FULLERENE-DOPED NANOSTRUCTURES AND METHODS THEREFOR

• US 20110204319A1
• Filed: 01/21/2011
• Published: 08/25/2011
• Est. Priority Date: 01/25/2010
• Status: Active Grant

• Current Assignee: Board of Trustees of the Leland Stanford Junior University (Stanford Management Co.)
• Original Assignee: Board of Trustees of the Leland Stanford Junior University (Stanford Management Co.)
• Inventors: Lemieux, Melburne C., Virkar, Ajay, Bao, Zhenan
• Granted Patent: US 8,530,271 B2
• Time in Patent Office: Days
• US Class Current: 257/9
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: B82Y 40/00 Manufacture or treatment of nanostructures
• CPC Class Codes: C01B 32/174 Derivatisation; Solubilisation; Dispersion in solvents
• CPC Class Codes: H10K 85/211 Fullerenes, e.g. C60
• CPC Class Codes: H10K 85/221 Carbon nanotubes
• CPC Class Codes: Y02E 10/549 Organic PV cells

Abstract

Nanostructures are doped to set conductivity characteristics. In accordance with various example embodiments, nanostructures such as carbon nanotubes are doped with a halogenated fullerene type of dopant material. In some implementations, the dopant material is deposited from solution or by vapor deposition, and used to dope the nanotubes to increase the thermal and/or electrical conductivity of the nanotubes.

Claims

1. A method for doping a carbon nanotube-based nanostructure, the method comprising:

applying a fullerene-based material to an outer surface of the nanostructure, the fullerene-based material having a Fermi level that is below the Fermi level of the nanostructure;

using the applied fullerene-based material to grow a fullerene-based dopant material on the nanostructure; and

doping the surface of the nanostructure with a dopant from the fullerene-based dopant material to effect a charge transfer from the dopant to the nanostructure and form a hybrid material including a portion of the nanostructure and the dopant, the hybrid material exhibiting a conductivity that is greater than a conductivity of the nanostructure, prior to doping via the fullerene-based dopant material.

2. The method of claim 1, further including, prior to applying the fullerene-based material, preparing the fullerene-based material by combining a fullerene with a non-fullerene-based material to set the Fermi level of the fullerene-based material to a level that is less than a Fermi level of the nanostructure.

3. The method of claim 1, further including, prior to applying the fullerene-based material, preparing the fullerene-based material by combining a fullerene with a halogen-based material to form a halogenated fullerene-based material having a Fermi level that is less than a Fermi level of the nanostructure.

4. The method of claim 1, wherein applying a fullerene-based material includes applying a non-polymeric fullerene-based material having a Fermi level that is at least 0.026 eV below the Fermi level of the nanostructure.

5. The method of claim 1, wherein applying a fullerene-based material includes applying a fullerene-based material having a conduction band that is at least 0.026 eV below the lowest energy level in the conduction band of the nanostructure.

6. The method of claim 1, wherein applying a fullerene-based material includes applying the fullerene-based material to a plurality of nanostructures forming a sheet,

using the applied fullerene-based material to grow a fullerene-based dopant material on the nanostructure includes growing a fullerene-based dopant material on the plurality of nanostructures, and

doping the surface of the nanostructure includes doping the surfaces of the plurality of nanostructures with a dopant from the fullerene-based dopant material to form a hybrid material on each nanostructure, the hybrid material including a portion of the nanostructure and the dopant and exhibiting a conductivity that is greater than a conductivity of the nanostructure, prior to doping via the fullerene-based dopant material, the hybrid material being formed as part of the conductive sheet to configure the sheet to pass at least 90% of light incident thereupon.

7. The method of claim 1, wherein doping the surface of the nanostructure includes reducing the resistance of the nanostructure by at least about 20%.

8. The method of claim 1, wherein applying a fullerene-based material includes applying a halogenated fullerene-based material.

9. The method of claim 1, wherein applying a fullerene-based material includes applying a fluorinated fullerene-based material.

10. The method of claim 1, wherein applying the fullerene-based material includes applying a material selected from the group of C₆₀F₁₈, C₆₀F₂₄, C₆₀F₃₆, C₆₀F₄₄, C₆₀F₄₈ and C₇₀F₅₄.

11. The method of claim 1, wherein

applying the fullerene-based material to the nanostructure includes selecting a thickness of the fullerene-based material to set a transparency of a film including a plurality of the nanostructures, and applying the fullerene-based material to the film of nanostructures at the selected thickness, and

nucleating the fullerene-based material includes nucleating the fullerene-based material at the selected thickness to form a nucleated material on the film and to set the transparency of the film to the set transparency.

