OIL COMPOSITION COMPRISING FUNCTIONALIZED NANOPARTICLES

• US 20120032543A1
• Filed: 02/04/2011
• Published: 02/09/2012
• Est. Priority Date: 01/26/2009
• Status: Abandoned Application

• Current Assignee: Baker Hughes Incorporated (Baker Hughes Company)
• Original Assignee: Baker Hughes Incorporated (Baker Hughes Company)
• Inventors: Chakraborty, Soma, Leonard, Ashley, Agrawal, Gaurav, Sheth, Ketankumar K.
• Application Number:
  US13/021,137
• Publication Number:
  US 20120032543A1
• Time in Patent Office: Days
• US Class Current: 310/90
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C10M 125/02 Carbon; Graphite
• CPC Class Codes: C10M 171/06 Particles of special shape or size
• CPC Class Codes: C10M 2201/041 Carbon; Graphite; Carbon black
• CPC Class Codes: C10M 2201/0413 used as base material
• CPC Class Codes: C10M 2201/061 Carbides; Hydrides; Nitrides
• CPC Class Codes: C10M 2201/0613 used as base material
• CPC Class Codes: C10M 2201/062 Oxides; Hydroxides; Carbonates or bicarbonates
• CPC Class Codes: C10M 2201/0623 used as base material
• CPC Class Codes: C10M 2201/065 Sulfides; Selenides; Tellurides
• CPC Class Codes: C10M 2201/0653 used as base material
• CPC Class Codes: C10M 2201/066 Molybdenum sulfide
• CPC Class Codes: C10M 2201/0663 used as base material
• CPC Class Codes: C10M 2201/105 Silica
• CPC Class Codes: C10M 2201/1053 used as base material
• CPC Class Codes: C10M 2201/14 inorganic compounds surface treated with organic compounds
• CPC Class Codes: C10M 2219/044 Sulfonic acids, Derivatives thereof, e.g. neutral salts
• CPC Class Codes: C10N 2020/06 Particles of special shape or size
• CPC Class Codes: C10N 2020/061 Coated particles
• CPC Class Codes: C10N 2030/02 Pour-point; Viscosity index
• CPC Class Codes: C10N 2030/06 : Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
• CPC Class Codes: C10N 2030/58 : Elastohydrodynamic lubrication, e.g. for high compressibility layers
• CPC Class Codes: C10N 2030/60 : Electro rheological properties
• CPC Class Codes: C10N 2040/14 : Electric or magnetic purposes
• CPC Class Codes: C10N 2040/16 : Dielectric; Insulating oil or insulators
• CPC Class Codes: C10N 2050/015 : Dispersions of solid lubricants
• CPC Class Codes: H02K 2201/03 : Machines characterised by aspects of the air-gap between rotor and stator
• CPC Class Codes: H02K 2205/12 : Machines characterised by means for reducing windage losses or windage noise
• CPC Class Codes: H02K 5/132 : Submersible electric motors H02K5/128 takes precedence
• CPC Class Codes: H02K 5/161 : radially supporting the rotary shaft at both ends of the rotor H02K5/165, H02K5/167, H02K5/173 take precedence
• CPC Class Codes: H02K 9/19 : for machines with closed casing and closed-circuit cooling using a liquid cooling medium, e.g. oil

Abstract

An improved oil composition is disclosed. The oil composition includes a base oil comprising a hydrocarbon, the base oil having a base thermal conductivity. The oil composition also includes a first additive comprising a plurality of derivatized first additive nanoparticles dispersed within the base oil to form a modified oil having a modified thermal conductivity, wherein the modified thermal conductivity is greater than the base thermal conductivity. Alternately, an improved oil composition includes a base oil comprising a hydrocarbon and a first additive comprising a plurality of derivatized first additive nanoparticles dispersed within the base oil to form a modified oil comprising a stabilized suspension of the derivatized first additive nanoparticles in the base oil.

Claims

1. An oil composition, comprising:

a base oil comprising a hydrocarbon, the base oil having a base thermal conductivity; and

a first additive comprising a plurality of derivatized first additive nanoparticles dispersed within the base oil to form a modified oil having a modified thermal conductivity, wherein the modified thermal conductivity is greater than the base thermal conductivity.

2. The oil composition of claim 1, wherein the first additive provides the modified oil with at least one modified oil property that is greater than a base oil property, the modified oil property selected from a group consisting of lubricity, electrical resistance, viscosity, elasticity, and combinations thereof.

3. The oil composition of claim 1, further comprising a second additive comprising a plurality of second additive nanoparticles or microparticles, or a combination thereof, dispersed within the base oil, wherein the second additive nanoparticles or microparticles are derivatized or underivatized, or a combination thereof.

