PECVD SHOWERHEAD CONFIGURATION FOR CMP UNIFORMITY AND IMPROVED STRESS

• US 20120108066A1
• Filed: 10/28/2011
• Published: 05/03/2012
• Est. Priority Date: 10/28/2010
• Status: Active Grant

• Current Assignee: Texas Instruments, Inc.
• Original Assignee: Texas Instruments, Inc.
• Inventors: New, Jason James, Pavone, Salvatore Frank
• Granted Patent: US 8,470,614 B2
• Time in Patent Office: Days
• US Class Current: 438/692
• CPC Class Codes: C23C 16/402 Silicon dioxide
• CPC Class Codes: C23C 16/45565 Shower nozzles
• CPC Class Codes: H01L 21/02164 the material being a silicon oxide, e.g. SiO2
• CPC Class Codes: H01L 21/02271 deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition H01L21/02266 takes precedence
• CPC Class Codes: H01L 21/31053 involving a dielectric removal step

Abstract

A dielectric deposition tool for forming a silicon dioxide layer on a wafer with a TEOS showerhead which delivers a flow rate per unit area from an edge band of the showerhead that is at least twice a flow rate per unit area from a central region of the showerhead. The edge band extends at least one half inch from an outer edge of the showerhead up to one fourth of the diameter of the wafer. A process of forming an integrated circuit by forming a silicon dioxide layer on a wafer containing the integrated circuit using the dielectric deposition tool. The silicon dioxide layer is thicker under the edge band than under the central region. A subsequent CMP operation reduces the thickness difference between the wafer outer annulus and the wafer core by at least half. The silicon dioxide layer has a compressive stress between 125 and 225 MPa.

Claims

1. A dielectric deposition tool for forming a dielectric layer on a wafer, comprising:

a tetraethylorthosilicate (TEOS) delivery showerhead, said wafer being disposed under said showerhead, said showerhead including;

an input port, said input port configured to receive TEOS gas;

an interior region connected to said input port, said interior region configured to distribute said TEOS gas; and

a bottom plate abutting said interior region, said bottom plate including an edge band and a central region, such that;

said edge band extends from an outer edge of said bottom plate at least one half an inch and up to one fourth of a diameter of said wafer;

said bottom plate includes a set of edge TEOS delivery apertures in said edge band, said edge TEOS delivery apertures being configured to deliver said TEOS gas from said interior region to said wafer;

said bottom plate includes a set of central TEOS delivery apertures in said central region, said central TEOS delivery apertures being configured to deliver said TEOS gas from said interior region to said wafer; and

so that an area percentage of said edge TEOS delivery apertures is at least twice an area percentage of said central TEOS delivery apertures, in which;

said area percentage of said edge TEOS delivery apertures is calculated by dividing a total area of said edge TEOS delivery apertures by an area of said edge band; and

said area percentage of said central TEOS delivery apertures is calculated by dividing a total area of said central TEOS delivery apertures by an area of said central region.

2. The dielectric deposition tool of claim 1, in which an average area of an instance of said edge TEOS delivery apertures is at least twice an average area of an instance of said central TEOS delivery apertures.

3. The dielectric deposition tool of claim 2, in which:

said edge TEOS delivery apertures are substantially circular and substantially equal in size to each other;

said central TEOS delivery apertures are substantially circular and substantially equal in size to each other; and

an average diameter of said edge TEOS delivery apertures is between 45 and 60 percent larger than an average diameter of said central TEOS delivery apertures.

4. The dielectric deposition tool of claim 2, in which said edge TEOS delivery apertures are non-circular and substantially equal in size and shape to each other.

5. The dielectric deposition tool of claim 1, in which:

said edge TEOS delivery apertures are substantially circular and substantially equal in size to each other;

said central TEOS delivery apertures are substantially circular and substantially equal in size to each other; and

an area density of said edge TEOS delivery apertures is at least twice an area density of said central TEOS delivery apertures, in which;

said area density of said edge TEOS delivery apertures is calculated by dividing a total number of said edge TEOS delivery apertures by an area of said edge band; and

said area density of said central TEOS delivery apertures is calculated by dividing a total number of said central TEOS delivery apertures by an area of said central region.

6. The dielectric deposition tool of claim 1, in which said interior region of said showerhead includes a diffuser which delivers an average flow rate of TEOS gas per unit area at said edge band which is at least twice an average flow rate of TEOS gas in said central region.

7. The dielectric deposition tool of claim 1, in which said showerhead is configured to deliver TEOS gas to a 200 mm wafer.

8. The dielectric deposition tool of claim 1, in which said showerhead is configured to deliver TEOS gas to a 300 mm wafer.

