CURABLE HYDROPHILIC COMPOSITIONS
First Claim
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1. A cured composition comprising the reaction product of:
- a) 1 to 20 parts by weight of a surface modified nanoparticle component having ethylenically unsaturated groups and hydrophilic poly(alkylene oxide) groups, wherein the average particle size of said nanoparticle component, prior to surface modification, is 20 nanometers or less; and
b) 80 to 99 parts by weight of a monomer component comprising;
a monofunctional poly(alkylene oxide) free-radically polymerizable macromonomer having a poly(alkylene oxide) moiety,and wherein the parts by weight of a) and b) are based on 100 parts by weight of the total cured composition.
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Abstract
A curable composition is described, including a gel material derived from the curable composition, and medical articles including such material, wherein the transparent gel material includes a polymerized monofunctional poly(alkylene oxide) macromonomer component and a surface modified nanoparticle component.
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Citations
14 Claims
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1. A cured composition comprising the reaction product of:
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a) 1 to 20 parts by weight of a surface modified nanoparticle component having ethylenically unsaturated groups and hydrophilic poly(alkylene oxide) groups, wherein the average particle size of said nanoparticle component, prior to surface modification, is 20 nanometers or less; and b) 80 to 99 parts by weight of a monomer component comprising; a monofunctional poly(alkylene oxide) free-radically polymerizable macromonomer having a poly(alkylene oxide) moiety, and wherein the parts by weight of a) and b) are based on 100 parts by weight of the total cured composition. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14)
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5. The cured composition of claim 1 wherein the surface modified nanoparticles comprise inorganic nanoparticles modified by a first surface modifying agent having an ethylenically unsaturated group and a second surface modifying agent having poly(alkylene oxide) groups.
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6. The cured composition of claim 1 wherein the nanoparticles are selected from the group consisting of silica, alumina, tin oxide, iron oxide, zirconia, vanadia, titania;
- and combinations thereof.
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7. The cured composition of claim 1 wherein the average particle size of said nanoparticle component, prior to surface modification, is less than 10 nanometers.
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8. The cured composition of claim 5 wherein said first surface modifying agent is of the formula Y—
- R3—
Si—
(OR4)b(R4)3-b, wherein;R3 is a covalent bond or a polyvalent hydrocarbon bridging group, Y is an ethylenically unsaturated polymerizable group, R4 is independently an alkyl, aryl, or aralkyl group of 1 to 8 carbon atoms optionally substituted in available positions by oxygen, nitrogen and/or sulfur atoms; and
b is 1 to 3.
- R3—
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9. The cured composition of claim 5 wherein said second surface modifying agent is of the formula R2—
- (OCH2CH2—
)n(OCH2CH(R1))m-Q′
-R3—
Si—
(OR4)b(R4)3-b, whereinQ′
is a divalent linking group;R1 is a C1 to C4 alkyl group, R2 is R1 or H, R3 is a covalent bond or a divalent hydrocarbon bridging group; R4 is independently an alkyl, aryl, or aralkyl group of 1 to 8 carbon atoms optionally substituted by catenary oxygen, nitrogen and/or sulfur atoms; n is at least 5, m may be 0, and the mole ratio of n;
m is at least 2;
1; andb is 1 to 3.
- (OCH2CH2—
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10. The cured composition of claim 5 wherein the ratio of hydrophilic poly(alkylene oxide) groups to ethylenically unsaturated groups on the surface of the inorganic nanoparticles is 1:
- 10 to 10;
1.
- 10 to 10;
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11. The cured composition of claim 5 wherein said first surface modifying agent is used in amounts sufficient to react with 10 to 90% of the available functional groups on the surface of the inorganic nanoparticles.
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12. The cured composition of claim 1 wherein the monomer component comprises:
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a) 30 to 80 wt. % of a monofunctional poly(alkylene oxide) free-radically polymerizable macromonomer having a poly(alkylene oxide) moiety; b) 5 to 40 wt. % of a polar monomer; c) 0 to 20 wt. % of a hydrophobic monomer; d) 0 to 20 wt. % of a multifunctional poly(alkylene oxide) free-radically polymerizable macromonomer having a poly(alkylene oxide) moiety.
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13. The cured composition of claim 12 comprising 0.1 to 20 wt. % of said multifunctional poly(alkylene oxide) free-radically polymerizable macromonomer.
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14. The cured composition of claim 8, wherein R3 is a poly(alkylene oxide) group.
Specification