4. The oil composition of claim 3, wherein the second additive provides the modified oil with at least one modified oil property that is greater than a base oil property, the modified oil property selected from a group consisting of thermal conductivity, lubricity, electrical resistance, viscosity, elasticity, and combinations thereof.

5. The oil composition of claim 1, wherein the modified oil comprises up to about 10% by volume of the first additive nanoparticles.

6. The oil composition of claim 3, wherein the modified oil comprises up to about 10% by volume of a sum of the first additive nanoparticles and the second additive nanoparticles.

7. The oil composition of claim 1, wherein the base oil comprises a natural oil or a synthetic oil, or a combination thereof.

8. The oil composition of claim 1, wherein the first nanoparticles are selected from a group consisting of a fullerene, graphene, graphite, nanodiamond, metallic oxide, metal sulfonate, molybdenum disulfide, tungsten disulfide, alumoxane, metallic carbide, metallic nitride, and combinations thereof.

9. The oil composition of claim 1, wherein each of the derivatized first additive nanoparticles is derivatized to include at least one functional group selected from the group consisting of carboxy, epoxy, ether, ester, ketone, amine, hydroxy, alkoxy, alkyl, aralkyl, alkene, alkyne, lactone, aryl, functionalized polymeric or oligomeric groups, or a combination thereof.

10. The oil composition of claim 3, wherein each of the derivatized first additive nanoparticles is derivatized to include at least one functional group selected from the group consisting of carboxy, epoxy, ether, ester, ketone, amine, hydroxy, alkoxy, alkyl, aralkyl, alkene, alkyne, lactone, aryl, functionalized polymeric or oligomeric groups, or a combination thereof.

11. The oil composition of claim 8, wherein the fullerene is selected from a group consisting of a buckeyball, buckeyball cluster, single-wall nanotube, multi-wall nanotube, and combinations thereof.

12. The oil composition of claim 8, wherein the metallic oxide is selected from a group consisting of aluminum oxide, silicon oxide, beryllium oxide, and combinations thereof.

13. The oil composition of claim 3, wherein the first additive nanoparticles or the second additive nanoparticles, or both of them, are selected from a group consisting of a fullerene, graphene, graphite, nanodiamond, metallic oxide, metal sulfonate, molybdenum disulfide, tungsten disulfide, alumoxane, metallic carbide, metallic nitride, and combinations thereof.

14. The oil composition of claim 1, wherein the modified oil comprises a substantially non-settling suspension.

15. The oil composition of claim 14, wherein the substantially non-settling suspension is substantially non-settling for a predetermined service interval.

16. The oil composition of claim 15, wherein the predetermined service interval is at least 3 months.

17. The oil composition of claim 1, wherein the modified thermal conductivity is substantially greater than the base thermal conductivity.

18. The oil composition of claim 1, wherein the modified thermal conductivity is at least 20 percent greater than the base thermal conductivity.

19. An oil composition, comprising:

a base oil comprising a hydrocarbon; and

a first additive comprising a plurality of derivatized first additive nanoparticles dispersed within the base oil to form a modified oil comprising a stabilized suspension of the derivatized first additive nanoparticles in the base oil.

20. The oil composition of claim 19, wherein the first additive further comprises a plurality of first additive microparticles, and wherein the first additive microparticles are derivatized or underivatized, or a combination thereof.

21. The oil composition of claim 20, wherein the base oil has a base thermal conductivity and the modified oil has a modified thermal conductivity, and wherein the modified thermal conductivity is substantially greater than the base thermal conductivity.

22. The oil composition of claim 20, further comprising a second additive comprising a plurality of second additive nanoparticles or microparticles, or a combination thereof, dispersed within the base oil

23. The oil composition of claim 22, wherein at least a portion of the second additive nanoparticles or microparticles, or a combination thereof, are derivatized.

24. The oil composition of claim 19, wherein the first additive nanoparticles or microparticles, or a combination thereof, comprise diamond.

25. An electric motor, comprising:

a rotatable shaft;

a stator;

a rotor disposed within the stator and spaced from the stator by a running clearance therebetween, the rotor configured for rotation of the shaft; and

an oil composition disposed in the running clearance, the oil composition comprising a base oil comprising a hydrocarbon, the base oil having a base thermal conductivity, and a first additive comprising a plurality of derivatized first additive nanoparticles dispersed within the base oil to form a modified oil comprising a stabilized suspension of the derivatized nanoparticles in the base oil and having a modified thermal conductivity, wherein the modified thermal conductivity is greater than the base thermal conductivity.