Anti-Reflective and Anti-Soiling Coatings with Self-Cleaning Properties

• US 20120040179A1
• Filed: 07/18/2011
• Published: 02/16/2012
• Est. Priority Date: 04/30/2009
• Status: Active Grant

• Current Assignee: First Solar Incorporated
• Original Assignee: Enki Technology, Inc. (First Solar Incorporated)
• Inventors: Dave, Bakul Champaklal
• Granted Patent: US 8,864,897 B2
• Time in Patent Office: Days
• US Class Current: 428/336
• CPC Class Codes: C03C 17/30 with silicon-containing compounds
• CPC Class Codes: C03C 2203/27 the alkoxides containing other organic groups, e.g. alkyl groups
• CPC Class Codes: C03C 2217/732 made of a single layer
• CPC Class Codes: C03C 2217/78 Coatings specially designed to be durable, e.g. scratch-resistant
• CPC Class Codes: C03C 2218/113 by sol-gel processes
• CPC Class Codes: C08G 77/24 halogen-containing groups
• CPC Class Codes: C09D 183/04 Polysiloxanes
• CPC Class Codes: C09D 183/08 containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
• CPC Class Codes: C09D 5/006 Anti-reflective coatings
• CPC Class Codes: C09D 5/1662 Synthetic film-forming substance
• CPC Class Codes: Y10T 428/265 1 mil or less
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane

Abstract

The embodiments of the invention are directed to coatings and their uses. More particularly, the embodiments of the invention are directed to coating compositions that include silane-based precursors that are used to form coatings through a sol-gel process. The coatings so formed are characterized by anti-reflective, abrasion resistant, and anti-soiling properties. The coatings also have extended weatherability to heat, humidity, and protection against ambient corrosives. The coatings formed from the compositions described herein have wide application, including, for example, use as coatings on the outer glass of solar cells.

Claims

1. A coating, comprising:

a dried gel formed from a sol comprising a hydrolyzed alkoxysilane, a hydrolyzed organosilane, and a hydrolyzed organofluorosilane;

wherein said dried gel comprises anti-reflective, abrasion resistant, and water repellant properties.

2. The coating of claim 1, wherein said alkoxysilane comprises tetramethoxysilane, said organosilane comprises methyltrimethoxysilane, and said organofluorosilane comprises trifluoropropyltrimethoxysilane.

3. The coating of claim 1, wherein said alkoxysilane comprises tetraethoxysilane, said organosilane comprises methyltrimethoxysilane, and said organofluorosilane comprises trifluoropropyltrimethoxysilane.

4. The coating of claim 1, wherein said alkoxysilane comprises tetramethoxysilane, said organosilane comprises methyltrimethoxysilane, and said organofluorosilane comprises (tridecafluoro-1,1,2,2-tetrahydrooctyl)trimethoxysilane.

5. The coating of claim 1, wherein said alkoxysilane comprises tetraethoxysilane, said organosilane comprises methyltrimethoxysilane, and said organofluorosilane comprises (tridecafluoro-1,1,2,2-tetrahydrooctyl)trimethoxysilane.

6. The coating of claim 1, wherein said sol comprises a mixture of a first sol comprising a hydrolyzed alkoxysilane and a second sol comprising a mixture of a hydrolyzed organosilane and a hydrolyzed organofluorosilane.

7. The coating of claim 1, wherein said sol comprises a relative weight percent ratio of said tetraalkoxysilane to a total of said organosilane and said organofluorosilane is about 0.2 to about 2.

8. The coating of claim 1, wherein said sol comprises a relative weight percent ratio of said organosilane to said organofluorosilane of about 0.5 to about 1.5.

9. The coating of claim 1, wherein said dried gel is formed from a mixture comprising said sol;

an organic solvent selected from the group consisting of alcohols, esters, ethers, aldehydes, and ketones; and

water, wherein an amount of the amount of said solvent and said water in said mixture is from about 50% to about 99.5% by weight.

10. The coating of claim 9, wherein a ratio of said solvent to said water is about 5 to about 20 by weight.

11. The coating of claim 9, wherein said dried gel comprises an abrasion resistance sufficient to pass standard EN 1096.2 abrasion testing when cured at less than 150°

C.

12. The coating of claim 1, wherein said sol further comprises an acid catalyst in an amount of about 0.001% to about 2% by weight and wherein said sol has a pH of about 1 to about 4.

13. The coating of claim 1, wherein said sol further comprises an base catalyst in an amount of about 0.001% to about 2% by weight and wherein said sol has a pH of about 7 to about 10.

14. The coating of claim 1, wherein said sol further comprises a low molecular weight polymer in an amount of about 0.1% to about 10% by weight.

15. The coating of claim 1, wherein said sol further comprises a particle size tuning additive in an amount of about 0.1% to about 2% by weight and that provides a transmission increase of about 0.5% to about 2.0% compared to a same coating without said particle size tuning additive.

16. The coating of claim 1, wherein said sol further comprises a cross-linking additive.

17. The coating of claim 1, wherein said sol further comprises an alkoxysilane precursor with functional groups that can react with a hydrophobic reactive agent and wherein said dried gel was exposed to a hydrophobic reactive agent such that said dried gel has an increased surface contact angle of up to about 15 degrees compared to a same coating without said alkoxysilane precursor with functional groups and said hydrophobic reactive agent.

18. The coating of claim 1, further comprising a substrate having a surface on which said dried gel is attached and wherein said dried gel has a thickness of about 80 nm to about 1 micron.

19. The coating of claim 1 further comprising a solar panel having a surface on which said dried gel is attached.

20. A coating, comprising:

a dried gel formed from a sol comprising a hydrolyzed alkoxysilane, a hydrolyzed organosilane, and a hydrolyzed organofluorosilane;

wherein said coating has a contact angle of about 90 degrees to about 178 degrees, a pencil hardness of about 2H to about 9H, and an increased transmission of about 1% to about 3.5% compared to a substrate without said coating.