BATTERY RESETTING PROCESS FOR SCAFFOLD FUEL ELECTRODE

• US 20120098499A1
• Filed: 10/19/2011
• Published: 04/26/2012
• Est. Priority Date: 10/20/2010
• Status: Active Grant

• Current Assignee: Form Energy, Inc.
• Original Assignee: Fluidic, Inc.
• Inventors: FRIESEN, Cody A., KRISHNAN, Ramkumar, PUZHAEV, Sergey, TRIMBLE, Todd
• Granted Patent: US 9,105,946 B2
• Time in Patent Office: Days
• US Class Current: 320/137
• CPC Class Codes: H01M 10/42 Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells H01M10/60 takes precedence
• CPC Class Codes: H01M 10/4207 for several batteries or cells simultaneously or sequentially
• CPC Class Codes: H01M 10/4242 Regeneration of electrolyte or reactants
• CPC Class Codes: H01M 10/425 Structural combination with electronic components, e.g. electronic circuits integrated to the outside of the casing printed circuits H05K1/00
• CPC Class Codes: H01M 10/44 Methods for charging or discharging circuits for charging H02J7/00
• CPC Class Codes: H01M 10/46 Accumulators structurally combined with charging apparatus circuits for charging H02J7/00
• CPC Class Codes: H01M 12/08 composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
• CPC Class Codes: H01M 50/70 Arrangements for stirring or circulating the electrolyte
• CPC Class Codes: H01M 50/77 with external circulating path
• CPC Class Codes: H01M 8/249 comprising two or more groupings of fuel cells, e.g. modular assemblies
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

An electrochemical cell includes a fuel electrode configured to operate as an anode to oxidize a fuel when connected to a load. The cell also includes an oxidant electrode configured to operate as a cathode to reduce oxygen when connected to the load. The fuel electrode comprises a plurality of scaffolded electrode bodies. The present invention relates to an electrochemical cell system and method of resetting the electrochemical cell by applying a charge (i.e. voltage or current) to the cell to drive oxidation of the fuel, wherein the fuel electrode operates as an anode, and the second cell operates as a cathode, removing uneven distributions of fuel that may cause premature shorting of the electrode bodies to improve capacity, energy stored, and cell efficiency.

Claims

1. A method for resetting an electrochemical cell, the electrochemical cell comprising:

a fuel electrode comprising a series of permeable electrode bodies arranged in spaced apart relation for receiving electrodeposited metal fuel;

an oxidant electrode spaced from the fuel electrode;

a charging electrode;

an ionically conductive medium contacting the electrodes;

the fuel electrode and the oxidant electrode being configured to, during discharge, oxidize the metal fuel at the fuel electrode and reduce an oxidant at the oxidant electrode to generate a electrical discharge current therebetween for application to a load; and

the fuel electrode and the charging electrode being configured to, during re-charge, reduce a reducible species of the fuel to electrodeposit the fuel on the fuel electrode and oxidize an oxidizable species of the oxidant by application of a electrical recharge current therebetween from a power source;

the method comprising;

applying an electrical reset current between the fuel electrode and at least one other aforesaid electrode of the cell with the fuel electrode functioning as an anode and the other aforesaid electrode functioning as a cathode, such that the metal fuel on the fuel electrode is oxidized into the reducible fuel species; and

removing the electrical reset current to discontinue the resetting process.

2. The method of claim 1, wherein the electrical reset current between the fuel electrode and the other aforesaid electrode provides approximately a potential difference capable of oxidizing a metal fuel on the fuel electrode, and reducing an oxidant at the other aforesaid electrode.

3. The method of claim 1, further comprising repeating the method a plurality of times.

4. The method of claim 1, further comprising determining if a resetting process is needed for the electrochemical cell, prior to applying the electrical reset current from the power source.

5. The method of claim 4, wherein determining if the resetting process is needed for the electrochemical cell comprises:

sensing a present charge capacity for the electrochemical cell;

comparing the present charge capacity to an initial charge capacity; and

if the present charge capacity is less than an initial charge capacity by a greater than a threshold amount, determining that a resetting process is needed.

6. The method of claim 4, wherein determining if the resetting process is needed comprises determining if a predetermined amount of elapsed time has occurred since the electrochemical cell was last discharged, or since the electrochemical cell was last reset.

7. The method of claim 6, wherein the predetermined amount of elapsed time contains a randomized time interval.

8. The method of claim 4 wherein determining if the resetting process is needed for the electrochemical cell comprises:

sensing a present voltage between the permeable electrode bodies;

comparing the present voltage to an initial voltage; and

if the present voltage is less than the initial voltage by greater than a threshold amount, determining that a resetting process is needed.

9. The method of claim 4, wherein determining if the resetting process is needed for the electrochemical cell comprises:

sensing a present resistance between the permeable electrode bodies;

comparing the present resistance to an initial resistance; and

if the present resistance is less than the initial resistance by greater than a threshold amount, determining that a resetting process is needed.