12. The method of claim 1, wherein applying a fullerene-based material to a nanostructure includes applying a fullerene-based material to a carbon-based nanostructure.

13. The method of claim 1, wherein doping the nanostructure with the applied material includes reducing a resistance value of the applied material with the dopant, relative to a resistance of the applied material, prior to doping.

14. The method of claim 1, wherein applying a fullerene-based material to the nanostructure includes applying a fullerene-based material to a nanostructure including at least one of a carbon nanotube, a single-walled carbon nanotube, a multi-walled carbon nanotube, a carbon fiber, a semiconducting carbon nanotube, a metallic carbon nanotube, an inorganic nanowire, an organic nanowire, a zinc oxide nanostructure, a silver nanostructure, a gold nanostructure, a silicon nanostructure, graphene and graphene oxide.

15. The method of claim 1, wherein applying a fullerene-based material includes depositing the fullerene-based material on the nanostructure from a solution.

16. The method of claim 1, wherein applying a fullerene-based material includes vapor-depositing the fullerene based material on the nanostructure.

17. The method of claim 1, wherein applying a fullerene-based material to a nanostructure includes applying a fullerene-based material that is selective to the nanostructure, to mitigate application of the fullerene-based material to other materials adjacent the nanostructure.

18. The method of claim 1, wherein the steps of applying and using the fullerene-based material include depositing the fullerene-based material on the nanostructure, upon which the fullerene-based material nucleates and grows to form the nucleated fullerene-based material.

19. The method of claim 1, wherein applying a fullerene-based material to a nanostructure includes applying the fullerene-based material to a structure having a thickness of at least about one micrometer.

20. The method of claim 1, wherein

applying a fullerene-based material to a nanostructure includes depositing the fullerene-based material on a coating on the nanostructure, and

nucleating the fullerene-based material includes forming at least some of the nucleated fullerene-based material on the coating.

21. A method for doping a carbon nanotube-based nanowire, the method comprising:

applying a fullerene-based material to a carbon nanotube-based nanowire, the fullerene-based material including a material selected from the group of C₆₀F₁₈, C₆₀F₂₄, C₆₀F₃₆, C₆₀F₄₈, C₆₀F₄₄ and C₇₀F₅₄);

nucleating the fullerene-based material to form a nucleated fullerene-based material on the carbon-based nanowire; and

doping the carbon nanotube-based nanowire with the nucleated fullerene-based material.

22. The method of claim 21, wherein the steps of applying and nucleating include depositing the fullerene-based material on the carbon-based nanowire, wherein the fullerene-based material nucleates on the carbon nanotube-based nanowire.

23. The method of claim 21, wherein

applying the fullerene-based material to a carbon nanotube-based nanowire includes selecting an amount of the fullerene-based material to be deposited on the nanowire to set a transparency of a device including a plurality of the nanowires, and applying the fullerene-based material to the plurality of nanowires at the selected amount;

and

nucleating the deposited fullerene-based material including nucleating the fullerene-based material to form a nucleated material on the nanowires and to set the transparency of the device to the set transparency.

24. A carbon nanotube-based nanowire circuit comprising:

a semiconducting carbon nanotube-based nanomaterial coupled between circuit nodes; and

a conductive hybrid material including a halogenated fullerene dopant and the carbon nanotube-based nanomaterial, the dopant configured to effect a charge transfer to the carbon nanotube-based nanomaterial, and configured to electrically couple the circuit nodes, the hybrid material exhibiting a conductivity that is higher than a conductivity of the carbon nanotube-based nanomaterial.

25. The nanowire circuit of claim 24, wherein the dopant includes a material selected from the group of C₆₀F₁₈, C₆₀F₂₄, C₆₀F₃₆, and C₆₀F₄₈, C₆₀F₄₄ and C₇₀F₅₄.

26. The nanowire circuit of claim 24, wherein the conductive hybrid material has a resistance value that is an order of magnitude less than a resistance value of the semiconducting carbon nanotube-based nanomaterial.

27. The nanowire circuit of claim 24, wherein the conductive hybrid material is configured and arranged with the nanowire to render the nanowire more thermally conductive than the semiconducting carbon nanotube-based nanomaterial.

28. The nanowire circuit of claim 24, wherein

the semiconducting carbon nanotube-based nanomaterial is a carbon nanotube, and

the conductive hybrid material is a sidewall of the carbon nanotube doped with the halogenated fullerene dopant.