9. The dielectric deposition tool of claim 1, in which said showerhead is configured so as to form a silicon dioxide layer on said wafer in which an average thickness of said silicon dioxide layer under said edge band is between 3 and 5 percent more than an average thickness of said silicon dioxide layer under said central region.

10. The dielectric deposition tool of claim 1, in which said showerhead is configured so as to form a silicon dioxide layer on said wafer, in which said silicon dioxide layer has a compressive stress between 125 and 225 megapascals (MPa).

11. A process of forming an integrated circuit, comprising steps:

disposing a wafer containing said integrated circuit in a dielectric deposition tool under a TEOS delivery showerhead of said dielectric deposition tool, said showerhead including;

an input port, said input port configured to receive TEOS gas;

an interior region connected to said input port, said interior region configured to distribute said TEOS gas; and

a bottom plate abutting said interior region, said bottom plate including an edge band and a central region, such that;

said edge band extends from an outer edge of said bottom plate at least one half an inch and up to one fourth of a diameter of said wafer;

said bottom plate includes a set of edge TEOS delivery apertures in said edge band, said edge TEOS delivery apertures being configured to deliver said TEOS gas from said interior region to said wafer;

said bottom plate includes a set of central TEOS delivery apertures in said central region, said central TEOS delivery apertures being configured to deliver said TEOS gas from said interior region to said wafer; and

so that an area percentage of said edge TEOS delivery apertures is at least twice an area percentage of said central TEOS delivery apertures, in which;

said area percentage of said edge TEOS delivery apertures is calculated by dividing a total area of said edge TEOS delivery apertures by an area of said edge band; and

said area percentage of said central TEOS delivery apertures is calculated by dividing a total area of said central TEOS delivery apertures by an area of said central region;

forming a layer of silicon dioxide on a top surface of said wafer by providing TEOS gas to said input port, so that;

an average flow rate per unit area of said TEOS gas from said edge band of said showerhead is at least twice an average flow rate per unit area of said TEOS gas from said central region of said showerhead; and

said silicon dioxide layer is thicker in a wafer outer annulus under said edge band of said showerhead than in a wafer core under said central region of said showerhead;

planarizing said silicon dioxide layer using a chemical mechanical polish (CMP) process, so that a thickness difference between an average thickness in said wafer outer annulus and an average thickness in said wafer core after completion of said CMP process is less than half a thickness difference between an average thickness in said wafer outer annulus and an average thickness in said wafer core after formation of said silicon dioxide layer and before said CMP process.

12. The process of claim 11, in which an average area of an instance of said edge TEOS delivery apertures is at least twice an average area of an instance of said central TEOS delivery apertures.

13. The process of claim 12, in which:

said edge TEOS delivery apertures are substantially circular and substantially equal in size to each other;

said central TEOS delivery apertures are substantially circular and substantially equal in size to each other; and

an average diameter of said edge TEOS delivery apertures is between 45 and 60 percent larger than an average diameter of said central TEOS delivery apertures.

14. The process of claim 12, in which said edge TEOS delivery apertures are non-circular and substantially equal in size and shape to each other.

15. The process of claim 11, in which:

said edge TEOS delivery apertures are substantially circular and substantially equal in size to each other;

said central TEOS delivery apertures are substantially circular and substantially equal in size to each other; and

an area density of said edge TEOS delivery apertures is at least twice an area density of said central TEOS delivery apertures, in which;

said area density of said edge TEOS delivery apertures is calculated by dividing a total number of said edge TEOS delivery apertures by an area of said edge band; and

said area density of said central TEOS delivery apertures is calculated by dividing a total number of said central TEOS delivery apertures by an area of said central region.

16. The process of claim 11, in which said interior region of said showerhead includes a diffuser which delivers an average flow rate of TEOS gas per unit area at said edge band which is at least twice an average flow rate of TEOS gas in said central region.

17. The process of claim 11, in which:

said showerhead is configured to deliver TEOS gas to a 200 mm wafer; and

a flow rate of said TEOS gas is such as provided by a flow rate of TEOS in liquid phase between 2.1 and 3.2 cubic centimeters per minute.

18. The process of claim 11, in which said showerhead is configured to deliver TEOS gas to a 300 mm wafer.

19. The process of claim 11, in which an average thickness of said silicon dioxide layer under said edge band is between 3 and 5 percent more than an average thickness of said silicon dioxide layer under said central region after formation of said silicon dioxide layer and before said CMP process.

20. The process of claim 11, in which said silicon dioxide layer has a compressive stress between 125 and 225 megapascals (MPa).