TRANSPARENT ELECTROACTIVE SYSTEM

• US 20110211245A1
• Filed: 10/07/2009
• Published: 09/01/2011
• Est. Priority Date: 10/09/2008
• Status: Active Grant

• Current Assignee: Essilor International SA
• Original Assignee: Essilor International SA
• Inventors: Duluard, Sandrine, Cano, Jean-Paul, Biver, Claudine
• Granted Patent: US 8,379,288 B2
• Time in Patent Office: Days
• US Class Current: 359/245
• CPC Class Codes: G02F 1/1525 characterised by a particular ion transporting layer, e.g. electrolyte
• CPC Class Codes: G02F 1/1533 structural features not otherwise provided for
• CPC Class Codes: G02F 2001/15145 the electrochromic layer comprises a mixture of anodic and cathodic compounds
• CPC Class Codes: G02F 2001/1557 Side by side arrangements of working and counter electrodes

Abstract

The invention relates to a transparent electroactive system that includes two electrodes (2, 3) juxtaposed on the same side of a closed space (12) containing electroactive substances. The two electrodes are separated by a distance of less than 250 μm, and a barrier (1) extending towards the inside of the closed space is placed between the electrodes. The separation between the electrodes is thus not visible, and a mutual neutralization between the electroactive substances is prevented. Advantageously, the electroactive substances are contained in cells (5) separated from each other within the closed space. The barrier (1) can thus be distinct from separation walls (4) between the cells, or can be assimilated with some intercellular walls.

Claims

1. A transparent electroactive system, that allows clear vision through said system, comprising:

external walls defining a closed volume, the system being transparent for a direction of sight passing through the external walls and said closed volume between two opposite sides;

a liquid and/or a gel contained in the closed volume;

two transparent electrodes, in contact with said liquid or gel on electron transfer surfaces, and intended to be respectively connected to two terminals of a variable power supply;

first and second electroactive substances distributed in the liquid or gel, with different respective redox potentials, at least some of the first and second electroactive substances having an optical effect variable between an oxidized form and a reduced form of said substances,

wherein the two electrodes are borne by a same one of the two external walls, being juxtaposed parallel to said external wall on a same one of the sides of the closed volume containing the liquid or gel, with a separation distance between said electrodes of less than 250 μ

m,

and in that the system furthermore comprises a barrier extending between the two electrodes, to a height of between 1 and 20 μ

m towards the interior of the closed volume, said height being measured from a mean level of the electron transfer surfaces of the two electrodes.

2. The system as claimed in claim 1, in which the height of the barrier is greater than or equal to 5 μ

m, beyond the mean level of the electron transfer surfaces of the two electrodes.

3. The system as claimed in claim 1, wherein in which the distance separating the two electrodes is less than 100 μ

m, preferably between 1 and 40 μ

m.

4. The system as claimed in any one of the preceding claims, furthermore comprising a network of internal walls partitioning the closed volume into cells juxtaposed parallel to the external walls, and in which at least one of the two electrodes is in contact with the liquid or gel contained in each cell.

5. The system as claimed in claim 4, in which the internal walls each have a height greater than or equal to the height of the barrier, preferably between 15 μ

m and 25 μ

m, perpendicular to the external walls.

6. The system as claimed in claim 4, in which, for at least some of the cells, the two electrodes are each in contact with the liquid or gel contained in each cell, with a portion of the barrier placed in said cell between the two electrodes, and the liquid or gel contained in said cell containing both the first and second electroactive substances.

7. The system as claimed in claim 4, in which, for at least some of the cells, only one of the two electrodes is in contact with the liquid or gel contained in each cell, a first of said cells, which is powered by one of the electrodes, being adjacent a second of said cells, which is powered by the other electrode, with a salt bridge between the two cells, and the internal wall separating said first and second cells forming a portion of the barrier between the two electrodes.

8. The system as claimed in claim 7, in which the salt bridge is impermeable to the first and second electroactive substances.

9. The system as claimed in claim 7, in which the salt bridge consists of a film of a gel or a membrane placed on the tops of the internal walls, on the side opposite the electrodes.

10. The system as claimed in claim 1, in which the first and second electroactive substances each have an optical effect variable between the oxidized form and the reduced form of said substances.

11. The system as claimed in claim 10, in which the first and second electroactive substances have respective colors, in at least one of the oxidized or reduced forms, which are complementary relative to said forms, so that said colors appear simultaneously when the system is operated.

12. The system as claimed in claim 11, in which the two electrodes are alternated, with a pitch of less than 1 mm, parallel to the external wall bearing said two electrodes.

13. The system as claimed in claim 1, in which the first or second electroactive substances have optical effect variable between the oxidized form and the reduced form of said substances, the others of said first and second substances not having optical effect variable between the oxidized form and the reduced form of said other substances, and in which one of the electrodes dedicated to transferring electrons to those of the substances that do not have variable optical effect, has a smaller electron transfer surface than the other electrode dedicated to transferring electrons to those of the substances that have the variable optical effect.

14. The system as claimed in any one of the preceding claims, in which the barrier is based on at least one organic, inorganic or hybrid material, or on a photoresist.

15. The system as claimed in claim 1, furthermore comprising a strip of a transparent and insulating material, placed between the two electrodes, with respective thicknesses of said electrodes and of said strip being designed to produce respective phase delays which are equal for a wave of visible light propagating at right angles to the electron transfer surfaces of the electrodes.

16. The system as claimed in claim 1, furthermore comprising an amount of a substance that is absorbing for a part at least of the visible light, placed between the two electrodes.

17. The system as claimed in claim 16, in which the absorbing substance is black.

18. The system as claimed in claim 16, in which the absorbing substance comprises at least one dye diffused in the external wall which bears the electrodes, on the side of and between said electrodes.

19. The system as claimed in claim 1, in which the electrodes have irregular contours, parallel to the external walls.

20. The system as claimed in claim 19, in which the contours of the electrodes have two-dimensional irregularities, parallel to the external walls.

21. The system as claimed in claim 1, forming a glazing pane, an ophthalmic spectacle lens, a helmet visor or a mask lens.