Pressure-Sensitive Adhesive Compound

• US 20120040180A1
• Filed: 02/16/2010
• Published: 02/16/2012
• Est. Priority Date: 03/04/2009
• Status: Abandoned Application

• Current Assignee: Tesa SE (Maxingvest AG)
• Original Assignee: Tasa Se
• Inventors: Husemann, Marc, Utesch, Nils
• Application Number:
  US13/254,077
• Publication Number:
  US 20120040180A1
• Time in Patent Office: Days
• US Class Current: 428/336
• CPC Class Codes: C08G 2170/40 Compositions for pressure-sensitive adhesives
• CPC Class Codes: C08G 77/12 containing silicon bound to hydrogen C08G77/045 takes precedence
• CPC Class Codes: C08G 77/20 containing silicon bound to unsaturated aliphatic groups C08G77/045 takes precedence
• CPC Class Codes: C08G 77/70 Siloxanes defined by use of the MDTQ nomenclature
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C09J 183/04 Polysiloxanes
• CPC Class Codes: Y10T 428/265 1 mil or less
• CPC Class Codes: Y10T 428/28 Web or sheet containing structurally defined element or component and having an adhesive outermost layer

Abstract

The present invention relates to the use of an adhesive compound, in particular a pressure-sensitive adhesive compound, based on silylated polyurethanes for bonding optical components, in particular optical films, wherein the adhesive compound has a transmission according to ASTM D 1003 of greater than 86% and a haze according to ASTM D 1003 of less than 5%.

Claims

1. An adhesive for the adhesive bonding of optical components, comprising polysiloxane, the adhesive having an ASTM D 1003 transmittance of more than 86% and an ASTM D 1003 haze of less than 5%.

2. The adhesive of claim 1, wherein the adhesive is based on condensation-crosslinking silicone with the following components:

a) a hydroxy-functionalized first organopolysiloxane, said first organopolysiloxane having at least one diorganosiloxane unit,

b) second organopolysiloxane, said second organopolysiloxane having

the following formula;

(R¹₃SiO_1/2)_x(SiO_4/2)₁,

where R¹ is a substituted or unsubstituted monovalent hydrocarbon group, a hydrogen atom or a hydroxyl group and x is a number between 0.5 and 1.2,

c) optionally a stabilizer, and

d) optionally an initiator.

3. The adhesive of claim 2, wherein the adhesive is compounded with a peroxo initiator in an amount of 0.2% to 5% by weight, based on the solids fraction of the adhesive.

4. The adhesive of claim 1 wherein the adhesive is based on addition-crosslinking silicone with the following components:

a) a first organopolysiloxane, said first organopolysiloxane having at least one diorganosiloxane unit and at least two silicon-bonded alkenyl groups in each molecule,

b) a second organopolysiloxane, said second organopolysiloxane having the following formula;

(R¹₃SiO_1/2)_x(SiO_4/2)₁,

where R¹ is a substituted or unsubstituted monovalent hydrocarbon group, a hydrogen atom or a hydroxyl group and x is a number between 0.5 and 1.2,

c) a third organopolysiloxane, said third organopolysiloxane carries on average at least two silicon-bonded hydrogen atoms in each molecule, said third organopolysiloxane being free from olefinic double bonds, and the amount of said third organopolysiloxane being selected such that there are 0.01 to 10 mol of silicon-bonded hydrogen atoms per mole of the total alkenyl groups of components a), b), and, where present, e),

d) an organometallic catalyst from group 10 of the Periodic Table of the Elements,

e) optionally an inhibitor.

5. The adhesive of claim 1 wherein the adhesive is crosslinked with actinic radiation in a dose of at least 10 kGy.

6. The adhesive of claim 2 wherein the ratio of the (R¹₃SiO_1/2)_x units (“

M units”

) to the (SiO_4/2)₁ units (“

Q units”

) is in the range from 0.5 to 1.2.

7. The adhesive of claim 2 wherein the weight-average molecular weight MW of the organopolysiloxane resins (MQ resins) is in the range from 500 g/mol to 100 000 g/mol.

8. The adhesive of claim 2 wherein the proportional ratio of the organopolysiloxane to the organopolysiloxane resin, based on percent by weight, is in the range from 20:

80 to 80;

20.

9. The adhesive of claim 1 wherein the optical component is electrically conductive and/of has a microstructured surface.

10. The adhesive of claim 1 wherein the adhesive is provided in the form of an adhesive tape.

11. The adhesive of claim 10, wherein the adhesive tape has at least one adhesive layer, preferably in that the adhesive layer has a layer thickness in the range from 25 to 150 μ

m, preferably in the range from 50 to 100 μ

m, or in that the adhesive layer has a layer thickness in the range from 100 to 250 μ

m, preferably in the range from 150 to 200 μ

m.

12. The adhesive of claim 11, wherein the adhesive layer is produced in only one coating step.

13. The adhesive of claim 3 wherein the peroxo initiator is benzoyl peroxide.