Mirrors for concentrating solar power (CSP) or concentrating photovoltaic (CPV) applications, and/or methods of making the same

• US 20120087029A1
• Filed: 10/08/2010
• Published: 04/12/2012
• Est. Priority Date: 10/08/2010
• Status: Abandoned Application

• Current Assignee: Guardian Glass LLC (KOCH Industries Incorporated)
• Original Assignee: Guardian Industries Corporation (KOCH Industries Incorporated)
• Inventors: Vandal, Robert A., Wang, Yei-Ping (Mimi) H.
• Application Number:
  US12/923,836
• Publication Number:
  US 20120087029A1
• Time in Patent Office: Days
• US Class Current: 359/883
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10183 being not continuous, e.g. in edge regions
• CPC Class Codes: B32B 17/1022 Metallic coatings
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: F24S 23/82 characterised by the material or the construction of the reflector
• CPC Class Codes: G02B 5/0816 Multilayer mirrors, i.e. having two or more reflecting layers G02B5/0883, G02B5/0891 take precedence
• CPC Class Codes: G02B 5/085 at least one of the reflecting layers comprising metal
• CPC Class Codes: G02B 5/0875 the reflecting layers comprising two or more metallic layers
• CPC Class Codes: Y02E 10/40 Solar thermal energy, e.g. solar towers

Abstract

Certain example embodiments relate to techniques for creating flat laminated mirrors, e.g., for use in concentrating solar power (CSP) applications. In certain example embodiments, the first substrate is a low iron glass substrate, and the second substrate (which may be thicker than the first substrate) is has a higher iron content than the firsts substrate. A reflective coating is provided between the first and second substrates. The first and second substrates are laminated together with the reflective coating between the substrates. In certain example embodiments a reflective article has a reflectivity above 90%, more preferably about 94.5%.

Claims

1. A method of making an article, the method comprising:

providing a first low-iron glass substrate, the first substrate having a thickness of about 0.5-3 mm;

disposing a reflective coating on a major surface of the first substrate;

providing a second glass substrate substantially parallel to the first substrate, the second substrate being oriented over the reflective coating, the second substrate being at least as thick as the first substrate;

laminating together the first substrate with the reflective coating disposed thereon and the second substrate,

wherein the reflective article has a reflectivity of at least 90 percent.

2. The method of claim 1, wherein the thickness of the first substrate is about 1.6 mm.

3. The method of claim 1, wherein the laminating is accomplished using polyvinyl butyral (PVB).

4. The method of claim 1, further comprising deleting 0.5-5 mm of the reflective coating from around a periphery of the first substrate.

5. The method of claim 3, wherein the PVB has a thickness 0.1-1.0 mm.

6. The method of claim 1, wherein the second substrate is at least twice as thick as the first substrate.

7. The method of claim 6, wherein the second substrate includes more iron than the first substrate.

8. The method of claim 1, wherein the second substrate includes a major surface area that is larger than a major surface area of the first substrate.

9. The method of claim 1, wherein the reflective coating comprises a plurality of thin film layers including a silver-based layer and a copper-based layer over and contacting the silver-based layer.

10. The method of claim 9, wherein the reflective coating further comprises a tin-inclusive layer, the tin-inclusive layer being interposed between and contacting both the first substrate and the silver-based layer.

11. The method of claim 10, wherein the silver-based layer is between about 80 mg per square foot to 95 mg per square foot.

12. The method of claim 11, wherein the silver layer is about 90 mg per square foot.

13. The method of claim 1, wherein the laminating together of the first and second substrates hermetically seals the reflective coating between the first and second substrates.

14. The method of claim 1, wherein the laminating involves heating the first and second substrates according to a heating profile that takes into account the different compositions of the first and second substrates.

15. The method of claim 14, wherein the heating profile involves preferentially heating the first substrate.

16. A method of making an article, the method comprising:

providing a first low-iron glass substrate, the first substrate having a thickness of about 0.5-3 mm;

disposing a multi-layer thin-film reflective coating on a major surface of the first substrate, the reflective coating comprising, in order moving away from the substrate, an tin-inclusive layer, an Ag-inclusive layer directly contacting the tin-inclusive layer, and a copper-inclusive layer directly contacting the Ag-inclusive layer;

providing a second glass substrate substantially parallel to the first substrate, the second substrate being oriented over the reflective coating, the second substrate being at least as thick as the first substrate, the second substrate having an iron content higher than an iron content of the first substrate;

laminating together the first substrate with the reflective coating disposed thereon and the second substrate using a heating profile selected to account for the different heating profiles of the first and second substrates caused by the differing iron contents.

17. The method of claim 16, wherein the second substrate is two or more times as thick as the first substrate.

18. The method of claim 16, wherein the first substrate is less than 2 mm thick and wherein the second substrate is greater than 2 mm thick.

19. The method of claim 16, wherein the heating profile further accounts for the presence of the reflective coating on the first substrate.

20. A coated article, comprising:

a first low-iron glass substrate having a thickness of 0.5-3 mm;

a reflective coating comprising a plurality of thin film layers disposed on a major surface of the first substrate; and

a second substrate that is substantially parallel to the first high transmission substrate, the second substrate having a higher iron content than the first substrate and being at least twice as thick as the first substrate,

wherein the first and second substrates are laminated together with PVB, the PVB hermetically sealing the reflective coating between the first and second substrates,

wherein the reflective article has a reflectivity above 90 percent.