METHOD AND DEVICE FOR REDUCING OLEFIN LOSSES DURING THE REMOVAL OF CARBON DIOXIDE FROM AN OLEFIN FLOW FROM DEHYDROGENATION REACTIONS

• US 20120053385A1
• Filed: 02/26/2010
• Published: 03/01/2012
• Est. Priority Date: 03/12/2009
• Status: Abandoned Application

• Current Assignee: Thyssenkrupp Uhde GmbH (Thyssenkrupp AG)
• Original Assignee: UHDE GmbH (Thyssenkrupp AG)
• Inventors: Menzel, Johannes
• Application Number:
  US13/256,063
• Publication Number:
  US 20120053385A1
• Time in Patent Office: Days
• US Class Current: 585/654
• CPC Class Codes: B01D 2251/21 Organic compounds not provided for in groups B01D2251/206 or B01D2251/208
• CPC Class Codes: B01D 2256/24 Hydrocarbons
• CPC Class Codes: B01D 2257/304 Hydrogen sulfide
• CPC Class Codes: B01D 2257/308 Carbonoxysulfide COS
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2257/70 Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
• CPC Class Codes: B01D 53/1462 Removing mixtures of hydrogen sulfide and carbon dioxide
• CPC Class Codes: B01D 53/77 Liquid phase processes
• CPC Class Codes: B01D 53/78 with gas-liquid contact
• CPC Class Codes: C07C 11/02 Alkenes
• CPC Class Codes: C07C 11/06 Propene
• CPC Class Codes: C07C 5/333 Catalytic processes
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02P 20/151 Reduction of greenhouse gas [GHG] emissions, e.g. CO2
• CPC Class Codes: Y02P 20/50 Improvements relating to the production of bulk chemicals

Abstract

The product gas from a dehydrogenation reaction is treated by a downstream gas scrub followed by depressurization in a high-pressure flash vessel equipped with mass transfer elements, wherein a fuel gas flows upwardly through the mass transfer elements in the high-pressure flash vessel countercurrent to depressurized solvent so that absorbed hydrocarbons are taken up by the fuel gas. The fuel gas is the heating gas for heating the dehydrogenation reactor and is, for example, natural gas. To increase efficiency, the hydrocarbon stream which has been separated from the acidic gas can be recirculated to the process gas path upstream of the gas scrub.

Claims

1-16. -16. (canceled)

17. A process for removing carbon dioxide from a hydrocarbon stream in the preparation of alkenes from alkanes, comprising:

introducing an industrially oxygen-free gas mixture containing a feed alkane and an inert gas into a reaction apparatus containing at least one catalyst bed to dehydrogenate the feed alkane, said reaction apparatus heated by a heating gas;

removing from the reaction apparatus a product gas mixture containing alkenes, alkanes, hydrogen, the inert gas and carbon dioxide (CO₂);

absorbing acidic gas constituents comprising one or more of carbon dioxide, hydrogen sulfide (H₂S), carbonyl sulfide (COS) and mercaptans present in the product gas by contacting the product gas with a solvent which absorbs acidic gases in a gas scrub downstream of the dehydrogenation, forming an adsorbate solution; and

conveying the adsorbate solution, which also contains coabsorbed hydrocarbons, to the top of a high-pressure flash vessel containing mass transfer elements, and feeding a fuel gas to the bottom of the high-pressure flash vessel countercurrent to the adsorbate solution flowing downwards over the mass transfer elements, wherein the major part of hydrocarbons present in the adsorbate solution including alkenes desorbed from the adsorbate solution leave the high-pressure flash vessel at the top,

wherein the fuel gas is the heating gas which is used for heating the dehydrogenation reactor.

18. The process of claim 17, wherein gas leaving the top of the high-pressure flash vessel is recirculated to the product gas path downstream of the dehydrogenation apparatus.

19. The process of claim 17, wherein the high-pressure flash vessel is operated at a pressure of from 1 to 20 bar.

20. The process of claim 17, wherein the high-pressure flash vessel is operated at a temperature of from 40°

C. to 160°

C.

21. The process of claim 17, wherein the alkane is propane and the alkene prepared therefrom is propylene.

22. The process of claim 17, wherein the inert gas in the dehydrogenation reaction is steam.

23. The process of claim 22, wherein the heating gas used for heating the dehydrogenation reactor is natural gas.

24. The process of claim 17, wherein the solvent for the gas scrub comprises a chemically acting absorption medium.

25. The process of claim 17, wherein the solvent for the gas scrub comprises an aqueous amine solution.

26. The process of claim 17, wherein an aqueous monoethanolamine solution is used as a solvent for the gas scrub.

27. The process of claim 17, wherein the solvent for the gas scrub comprises an aqueous methyldiethanolamine solution.

28. The process of claim 26, wherein the solvent for the gas scrub contains an activator selected from the group consisting of primary and secondary amines.

29. The process of claim 27, wherein the solvent for the gas scrub contains an activator selected from the group consisting of primary and secondary amines.

30. The process of claim 17, wherein the product gas which has been freed of acidic gases is fed to a “

cold box” and

to a recovery column for further recovery of alkenes still present in the product gas.

31. An apparatus for removing carbon dioxide from a hydrocarbon stream in the preparation of alkenes from alkanes, comprising a gas scrubbing absorption column which contacts an acidic gas-containing process stream with an acidic gas-absorbing solvent, wherein downstream of the absorption column there is a high-pressure flash vessel which depressurizes acidic gas-laden solvent and this high-pressure flash vessel has an inlet for the acidic gas-laden solvent, an inlet for a fuel gas, an outlet for an acidic gas-laden solvent and an outlet for a gaseous hydrocarbon stream.