10. The method of claim 4, wherein determining if the resetting process is needed for the electrochemical cell comprises:

determining if the cell is entering a passivation regime where the metal fuel has an increased likelihood of passivating; and

,

if the cell is entering the passivation regime, applying the electrical reset current, wherein the electrical reset current corresponds to oxidizing the metal fuel in a transpassive regime, where the metal fuel has a decreased likelihood of passivating.

11. The method of claim 10, further comprising, prior to applying the electrical reset current, controlling the present voltage and/or the electrical discharge current to consume a threshold amount of the fuel without entering the passivation regime.

12. The method of claim 1, wherein the electrical reset current is approximately above 0 mA/cm2 through 10 mA/cm2.

13. The method of claim 1, wherein the electrical reset current corresponds to a reset voltage of above −

1V through 1V.

14. The method of claim 1, wherein the charging electrode is selected from the group consisting of (a) the oxidant electrode, (b) a third electrode spaced from the oxidant electrode, and (c) a portion of the fuel electrode.

15. The method of claim 14, wherein the charging electrode during recharge is a dynamic charging electrode comprising at least some of the permeable electrode bodies.

16. The method of claim 14, wherein the charging electrode is the oxidant electrode, and the other aforesaid electrode is thus also the oxidant electrode, and wherein the other aforesaid electrode reduces oxygen.

17. The method of claim 14, wherein the charging electrode is the third electrode, and the other aforesaid electrode is the oxidant electrode, and wherein the other aforesaid electrode reduces oxygen.

18. The method of claim 14, wherein the charging electrode is the third electrode, and the other aforesaid electrode is also the third electrode, and wherein the other aforesaid electrode reduces water in the ionically conductive medium.

19. The method of claim 14, wherein the charging electrode is the third electrode, and the other aforesaid electrode is also the third electrode, and wherein the other aforesaid electrode reduces oxygen dissolved within the ionically conductive medium.

20. The method of claim 1, wherein the electrochemical cell further comprises an electrode holder comprising a cavity for holding the fuel electrode, a plurality of inlets connected to the cavity on one side of the cavity and configured to supply the ionically conductive medium to the cavity, and a plurality of outlets connected to the cavity on an opposite side of the cavity and configured to allow the ionically conductive medium to flow out of the cavity.

21. The method of claim 20, wherein the electrochemical cell further comprises a plurality of spacers extending across the fuel electrode and the cavity in a spaced relation from each other to define a plurality of flow lanes in the cavity, wherein one of the plurality of inlets and one of the plurality of outlets are associated with each flow lane so that the ionically conductive medium flows into each flow lane via the associated inlet, across the fuel electrode, and out of the flow lane via the associated outlet.

22. The method of claim 21, further comprising flowing the ionically conductive medium through the inlets and into the flow lanes, prior to applying the electrical reset current from the power source.

23. The method of claim 1, wherein the electrochemical cell further comprises an electrode holder comprising a cavity for holding the fuel electrode, and a passageway through which the ionically conductive medium flows into the cavity, wherein the cavity comprises a plurality of fluidization zones, each fluidization zone being at least partially defined by diverging surfaces where the passageway is connected to the cavity, the fluidization zones being configured to fluidize precipitates in the ionically conductive medium as the ionically conductive medium flows into the cavity.

24. The method of claim 23, further comprising flowing the ionically conductive medium into the fluidization zones prior to applying the electrical reset current from the power source.

25. An electrochemical cell system comprising:

an electrochemical cell comprising;

a fuel electrode comprising a series of permeable electrode bodies arranged in spaced apart relation for receiving electrodeposited metal fuel;

an oxidant electrode spaced apart from the fuel electrode;

a charging electrode;

an ionically conductive medium communicating the electrodes;

circuitry configured to provide electrical connections between the electrodes, a power input circuit, and a power output circuit;

a plurality of switches in the circuitry, configured to selectively open or close the electrical connections the between the electrodes, the power input circuit, and the power output circuit;

wherein the cell is configured to generate an electrical discharge current by oxidizing the metal fuel on the electrode bodies of the fuel electrode and reducing an oxidizer at the oxidant electrode; and

wherein the spaced apart relation of said permeable electrode bodies of the fuel electrode enables an electrical recharge current to be applied between the charging electrode and at least one of the permeable anode bodies with the charging electrode functioning as an anode and the at least one permeable electrode body functioning as a cathode, such that reducible fuel ions are reduced and electrodeposited from the ionically conductive medium as fuel in oxidizable form on the at least one permeable electrode body, whereby the electrodeposition causes growth of the fuel among the permeable electrode bodies such that the electrodeposited fuel establishes an electrical connection between the permeable electrode bodies; and

a controller configured to control an open state or a closed state of each of the plurality of switches of the electrochemical cell, wherein the controller is further configured to initiate a resetting process by;

selectively operating the plurality of switches to apply an electrical reset current from a power source to the power input circuit and between the fuel electrode and at least one other aforesaid electrode with the fuel electrode functioning as an anode and the other aforesaid electrode functioning as a cathode, such that the metal fuel on the fuel electrode is oxidized into a reducible fuel species; and

selectively operating the plurality of switches to remove the electrical reset current to discontinue the resetting process.

