AQUEOUS POLYMER DISPERSION

• US 20110306727A1
• Filed: 01/13/2010
• Published: 12/15/2011
• Est. Priority Date: 01/22/2009
• Status: Abandoned Application

• Current Assignee: Bayer Materialscience AG (Covestro AG)
• Original Assignee: Bayer Materialscience AG (Covestro AG)
• Inventors: Grablowitz, Hans Georg, Gertzmann, Rolf, Achten, Dirk, Almato Guiteras, Maria, Garcia Martinez, Joan Miguel
• Application Number:
  US13/145,510
• Publication Number:
  US 20110306727A1
• Time in Patent Office: Days
• US Class Current: 524/710
• CPC Class Codes: C08F 212/08 Styrene
• CPC Class Codes: C08F 220/06 Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
• CPC Class Codes: C08F 220/14 Methyl esters , e.g. methyl (meth)acrylate
• CPC Class Codes: C08F 220/16 of phenols or of alcohols containing two or more carbon atoms
• CPC Class Codes: C08F 265/06 Polymerisation of acrylate or methacrylate esters on to polymers thereof
• CPC Class Codes: C08F 285/00 Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
• CPC Class Codes: C09D 15/00 Woodstains
• CPC Class Codes: C09D 151/003 grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds C09D151/04, C09D151/06 take precedence

Abstract

The present invention relates to aqueous polymer dispersions having a core-shell structure, to a method for the production thereof and to the use thereof as a coating agent.

Claims

1. Aqueous, polymer dispersion comprising at least one core copolymer A) and at least one shell copolymer B), wherein the glass transition temperature (T_g) of the core is from 70°

C. to 100°

C., the glass transition temperature (T_g) of the shell is from 20°

C. to 55°

C. and the overall glass transition temperature (T_g) of the core-shell copolymer is from 30°

C. to 80°

C., and the dispersion contains an emulsifier content in an amount of ≦

1.5 wt. %, based on the solids.

2. Aqueous polymer dispersion according to claim 1, wherein the polymer particles have a mean particle size of from 75 to 140 nm.

3. Aqueous polymer dispersion according to claim 1, wherein the T_g of copolymer B) is at least 30°

C. lower than the T_g of copolymer A).

4. Aqueous polymer dispersion according to claim 1, wherein the monomer mixture of copolymer A) and B) comprises

a) (meth)acrylate,

b) at least one vinyl aromatic compound having up to 20 carbon atoms,

c) at least one acid-functional monomer and

d) optionally at least one hydroxy-functional monomer.

5. Aqueous polymer dispersion according to claim 1, wherein the content of monomer a) in copolymer A) is from 20 to 80 wt. %, the content of monomer b) is from 19 to 79 wt. %, the content of monomer c) is from 1 to 10 wt. %, and the content of monomer d) is <

30 wt. %, the sum of components a), b), c) and optionally d) being 100 wt. %.

6. Aqueous polymer dispersion according to claim 1, wherein the content of monomer a) in copolymer B) is from 35 to 90 wt. %, the content of monomer b) is from 9.9 to 60 wt. %, the content of monomer c) is from 0.1 to 3.7 wt. %, and the content of monomer d) is <

30 wt. %, the sum of components a), b), c) and optionally d) being 100 wt. %.

7. Aqueous polymer dispersion according to claim 1, wherein the weight ratio of the monomer of copolymer A) to the monomer of copolymer B) is from 3:

1 to 1;

5.

8. Aqueous polymer dispersion according to claim 1, wherein the emulsifier is an alkyl phosphate ester.

10. Aqueous coating composition comprising an aqueous polymer dispersions according to claim 1.

11. An aqueous polymer dispersion according to claim 1 capable of being used in the production of a coating on a substrate.

12. Dispersion according to claim 11, wherein the substrate comprises wood or derived timber products.

9. Process for the preparation of the polymer dispersion, wherein water, emulsifier and optionally a small amount of initiator are first placed in a reaction vessel, then a metered addition of an amount of monomers a) to c) of from 1 to 10 wt. % is carried out, optionally with the simultaneous metered addition of the initiator, to form an internal seed, and monomers a) to d) for copolymer A) (core) are then added stepwise to the internal seed and polymerised to a conversion of at least 5.0 wt. %, in each case based on their total weight, and monomers a) to d) for copolymer B) are added and polymerised to a conversion of at least 85.0 wt. %, in each case based on their total weight.