PROCESS FOR PREPARING WATER ABSORBENT RESIN WITH HIGH PERFORMANCE

• US 20110301303A1
• Filed: 06/07/2011
• Published: 12/08/2011
• Est. Priority Date: 06/08/2010
• Status: Active Grant

• Current Assignee: LG Chem Limited (LG Corporation)
• Original Assignee: LG Chem Limited (LG Corporation)
• Inventors: KIM, Jun-Kyu, KWON, Jong-Hyuk, HUR, Young-Jae, DO, Yun-Kyung
• Granted Patent: US 8,507,620 B2
• Time in Patent Office: Days
• US Class Current: 525/384
• CPC Class Codes: C08F 122/20 Esters containing oxygen in addition to the carboxy oxygen
• CPC Class Codes: C08F 20/18 with acrylic or methacrylic acids
• CPC Class Codes: C08F 220/06 Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
• CPC Class Codes: C08F 8/14 Esterification

Abstract

The present invention relates to a process for preparing a water absorbent resin, particularly to a process for preparing a water absorbent resin which can resolve the uneven size of the fine pulverized gel-type resin and long pulverizing time those are the problems of prior process for preparing the water absorbent resin, by carrying out the pulverizing process of the gel-type resin divided into the coarse pulverizing process which is carried out with the internal cross-linking polymerization, and the fine pulverizing process. According to the preparation process, it is possible to mass-produce the water absorbent resin showing excellent absorption under pressure and low extractable content.

Claims

1. A process for preparing a water absorbent resin, comprising the steps of:

(a) coarse pulverizing a gel-type resin while internal cross-linking and polymerizing the gel-type resin from an aqueous solution of a partially neutralized acrylic acid-based monomer having an acid group, in the presence of a first cross-linking agent, so as to form a coarse pulverized gel-type resin having the size of 3 to 150 mm;

(b) fine pulverizing the coarse pulverized gel-type resin so as to prepare a fine gel-type resin having the size of 1 to 20 mm;

(c) drying the fine gel-type resin;

(d) milling the dried fine gel-type resin and fractionating the same so as to prepare a base resin powder comprising particles having the size of 100 to 850 μ

m in an amount of 70 weight % or more; and

(e) surface cross-linking the base resin powder with a second cross-linking agent so as to prepare the water absorbent resin.

2. The process for preparing the water absorbent resin according to claim 1, wherein the step (a) is carried out in a mixing reactor having cutting force or shearing force.

3. The process for preparing the water absorbent resin according to claim 2, wherein the mixing reactor having cutting force or shearing force comprises a plurality of rotating blades, or a rotating blade and a still blade, and coarse pulverizes the internal cross-linked and polymerized gel-type resin by providing the shearing force thereto, and the rotating speed of the rotating blade is 3.0 to 300 m/min.

4. The process for preparing the water absorbent resin according to claim 1, wherein the acrylic acid-based monomer is a compound represented by the following Chemical Formula 1:

R¹—

COOM¹ 

 

[Chemical Formula 1]

wherein, R¹ is a C₂-C₅ alkyl group including an unsaturated bond, M¹ is hydrogen, a monovalent or divalent metal, ammonium group, or an organic amine salt.

5. The process for preparing the water absorbent resin according to claim 1, wherein the aqueous solution of the partially neutralized acrylic acid-based monomer is an aqueous solution of the acrylic acid-based monomer of which 40 to 90 mole % is neutralized.

6. The process for preparing the water absorbent resin according to claim 1, wherein the first cross-linking agent includes at least one selected from group consisting of N,N-methylenebisacrylamide, trimethylolpropane tri(meth)acrylate, ethyleneglycol di(meth)acrylate, polyethyleneglycol (meth)acrylate, propyleneglycol di(meth)acrylate, polypropyleneglycol (meth)acrylate, butandiol di(meth)acrylate, butyleneglycol di(meth)acrylate, diethyleneglycol di(meth)acrylate, hexanediol di(meth)acrylate, triethyleneglycol di(meth)acrylate, tripropyleneglycol di(meth)acrylate, tetraethyleneglycol di(meth)acrylate, dipentaerythritol pentaacrylate, glycerin tri(meth)acrylate, pentaerythritol tetraacrylate, triarylamine, ethyleneglycol diglycidyl ether, propylene glycol, glycerin, and ethylene carbonate.

7. The process for preparing the water absorbent resin according to claim 1, wherein the coarse pulverized gel-type resin prepared in the step (a) has the moisture content of 30 to 80%.

8. The process for preparing the water absorbent resin according to claim 1, wherein the fine gel-type resin dried in the step (c) has the moisture content of 0.1 to 15%.

9. The process for preparing the water absorbent resin according to claim 1, wherein the second cross-linking agent includes at least one selected from the group consisting of ethyleneglycol diglycidyl ether, polyethyleneglycol diglycidyl ether, glycerol polyglycidyl ether, propyleneglycol diglycidyl ether, polypropyleneglycol diglycidyl ether, ethyleneglycol, diethyleneglycol, propyleneglycol, triethyleneglycol, tetraethyleneglycol, propanediol, dipropyleneglycol, polypropyleneglycol, glycerin, polyglycerin, butanediol, heptanediol, hexanediol, trimethylolpropane, pentaerythritol, sorbitol, calcium hydroxide, magnesium hydroxide, aluminum hydroxide, iron hydroxide, calcium chloride, magnesium chloride, aluminum chloride, and iron chloride.

10. The process for preparing the water absorbent resin according to claim 1, wherein the coarse pulverizing time in the step (a) is about 1 minute to 1 hour.