ELECTROCHROMIC FORMULATION, METHOD FOR THE PRODUCTION THEREOF, AND ORGANIC ELECTROCHROMIC COMPONENT

• US 20120069419A1
• Filed: 05/06/2010
• Published: 03/22/2012
• Est. Priority Date: 05/29/2009
• Status: Abandoned Application

• Current Assignee: Siemens AG
• Original Assignee: Siemens AG
• Inventors: Kanitz, Andreas, Maleika, Marek, Roth, Wolfgang
• Application Number:
  US13/375,034
• Publication Number:
  US 20120069419A1
• Time in Patent Office: Days
• US Class Current: 359/265
• CPC Class Codes: C09K 9/02 Organic tenebrescent materials
• CPC Class Codes: G02F 1/1503 caused by oxidation-reduction reactions in organic liquid solutions, e.g. viologen solutions

Abstract

Formulations can be used in organically based electrochromic components, such as for the production of state indicators, the activated state of which is maintained for as long as possible without an electric current. Organically based electrochromic formulations contain one or more optionally cathodically (coloring) activatable electrochromic coloring systems, as well as an anodically activatable antagonist formed of an amine which dimerizes to a hydrazinium salt by releasing an electron. Titanium dioxide is introduced as an image background (maximum opacity), and additionally a dispersant is introduced which can be crosslinked or partly crosslinked.

Claims

1-7. -7. (canceled)

8. A bistable switchable electrochromic formulation comprising:

a cathodically switchable electrochromic color system;

an anodically switchable antagonist having the following structure I

9. The formulation as claimed in claim 8, wherein the cathodically switchable electrochromic color system is a 4,4′

-bipyridinium compound or a substituted form thereof.

10. The formulation as claimed in claim 8, wherein the cathodically switchable electrochromic color system is selected from the group consisting of N,N′

-disubstituted saline derivatives of bipyridines and N,N′

-disubstituted saline derivatives of 2,5-di(pyridine-4-yl)pyrimidine.

11. The formulation as claimed in claim 8, wherein the cathodically switchable electrochromic color system is selected from the group consisting of poly-dodecylene-4,4′

-bipyridinium-dibromide and N,N′

-diheptyl-2,5-pyrimidinylene-di-4-pyridinium-dibromide.

12. The formulation as claimed in claim 8, wherein the white pigment is titanium dioxide.

13. The formulation as claimed in claim 8, wherein the dispersing agent is a glycol.

14. The formulation as claimed in claim 8, wherein in the structure I, “

Spacer”

stands for an alkene grouping having from 2 to 6 C atoms.

15. The formulation as claimed in claim 8, wherein in the structure I, A⁻

is an —

SO₃⁻

, —

COO⁻

, or —

O⁻

anion.

16. The formulation as claimed in claim 8, wherein in the structure I, K⁺ is an alkali ion, an ammonium ion, or a substituted alkyl ammonium ion.

17. The formulation as claimed in claim 8, wherein the anodically switchable antagonist is represented by the following formula:

18. The formulation as claimed in claim 8, wherein the anodically switchable antagonist is represented by the following formula:

19. The formulation as claimed in claim 8, wherein the anodically switchable antagonist is represented by the following formula:

20. The formulation as claimed in claim 8, wherein the anodically switchable antagonist is represented by the following formula:

21. A method for producing a bistable switchable electrochromic formulation, comprising:

providing an anodically switchable antagonist having the following structure I

22. An organic electrochromic component comprising:

at least first and second electrodes; and

a bistable switchable electrochromic formulation sandwiched between the first and second electrodes, the electrochromic formulation comprising;

a cathodically switchable electrochromic color system;

an anodically switchable antagonist having the following structure I