26. The electrochemical cell system of claim 25, wherein the controller is configured to determine if the resetting process is needed for the electrochemical cell, prior to applying an electrical reset current from the power source.

27. The electrochemical cell system of claim 26, wherein determining if the resetting process is needed for the electrochemical cell comprises:

sensing a present charge capacity for the electrochemical cell;

comparing the present charge capacity to an initial charge capacity; and

if the present charge capacity is less than an initial charge capacity by a greater than a threshold amount, determining that a resetting process is needed.

28. The electrochemical cell system of claim 26, wherein determining if the resetting process is needed comprises determining if a predetermined amount of elapsed time has occurred since the electrochemical cell was last discharged, or since the electrochemical cell was last reset.

29. The electrochemical cell system of claim 28, wherein the predetermined amount of elapsed time contains a randomized time interval.

30. The electrochemical cell system of claim 26, wherein determining if the resetting process is needed comprises determining if a predetermined number of discharge and recharge cycles have occurred since the electrochemical cell was initially charged or last reset.

31. The electrochemical cell system of claim 26, wherein determining if the resetting process is needed comprises determining if a randomized number of discharge and recharge cycles have occurred since the electrochemical cell was initially charged or last reset.

32. The electrochemical cell system of claim 26, wherein determining if the resetting process is needed for the electrochemical cell comprises:

sensing a present voltage between the permeable electrode bodies;

comparing the present voltage to an initial voltage; and

if the present voltage is less than the initial voltage by greater than a threshold amount, determining that a resetting process is needed.

33. The electrochemical cell system of claim 26, wherein determining if the resetting process is needed for the electrochemical cell comprises:

sensing a present resistance between the permeable electrode bodies;

comparing the present resistance to an initial resistance; and

if the present resistance is less than the initial resistance by greater than a threshold amount, determining that a resetting process is needed.

34. The electrochemical cell system of claim 26, wherein determining if the resetting process is needed for the electrochemical cell comprises:

determining if the cell is entering a passivation regime where the metal fuel has an increased likelihood of passivating; and

,

if the cell is entering the passivation regime, applying the electrical reset current, wherein the electrical reset current corresponds to oxidizing the metal fuel in a transpassive regime, where the metal fuel has a decreased likelihood of passivating.

35. The electrochemical cell system of claim 25, wherein the electrical reset current is approximately above 0 mA/cm2 through 10 mA/cm2.

36. The electrochemical cell system of claim 25, wherein the electrical reset current corresponds to a reset voltage of above −

1V through 1V.

37. The electrochemical cell system of claim 25, wherein the charging electrode is selected from the group consisting of (a) the oxidant electrode, (b) a third electrode spaced from the oxidant electrode, and (c) a portion of the fuel electrode.

38. The electrochemical cell system of claim 37, wherein the charging electrode during re-charge is a dynamic charging electrode comprising at least some of the permeable electrode bodies.

39. The electrochemical cell system of claim 37, wherein the charging electrode is the oxidant electrode, and the other aforesaid electrode is thus also the oxidant electrode, and wherein the other aforesaid electrode reduces oxygen.

40. The electrochemical cell system of claim 37, wherein the charging electrode is the third electrode, and the other aforesaid electrode is the oxidant electrode, and wherein the other aforesaid electrode reduces oxygen.

41. The electrochemical cell system of claim 37, wherein the charging electrode is the third electrode, and the other aforesaid electrode is also the third electrode, and wherein the other aforesaid electrode reduces water in the ionically conductive medium.

42. The electrochemical cell system of claim 37, wherein the charging electrode is the third electrode, and the other aforesaid electrode is also the third electrode, and wherein the other aforesaid electrode reduces oxygen dissolved within the ionically conductive medium.

43. The electrochemical cell system of claim 25, further comprising a plurality of the electrochemical cell and a second plurality of switches therebetween, wherein the controller is further configured to selectively open and/or close the second plurality of switches to apply the electrical reset current from the power source to the power input circuits of one or more of the plurality of the electrochemical cell.

44. The electrochemical cell system of claim 43, wherein the controller is further configured to determine if a resetting process is needed for each of the plurality of electrochemical cells, and if the resetting process is needed for at least some of the plurality of electrochemical cells, initiating the resetting process for the at least some of the plurality of electrochemical cells.