METHOD FOR PRODUCING WAXES AND GREASE BASE STOCKS THROUGH CATALYTIC DEPOLYMERISATION OF WASTE PLASTICS

• US 20120016169A1
• Filed: 07/15/2010
• Published: 01/19/2012
• Est. Priority Date: 07/15/2010
• Status: Active Grant

• Current Assignee: Greenmantra Recycling Technologies Ltd.
• Original Assignee: Greenmantra Recycling Technologies Ltd.
• Inventors: KUMAR, ANIL
• Granted Patent: US 8,664,458 B2
• Time in Patent Office: Days
• US Class Current: 585/241
• CPC Class Codes: C08J 11/16 by treatment with inorganic material C08J11/14 takes precedence
• CPC Class Codes: C08J 2323/06 Polyethene
• CPC Class Codes: C10G 1/10 from rubber or rubber waste
• CPC Class Codes: C10G 2300/1003 Waste materials
• CPC Class Codes: C10M 101/025 waxes
• CPC Class Codes: C10M 107/04 Polyethene
• CPC Class Codes: C10M 2205/143 used as base material
• CPC Class Codes: C10M 2205/163 used as base material
• CPC Class Codes: C10N 2020/019 Shear stability
• CPC Class Codes: C10N 2020/02 Viscosity; Viscosity index
• CPC Class Codes: C10N 2020/04 Molecular weight; Molecular weight distribution
• CPC Class Codes: C10N 2030/02 Pour-point; Viscosity index
• CPC Class Codes: C10N 2030/24 Emulsion properties
• CPC Class Codes: C10N 2030/68 Shear stability
• CPC Class Codes: C10N 2050/10 Semi-solids; greasy
• CPC Class Codes: C10N 2070/00 Specific manufacturing methods for lubricant compositions
• CPC Class Codes: Y02W 30/62 Plastics recycling; Rubber recycling

Abstract

A process of depolymerization of mixed polyethylene waste is disclosed. In one embodiment, in a process for converting mixed polyethylene waste to make waxes and grease base stocks through catalytic depolymerization, the mixed polyethylene waste is preheated to form a molten mixed polyethylene waste. Then depolymerization reaction of the molten mixed polyethylene waste is started. The depolymerization reaction uses a catalyst in a high pressure reactor at a desired temperature using heaters in the high pressure reactor. The catalyst is disposed on a stirring blade. Progression of depolymerization reaction of the molten mixed polyethylene waste is allowed to continue until a pressure in the high pressure reactor reaches a desired value. The heaters are turned off and depolymerization reaction of the molten mixed polyethylene waste is stopped upon the pressure in the reactor reaching desired value. The mixed polyethylene waste is converted to wax or grease base stock.

Claims

1. A process for converting mixed polyethylene waste to make waxes and grease base stock through catalytic depolymerization, comprising:

preheating the mixed polyethylene waste to form a molten mixed polyethylene waste;

starting depolymerization reaction of the molten mixed polyethylene waste using a catalyst in a high pressure reactor at a desired temperature using heaters in the high pressure reactor and wherein the catalyst is disposed on a stirring blade;

allowing progression of the depolymerization reaction of the molten mixed polyethylene waste to continue until a pressure in the high pressure reactor reaches a desired value; and

turning off the heaters and stopping the depolymerization reaction of the molten mixed polyethylene waste upon the pressure in the reactor reaching the desired value and wherein the mixed polyethylene waste is converted to wax or a grease base stock.

2. The process of claim 1, further comprising:

draining the converted wax or grease base stock into a container when the converted wax or grease base stock is liquid and is substantially above flash point.

3. The process of claim 1, wherein the temperature is in the range of about 300°

C. to 600°

C.

4. The process of claim 1, wherein preheating the mixed polyethylene waste to form the molten mixed polyethylene waste comprises:

preheating the mixed polyethylene waste using an extruder to form the molten mixed polyethylene waste and wherein the extruder is attached to the reactor.

5. The process of claim 4, further comprising:

substantially continuously pushing the mixed polyethylene waste into the reactor upon the mixed polyethylene reaching the molten state in the extruder.

6. The process of claim 1, wherein the pressure is in the range of about 50 psig-350 psig.

7. The process of claim 1, wherein the mixed polyethylene waste comprises polyethylene selected from the group consisting of low density polyethylene (LPDE), linear low density polyethylene (LLPDE) and high density polyethylene (HPDE).

