POLYURETHANE MATERIALS COMPRISING CARBON NANOTUBES

• US 20120112133A1
• Filed: 03/05/2010
• Published: 05/10/2012
• Est. Priority Date: 03/13/2009
• Status: Abandoned Application

• Current Assignee: Bayer Materialscience AG (Covestro AG)
• Original Assignee: Bayer Materialscience AG (Covestro AG)
• Inventors: Meyer, Helmut, Bahnmüller, Stefan, Dijkstra, Dirk, Henning, Wolfgang, Koning, Cornelis Eme, Van Steenis, Jan Hein, Mulders, Steffan Franciscus Marjo
• Application Number:
  US13/255,931
• Publication Number:
  US 20120112133A1
• Time in Patent Office: Days
• US Class Current: 252/511
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C08G 18/0828 containing sulfonate groups or groups forming them
• CPC Class Codes: C08G 18/12 using two or more compounds having active hydrogen in the first polymerisation step
• CPC Class Codes: C08G 18/3857 having nitrogen in addition to sulfur
• CPC Class Codes: C08G 18/4238 derived from dicarboxylic acids and dialcohols
• CPC Class Codes: C08G 18/664 with compounds of group C08G18/3203
• CPC Class Codes: C08G 18/73 acyclic
• CPC Class Codes: C08G 18/755 and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
• CPC Class Codes: C08J 2375/04 Polyurethanes
• CPC Class Codes: C08J 2375/06 from polyesters
• CPC Class Codes: C08J 3/215 at least one additive being also premixed with a liquid phase
• CPC Class Codes: C08J 5/005 Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials
• CPC Class Codes: C08K 3/041 Carbon nanotubes
• CPC Class Codes: C08L 75/06 from polyesters
• CPC Class Codes: C09D 175/06 from polyesters

Abstract

The invention relates to semicrystalline polyurethane (PU) compositions which have been filled with carbon nanotubes (CNTs) and have improved electrical properties, and which are obtainable on the basis of water-based polyurethane-CNT mixtures. The invention further relates to a process for producing the polyurethane compositions, in which water-based polyurethane latices are mixed with carbon nanotubes dispersed in water. The invention further relates to films produced by pressurized injection moulding processes or processing of casting solutions.

Claims

1-17. -17. (canceled)

18. An electrically conductive polyurethane composition comprising at least one polyurethane polymer and carbonaceous nanoparticles, wherein the at least one polyurethane polymer has a substantial portion of semicrystalline polyurethane, and wherein the carbonaceous nanoparticles comprise at least 20% carbon nanotubes.

19. The electrically conductive polyurethane composition according to claim 18, wherein the at least one polyurethane polymer has at least 10% by weight of semicrystalline polyurethane.

20. The electrically conductive polyurethane composition according to claim 18, wherein the carbonaceous nanoparticles consists essentially of carbon nanotubes.

21. The electrically conductive polyurethane composition according to claim 18, wherein the electrically conductive polyurethane composition comprises at least 0.1% by weight of carbonaceous nanoparticles.

22. The electrically conductive polyurethane composition according to claim 18, wherein the electrically conductive polyurethane composition comprises not more than 8% by weight.

23. The electrically conductive polyurethane composition according to claim 18, wherein the conductivity of the polyurethane composition is at least 1·

10<sup>−

5</sup> S/cm.

24. The electrically conductive polyurethane composition according to claim 23, wherein the carbonaceous nanoparticles consists of carbon nanotubes, and the proportion of the carbon nanotubes in the composition is not more than 3% by weight.

25. The electrically conductive polyurethane composition according to claim 18, wherein the carbon nanotubes have a ratio of length to external diameter of greater than 5.

26. The electrically conductive polyurethane composition according to claim 18, wherein the carbon nanotubes essentially have a mean diameter of 3 to 100 nm.

27. The electrically conductive polyurethane composition according to claim 18, wherein the carbon nanotubes comprise scroll type carbon nanotubes.

28. The electrically conductive polyurethane composition according to claim 18, wherein the semicrystalline polyurethane is formed from

A. at least one difunctional aliphatic or aromatic polyesterpolyol with a molecular weight of 400 to 5000 g/mol,

B. optionally difunctional or higher-functionality polyol components with a molecular weight of 62 to 399,

C. at least one di- or polyisocyanate component and

D. optionally one or more aminic chain extenders.

29. The electrically conductive polyurethane composition according to claim 18, wherein the semicrystalline polyurethane is based on polyurethane dispersions.

30. The electrically conductive polyurethane composition according to claim 18, wherein the semicrystalline polyurethane is partly crystalline and has, in the DSC analysis, a melting or crystallization peak which corresponds to a melting enthalpy of at least 5 J/g.

31. The electrically conductive polyurethane composition according to claim 18, wherein the polyurethane composition further comprises a filler, a reinforcer, a stabilizer, a dispersant, an additive, or mixtures thereof.

37. A coating in motor vehicle construction or a housing of an electrical appliance comprising the polyurethane composition according to claim 18.

32. A process for producing an electrically conductive polyurethane composition, comprising

a) preparing an aqueous dispersion of carbonaceous nanoparticles,

b) mixing the dispersion of the carbonaceous nanoparticles with an aqueous polyurethane dispersion,

c) removing water from the mixture,

d) hardening the dried product from step c) by applying heat,

wherein the polyurethane dispersion is based on substantial amounts of semicrystalline polyurethane.

33. The process according to claim 32, wherein the polyurethane dispersion is based on at least 20% by weight of semicrystalline polyurethane.

34. The process according to claim 32, wherein, in the preparation of the aqueous dispersion of the carbonaceous nanoparticles a), a surface-active substance is added as a dispersant.

35. The process according to claim 32, wherein the surface-active substance is selected from the group consisting of hydrocarbon sulphates or sulphonates, which includes sodium dodecylsulphonate (SDS), the polyalkylene oxide-based dispersants, the water-dispersible pyrrolidones, or block copolymers which are surface-active in an aqueous medium.

36. The process according to claim 32, wherein the aqueous dispersion is prepared in step a) by employing ultrasound.