the filtration technique is of importance C02F1/44 takes precedence; construction of filters in general B01D24/00 - B01D41/00
• CPC Class Codes: C02F 1/04 by distillation or evaporation
• CPC Class Codes: C02F 1/16 using waste heat from other processes
• CPC Class Codes: C02F 1/38 by centrifugal separation
• CPC Class Codes: C02F 1/445 by forward osmosis
• CPC Class Codes: C02F 1/447 by membrane distillation distillation and evaporation without the use of membranes C02F1/04
• CPC Class Codes: C02F 1/448 by pervaporation
• CPC Class Codes: C02F 2001/007 Processes including a sedimentation step
• CPC Class Codes: C02F 2103/32 from the food or foodstuff industry, e.g. brewery waste waters
• CPC Class Codes: C02F 2103/343 from the pharmaceutical industry, e.g. containing antibiotics
• CPC Class Codes: Y02W 10/33 using wind energy
• CPC Class Codes: Y02W 10/37 using solar energy

Abstract

Separation processes using engineered osmosis are disclosed generally involving the extraction of solvent from a first solution to concentrate solute by using a second concentrated solution to draw the solvent from the first solution across a semi-permeable membrane. One or both of the solute and solvent may be a desired product. Enhanced efficiency may result from using low grade waste heat from industrial or commercial sources.

Claims

1. A forward osmosis separation process, comprising:

introducing a first solution comprising a solvent and at least one target species on a first side of a semi-permeable membrane;

introducing a second solution comprising ammonia and carbon dioxide in a molar ratio of at least 1;

1 on a second side of the semi-permeable membrane, thereby forming an osmotic concentration gradient across the semi-permeable membrane which promotes the flow of at least a portion of the solvent of the first solution across the semi-permeable membrane to form a third solution on the first side of the semi-permeable membrane and a fourth solution on the second side of the semi-permeable membrane;

promoting the flow of at least a portion of the fourth solution to a separation operation to thereby generate draw solutes and a solvent stream;

returning the draw solutes to the second side of the semi-permeable membrane; and

recovering the at least one target species from the third solution.

2. The process of claim 1, wherein the first solution is an aqueous solution.

3. The process of claim 1, wherein the first solution comprises a stream from a pharmaceutical or food grade operation.

4. The process of claim 3, wherein the target species comprises a salt, sugar, enzyme, protein or microorganism.

5. The process of claim 1, wherein introducing the first solution on a first side of the semi-permeable membrane comprises immersing the semi-permeable membrane in the first solution.

6. The process of claim 4, wherein introducing the second solution comprises directing the second solution along the second side of the semi-permeable membrane.

7. The process of claim 1, wherein the first solution is introduced continuously.

8. The process of claim 1, wherein introducing at least a portion of the fourth solution to a separation operation comprises introducing at least a portion of the fourth solution to a distillation column, membrane distillation system or pervaporation system.

9. The process of claim 8, further comprising supplying waste heat to the separation operation.

10. The process of claim 8, further comprising processing the solvent stream.

11. The process of claim 1, wherein recovering the at least one target species comprises introducing the third solution to a settling vessel, hydrocyclone, precipitator, or force gradient operation.

12. The process of claim 11, further comprising introducing the at least one recovered target species to a further treatment unit.

13. The process of claim 12, further comprising supplying the at least one treated target species to a downstream point of use.

14. A forward osmosis waste treatment process, comprising:

introducing a first solution comprising a solvent and at least one constituent on a first side of a semi-permeable membrane;

introducing a concentrated draw solution comprising ammonia and carbon dioxide in a molar ratio of at least 1;

1 on a second side of the semi-permeable membrane to maintain an osmotic concentration gradient across the semi-permeable membrane;

promoting flow of at least a portion of the solvent of the first solution across the semi-permeable membrane to form a second solution on the first side of the semi-permeable membrane and a dilute draw solution on the second side of the semi-permeable membrane;

introducing at least a portion of the dilute draw solution to a separation operation to thereby generate draw solutes and a solvent stream;

returning the draw solutes to the second side of the semi-permeable membrane; and

removing the at least one constituent from the second solution.

15. The process of claim 14, wherein the first solution comprises wastewater.

16. The process of claim 15, wherein the first solution comprises salts, organic matter, suspended colloids or biological organisms.

17. The process of claim 14, wherein introducing the first solution on the first side of the semi-permeable membrane comprises immersing the semi-permeable membrane in the first solution.

18. The process of claim 14, wherein introducing the concentrated draw solution comprises directing the concentrated draw solution along the second side of the semi-permeable membrane.

19. The process of claim 14, wherein the first solution is introduced continuously.

20. The process of claim 14, wherein introducing at least a portion of the dilute draw solution to a separation operation comprises introducing at least a portion of the dilute draw solution to a distillation column, membrane distillation system or pervaporation system.

21. The process of claim 20, further comprising supplying waste heat to the separation operation.

22. The process of claim 14, further comprising processing the solvent stream.

23. The process of claim 14, wherein removing the at least one constituent comprises introducing the second solution to a settling vessel, hydrocyclone or blowdown operation.

24. The process of claim 23, further comprising introducing the at least one constituent to a further treatment operation.

25. A forward osmosis separation process, comprising:

introducing a first solution comprising a solvent and at least one precipitable solute on a first side of a semi-permeable membrane;

introducing a second solution comprising ammonia and carbon dioxide in a molar ratio of at least 1;

1 on a second side of the semi-permeable membrane, thereby forming an osmotic concentration gradient across the semi-permeable membrane that promotes the flow of at least a portion of the solvent of the first solution across the semi-permeable membrane to form a third solution on the first side of the semi-permeable membrane and a fourth solution on the second side of the semi-permeable membrane;

promoting the flow of at least a portion of the fourth solution to a separation operation to thereby generate draw solutes and a solvent stream;

returning the draw solutes to the second side of the semi-permeable membrane; and

recovering the at least one precipitable solute from the third solution.

26. The process of claim 25, wherein the at least one precipitable solute comprises an ionic salt species selected from the group consisting of chloride, sulfate, bromide, silicate, iodide, phosphate, sodium, magnesium, calcium, potassium, nitrate, arsenic, lithium, boron, strontium, molybdenum, manganese, aluminum, cadmium, chromium, cobalt, copper, iron, lead, nickel, selenium, silver, and zinc.