METHOD AND DEVICES FOR HEATING UREA-CONTAINING MATERIALS IN VEHICLE EMISSION CONTROL SYSTEM

• US 20120045378A1
• Filed: 08/15/2011
• Published: 02/23/2012
• Est. Priority Date: 08/19/2010
• Status: Active Grant

• Current Assignee: Dow Global Technologies LLC (Dow, Inc.)
• Original Assignee: Dow Global Technologies LLC (Dow, Inc.)
• Inventors: Bank, David H., Soukhojak, Andrey
• Granted Patent: US 8,361,422 B2
• Time in Patent Office: Days
• US Class Current: 423/212
• CPC Class Codes: B01B 1/005 Evaporation for physical or chemical purposes; Evaporation apparatus therefor, e.g. evaporation of liquids for gas phase reactions
• CPC Class Codes: B01D 2251/206 Ammonium compounds
• CPC Class Codes: B01D 2251/2067 Urea
• CPC Class Codes: B01D 53/9418 for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
• CPC Class Codes: C01C 1/086 from urea
• CPC Class Codes: F01N 2240/02 a heat exchanger
• CPC Class Codes: F01N 2240/10 a heat accumulator
• CPC Class Codes: F01N 2240/25 an ammonia generator
• CPC Class Codes: F01N 2610/02 the substance being ammonia or urea
• CPC Class Codes: F01N 2610/10 the substance being heated, e.g. by heating tank or supply line of the added substance
• CPC Class Codes: F01N 3/2066 Selective catalytic reduction [SCR]
• CPC Class Codes: F28D 15/0266 with separate evaporating and condensing chambers connected by at least one conduit; Loop-type heat pipes; with multiple or common evaporating or condensing chambers F28D15/043 takes precedence
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y02P 20/129 Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
• CPC Class Codes: Y02T 10/12 Improving ICE efficiencies

Abstract

The invention relates to systems and methods for heating a solid or liquid reducing material such as an urea-containing material for NO_x selective catalytic reduction (‘SCR’) using a heat stored in a thermal energy storage material, such as a phase change material. The stored heat may be heat from an exhaust waste, such as from an exhaust gas of an internal combustion engine. The reducing material may be a solid reducing material. Other reducing materials include aqueous solutions such as an aqueous solution containing, consisting essentially of, or consisting of urea and water. In one aspect, the process may include a step of evaporating an aqueous solution of urea for immediate urea hydrolysis.

Claims

1. A system comprising

i. a container for containing a supply of a solid or liquid reducing material, wherein the container has one or more exits so that the reducing material can be removed from the container;

ii. a gas producing reactor for converting at least some of the solid or liquid reducing material into ammonia and carbon dioxide, wherein the gas producing reactor is in fluid communication with the one or more exits of the container; and

iii. a heat storage device in thermal communication with the gas producing reactor and/or a region of the one or more exits of the container, wherein the heat storage device includes one or more thermal energy storage material in a sufficient amount so that the heat storage device is capable of heating at least a solid surface of the gas producing reactor and/or at least one or more exits of the container to a temperature sufficient for producing ammonia and/or carbon dioxide.

2. The system of claim 1, wherein the thermal communication between the heat storage device and the gas producing reactor and/or the region of the one or more exits of the container includes one or more paths capable of circulating a heat transfer fluid so that heat can be removed from the heat storage device and transferred to the gas producing reactor and/or the region of the one or more exits of the container.

3. The system of claim 2, wherein the system includes one or more paths for transferring thermal energy from an exhaust of combustion engine to the heat storage device including one or any combination of the following:

i) a heat pipe in thermal communication between the exhaust and the heat storage device;

ii) a loop in thermal communication between the exhaust and the heat storage device, wherein the loop is capable of flowing a heat transfer fluid;

or

iii) a flow of at least a portion of the exhaust through the heat storage device.

4. The system of claim 3, wherein the thermal energy storage material has a liquidus temperature of about 150°

C. or more;

the heat storage device includes a sufficient amount of thermal energy storage material so that the device is capable of heating at least a solid surface of the gas producing reactor and/or at least one more exits of the container to a temperature of about 200°

C. or more.

5. The system of claim 4, wherein the solid or liquid reducing material is a liquid, and the gas producing reactor includes a sprayer for spraying the solid or liquid reducing material into the gas producing reactor.

