TWO SILICON-CONTAINING PRECURSORS FOR GAPFILL ENHANCING DIELECTRIC LINER

• US 20120094468A1
• Filed: 07/14/2011
• Published: 04/19/2012
• Est. Priority Date: 10/15/2010
• Status: Active Grant

• Current Assignee: Applied Materials Incorporated
• Original Assignee: Applied Materials Incorporated
• Inventors: Hamana, Hiroshi, Gee, Paul Edward, Venkataraman, Shankar, Bhatia, Sidharth
• Granted Patent: US 8,664,127 B2
• Time in Patent Office: Days
• US Class Current: 438/437
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: H01L 21/02126 the material containing Si, O, and at least one of H, N, C, F, or other non-metal elements, e.g. SiOC, SiOC:H or SiONC
• CPC Class Codes: H01L 21/02164 the material being a silicon oxide, e.g. SiO2
• CPC Class Codes: H01L 21/022 the layer being a laminate, i.e. composed of sublayers, e.g. stacks of alternating high-k metal oxides adhesion layers or buffer layers H01L21/02304, H01L21/02362
• CPC Class Codes: H01L 21/02216 the compound being a molecule comprising at least one silicon-oxygen bond and the compound having hydrogen or an organic group attached to the silicon or oxygen, e.g. a siloxane
• CPC Class Codes: H01L 21/02222 the compound being a silazane
• CPC Class Codes: H01L 21/02271 deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition H01L21/02266 takes precedence
• CPC Class Codes: H01L 21/76224 using trench refilling with dielectric materials trench filling with polycristalline silicon H01L21/763; together with vertical isolation, e.g. trench refilling in a SOI substrate H01L21/76264

Abstract

Aspects of the disclosure pertain to methods of depositing silicon oxide layers on substrates. In embodiments, silicon oxide layers are deposited by flowing a silicon-containing precursor having a Si—O bond, an oxygen-containing precursor and a second silicon-containing precursor, having both a Si—C bond and a Si—N bond, into a semiconductor processing chamber to form a conformal liner layer. Upon completion of the liner layer, a gap fill layer is formed by flowing a silicon-containing precursor having a Si—O bond, an oxygen-containing precursor into the semiconductor processing chamber. The presence of the conformal liner layer improves the ability of the gap fill layer to grow more smoothly, fill trenches and produce a reduced quantity and/or size of voids within the silicon oxide filler material.

Claims

1. A method for filling a trench with silicon oxide wherein the trench is on a patterned substrate within a substrate processing region of a semiconductor processing chamber, the method comprising the sequential operations of:

forming a conformal silicon oxide liner layer by concurrently flowing a first silicon-containing precursor, a second silicon-containing precursor and an oxygen-containing precursor into the substrate processing region, wherein the first silicon-containing precursor comprises a Si—

O bond, and the second silicon-containing precursor comprises a Si—

C bond and a Si—

N bond; and

forming a silicon oxide gapfill layer by concurrently flowing the first silicon-containing precursor and the oxygen-containing precursor into the substrate processing region.

2. The method of claim 1 wherein the first silicon-containing precursor comprises at least one precursor selected from the group consisting of tetraethyl orthosilicate, tetramethoxysilane and triethoxysilane.

3. The method of claim 2 wherein a flow rate of the first silicon-containing precursor is about 500 mg per minute or greater during deposition of the silicon oxide.

4. The method of claim 1 wherein the oxygen-containing precursor comprises at least one precursor selected from the group consisting of ozone (O₃), oxygen (O₂) and oxygen radicals (O).

5. The method of claim 1 wherein the method further comprises flowing water vapor into the semiconductor processing chamber during the operation of forming the conformal silicon oxide liner layer.

6. The method of claim 1 wherein the method further comprises flowing water vapor into the semiconductor processing chamber during the operation of forming the silicon oxide gapfill layer.

7. The method of claim 1 wherein the second silicon-containing precursor comprises hexamethyl disilazane.

8. The method of claim 1 wherein flowing the second silicon-containing precursor comprises flowing the second silicon-containing precursor at a flow rate greater than 1 mg per minute during deposition of the conformal silicon oxide liner layer.

9. The method of claim 1 wherein the second silicon-containing precursor comprises tetramethyl disilazane.

10. The method of claim 1 comprising filling the trench with the conformal silicon oxide liner layer and the silicon oxide gapfill layer.

11. The method of claim 1 wherein a width of the trench is 40 nm or less.

12. The method of claim 1 wherein the trench comprises a silicon surface, a silicon nitride surface, and a silicon oxide surface upon which the conformal silicon oxide liner layer is formed.

13. The method of claim 1 wherein a temperature of the patterned substrate is less than 600°

C. during the operation of forming the conformal silicon oxide liner layer and the operation of forming the silicon oxide gapfill layer.

14. The method of claim 1 wherein a temperature of the patterned substrate is less than 400°

C. during the operation of forming the conformal silicon oxide liner layer and the operation of forming the silicon oxide gapfill layer.

15. The method of claim 1 wherein a pressure in the substrate processing region is below 700 torr during the operation of forming the conformal silicon oxide liner layer and the operation of forming the silicon oxide gapfill layer.

16. The method of claim 1 wherein a thickness of the conformal silicon oxide liner layer is less than or about 40 nm.

17. The method of claim 1 wherein a thickness of the conformal silicon oxide liner layer is between about 5 nm and about 30 nm.

18. The method of claim 1 further comprising flowing the second silicon-containing precursor during formation of the silicon oxide gapfill layer, wherein a flow rate of the second silicon-containing precursor into the substrate processing region during formation of the silicon oxide gapfill layer is less than a flow rate of the second silicon-containing precursor during formation of the conformal silicon oxide liner layer.

19. The method of claim 1 wherein essentially no flow of the second silicon-containing precursor enters the substrate processing region during formation of the silicon oxide gapfill layer.