8. The process of claim 1, wherein the mixed polyethylene waste comprises impurities up to about 10%, and wherein the impurities comprises materials selected from the group consisting of polypropylene and polystyrene.

9. The process of claim 1, wherein the catalyst is [Fe—

Cu—

Mo—

P]/Al₂O₃.

10. The process of claim 1, further comprising:

varying the desired value of the pressure in the high pressure reactor to produce different grades of waxes and grease base stocks.

11. The process of claim 2, further comprising:

inducing coalescence of pigment particles/impurities in the drained converted wax or grease base stock using a high to low pressure cycle; and

allowing the pigment particles/impurities and the converted wax or grease base stock to settle in the container as separate layers.

12. A process for converting primary granules of polyethylene to make waxes and grease base stock through catalytic depolymerization, comprising:

preheating the primary granules of polyethylene to form a molten primary granules of polyethylene;

starting depolymerization reaction of the molten primary granules of polyethylene using a catalyst in a high pressure reactor at a desired temperature using heaters in the high pressure reactor and wherein the catalyst is disposed on a stirring blade;

allowing progression of the depolymerization reaction of the molten primary granules of polyethylene to continue until a pressure in the high pressure reactor reaches a desired value; and

turning off the heaters and stopping the depolymerization reaction of the molten primary granules of polyethylene upon the pressure in the reactor reaching the desired value and wherein the primary granules of polyethylene is converted to wax or grease base stock.

13. The process of claim 12, further comprising:

draining the converted wax or the grease base stock into a container when the converted wax or grease base stock is liquid and is substantially above flash point.

14. The process of claim 12, wherein the temperature is in the range of about 300°

C. to 600°

C.

15. The process of claim 12, wherein the pressure is in the range of about 50 psig-350 psig.

16. The process of claim 12, wherein preheating the primary granules of polyethylene to form the molten primary granules of polyethylene comprises:

preheating the primary granules of polyethylene using an extruder to form the molten primary granules of polyethylene and wherein the extruder is attached to the reactor.

17. The process of claim 16, further comprising:

substantially continuously pushing the primary granules of polyethylene into the reactor upon the primary granules of polyethylene reaching the molten state in the extruder.

18. The process of claim 12, wherein the primary granules of polyethylene comprises polyethylene selected from the group consisting of LPDE, LLPDE and HPDE.

19. The process of claim 12, wherein the catalyst is [Fe—

Cu—

Mo—

P]/Al₂O₃.

20. The process of claim 12, further comprising:

varying the desired value of the pressure in the high pressure reactor to produce different grades of waxes and grease base stocks.

21. The process of claim 13, further comprising:

inducing coalescence of pigment particles/impurities in the drained converted wax or grease base stock using a high to low pressure cycle; and

allowing the pigment particles/impurities and the converted wax or grease base stock to settle in the container as separate layers.

22. A process for converting mixed polyethylene waste to make grease base stock through catalytic depolymerization, comprising:

preheating the mixed polyethylene waste to form a molten mixed polyethylene waste;

starting depolymerization reaction of the molten mixed polyethylene waste using a catalyst in a high pressure reactor at a desired temperature using heaters in the high pressure reactor and wherein the catalyst is disposed on a stirring blade;

allowing progression of the depolymerization reaction of the molten mixed polyethylene waste to continue until a pressure in the high pressure reactor reaches a desired value; and

turning off the heaters and stopping the depolymerization reaction of the molten mixed polyethylene waste upon the pressure in the reactor reaching the desired value and wherein the mixed polyethylene waste is converted to the grease base stock.

23. The process of claim 22, further comprising:

draining the converted grease base stock into a container when the converted grease base stock is liquid and is substantially above flash point.

24. A process for converting mixed polyethylene waste to make waxes through catalytic depolymerization, comprising:

preheating the mixed polyethylene waste to form a molten mixed polyethylene waste;

starting depolymerization reaction of the molten mixed polyethylene waste using a catalyst in a high pressure reactor at a desired temperature using heaters in the high pressure reactor and wherein the catalyst is disposed on a stirring blade;

allowing progression of the depolymerization reaction of the molten mixed polyethylene waste to continue until a pressure in the high pressure reactor reaches a desired value; and

turning off the heaters and stopping the depolymerization reaction of the molten mixed polyethylene waste upon the pressure in the reactor reaching the desired value and wherein the mixed polyethylene waste is converted to wax.

25. The process of claim 24, further comprising:

draining the converted wax into a container when the converted wax is liquid and is substantially above flash point.