6. The system of claim 4, wherein the solid or liquid reducing material is a solid and the heat storage device is in thermal communication with the one or more exits of the container, so that the solid or liquid reducing material can be heated to a temperature of 200°

C. or more prior to entering the gas producing reactor.

7. The system of claim 4, wherein the gas producing reactor includes a heat exchanger for transferring heat from a heat transfer fluid to a solid surface of the gas producing reactor.

8. The system of claim 4, wherein the gas producing reactor includes an exhaust gas inlet for receiving a portion of the exhaust gas so that the portion of the exhaust gas can be used as a carrier gas, wherein the exhaust gas inlet is arranged so that the carrier gas passes through a solid surface of the gas producing reactor having a temperature greater than about 200°

C. prior to contacting the solid or liquid reducing material, so that the carrier gas can heat and convey the reducing material and/or the reaction products therefrom.

9. A method comprising a step of maintaining a solid surface temperature of a vehicle ammonia-producing reactor above 200°

C. using stored waste heat.

10. The method of claim 9, wherein the step of maintaining the solid surface temperature includes a step of at least partially discharging the heat storage device.

11. The method of claim 10, wherein

the stored waste heat is stored in a heat storage device,

the heat storage device includes a thermal energy storage material having a liquidus temperature of about 150°

C. or more, and

the process includes a step of at least partially charging the heat storage device using heat from the exhaust of an internal combustion engine so that the temperature of the thermal energy storage material increases and/or the concentration of the thermal energy storage material that is in a liquid state increases;

wherein the charging and discharging steps are asynchronous.

12. The method of claim 11, wherein

the step of at least partially discharging heat includes circulating a first heat transfer fluid between the heat storage device and the ammonia-producing reactor and/or a component that is in thermal communication with the ammonia-producing reactor using a heat pipe or a fluid loop;

and

the step of at least partially charging the heat storage device includes circulating a second heat transfer fluid between the heat storage device and the exhaust of an internal combustion engine and/or a component in thermal communication with the exhaust using a heat pipe or a fluid loop.

13. The method claim 9, wherein the process includes

a thermolysis step of heating urea to a temperature sufficiently high so that ammonia is produced;

a hydrolysis step at a temperature sufficiently high so that ammonia and carbon dioxide is produced; and

a step of reacting ammonia with NO and/or NO₂ molecules, and optionally O₂, in the presence of a catalyst so that N₂ is produced.

14. A method comprising:

feeding a feed portion of solid or liquid reducing material into a gas producing reactor;

heating the feed portion of the solid or liquid reducing material, using heat stored in a heat storage device, to a temperature sufficiently high that thermolysis and/or hydrolysis occurs;

wherein the solid or liquid reducing material has a concentration of urea of about 50 wt. % or more, based on the total weight of the solid or liquid reducing material; and

the heat storage device includes a thermal energy storage material having a liquidus temperature sufficiently high that the urea-containing material can be heated using latent heat and/or sensible heat from the thermal energy storage material.

15. The process of claim 14, wherein the thermal energy storage material has a liquidus temperature from about 150°

C. to about 450°

C.

16. The process of claim 15, wherein

the solid or liquid reducing material is a urea-containing material;

and

the process includes;

reacting the urea-containing material to produce ammonia;

adding the ammonia to an exhaust gas containing one or more nitrogen oxides of an internal combustion engine; and

catalytically reacting the ammonia with nitrogen oxides so that the concentration of nitrogen oxide in the exhaust gas is reduced.

17. The process of claim 16, wherein the solid or liquid reducing material includes less than 40 wt. % water so that the amount of thermal energy wasted in vaporizing the water is reduced.

18. The process of claim 17, wherein the solid or liquid reducing material is an urea-containing material and the urea-containing material includes from about 15 to about 30 wt. % water, based on the total weight of the urea-containing material.

19. The process of claim 14, wherein the solid or liquid reducing material is an urea-containing material, the urea-containing material is stored in a reservoir as a solid material;

and

the process includes conveying the feed portion of the solid urea-containing material so that the feed portion of the urea-containing material contacts a solid surface having a temperature of about 200°

C. or more.

20. The process of claim 19 wherein the step of conveying the urea-containing material includes a step of rotating a screw so that the urea-containing material advances from the reservoir;

wherein the screw is

i) a positioning screw, and the positioning screw advances a plate or plunger that forces the urea-containing material from the reservoir;

or

ii) a conveying screw positioned inside a feed tube and the urea-containing material advances along the feed tube during the rotating of the conveying screw.