FIBROUS SUBSTRATE WITH A SOLID HYPOHALITE PRECIPITATE FORMED THEREIN AND PROCESS OF MAKING

• US 20120141568A1
• Filed: 01/28/2011
• Published: 06/07/2012
• Est. Priority Date: 12/03/2010
• Status: Active Grant

• Current Assignee: Clorox Company
• Original Assignee: Clorox Company
• Inventors: Privitera, Marc P., Smith, William L., White, Edward Jason, Adams, Leslie N.
• Granted Patent: US 8,268,770 B2
• Time in Patent Office: Days
• US Class Current: 424/409
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 25/10 Macromolecular compounds
• CPC Class Codes: A01N 25/34 Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
• CPC Class Codes: A01N 59/00 Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
• CPC Class Codes: B08B 1/143 Wipes
• CPC Class Codes: B32B 2250/20 All layers being fibrous or filamentary
• CPC Class Codes: B32B 2262/02 Synthetic macromolecular fibres
• CPC Class Codes: B32B 2262/04 Cellulosic plastic fibres, e.g. rayon
• CPC Class Codes: B32B 2262/06 Vegetal fibres
• CPC Class Codes: B32B 2262/14 Mixture of at least two fibres made of different materials
• CPC Class Codes: B32B 2264/10 Inorganic particles
• CPC Class Codes: B32B 2432/00 Cleaning articles, e.g. mops, wipes personal care B32B2555/00
• CPC Class Codes: B32B 5/08 the fibres or filaments of a layer being of different substances , e.g. conjugate fibres, mixture of different fibres
• CPC Class Codes: B32B 5/26 another layer next to it also being fibrous or filamentary relative arrangement of fibres or filaments of different layers B32B5/12
• CPC Class Codes: C11D 3/3953 Inorganic bleaching agents C11D3/3951 takes precedence

Abstract

A cleaning substrate which comprises at least one layer of a solid hypohalite precipitate, wherein the hypohalite precipitate is formed in situ on the layer of substrate material. A process for making a fibrous cleaning substrate comprising the steps of: a) providing at least one layer of fibrous material; b) exposing the fibrous layer to an aqueous alkaline earth salt solution; c) treating the fibrous layer with a hypochlorite solution; d) allowing the aqueous alkaline earth salt solution combine with the hypochlorite solution to form a solid hypochlorite precipitate around the fibers in the fibrous material and a liquid phase, and e) removing at least 65% of the liquid phase from the fibrous substrate.

Claims

1. A process for making a hypochlorite-releasing substrate comprising the steps of:

a. providing at least one layer of fibrous material comprising synthetic fibers;

b. treating the fibrous layer to an effective amount of an aqueous alkaline earth salt solution,

c. treating the fibrous layer with an effective amount of a hypochlorite solution, and

d. allowing the aqueous alkaline earth salt solution combine with the hypochlorite solution to form a solid hypochlorite precipitate around the fibers in the fibrous material and a liquid phase, and

e. removing at least 65% of the liquid phase from the substrate.

2. The process for making a hypochlorite-releasing substrate according to claim 1, wherein the alkaline earth salt solution selected from the group consisting of:

magnesium chloride, calcium chloride, calcium hydroxide, magnesium hydroxide and any mixtures or combinations thereof.

3. The process for making a hypochlorite-releasing substrate according to claim 1, wherein the hypochlorite solution comprises compounds selected from the group consisting of:

sodium hypochlorite, potassium hypochlorite, lithium hypochlorite, calcium hypochlorite, magnesium hypochlorite, hypochlorous acid, and any mixtures of combinations thereof.

4. The process for making a hypochlorite-releasing substrate according to claim 1, wherein the fibrous material comprises fibers selected from the group consisting of:

natural cellulose, regenerated cellulose, polyester, acrylic, nytril, cellulose ester, olefin, vinyl and any combinations or mixtures thereof.

5. The process for making a hypochlorite-releasing substrate according to claim 1, wherein the fibers are selected from the group consisting of:

polypropylene, polyethylene, polyester and any mixtures or combinations thereof.

6. The process for making a hypochlorite-releasing substrate according to claim 1, wherein the solid hypochlorite precipitate contains salts selected from the group consisting of:

hypochlorite monohydrate salt, hypochlorite dihydrate salt, hemibasic hypochlorite salt, monobasic hypochlorite salt, dibasic hypochlorite salt, anhydrous hypochlorite salt, and mixtures and combinations thereof.

7. A fibrous hypochlorite-releasing substrate according to claim 1 wherein the substrate comprises two or more layers of fibrous materials.

8. A fibrous hypochlorite-releasing substrate according to claim 1 wherein the solid hypochlorite precipitate forms around the fibers in the fibrous material.

9. A fibrous hypochlorite-releasing substrate according to claim 1 wherein the solid hypochlorite precipitate adheres to the substrate without the aid of binders, adhesives, glues, tackifying agents, or the like.

14. The process for making a hypochlorite-releasing substrate according to claim 9, further comprising a step of adding bleach stable surfactants to at least one fibrous layer.

10. The process for making a hypochlorite-releasing substrate comprising the steps of:

a. providing at a first layer of fibrous material comprising fibers selected from the group consisting of;

natural cellulose, regenerated cellulose, polyester, acrylic, nytril, cellulose ester, olefin, vinyl and any combinations or mixtures thereof,

b. treating the first fibrous layer to an effective amount of an aqueous alkaline earth salt solution,

c. providing a second layer of fibrous material comprising synthetic fibers;

d. treating the second fibrous layer with an effective amount of a hypochlorite solution, and

e. contacting the first layer of fibrous material with the second layer of fibrous material and allowing the aqueous alkaline earth salt solution combine with the hypochlorite solution to form a solid hypochlorite precipitate.

11. The process for making a hypochlorite-releasing substrate according to claim 10, wherein the alkaline earth salt solution selected from the group consisting of:

magnesium chloride, calcium chloride, calcium hydroxide, magnesium hydroxide and any mixtures or combinations thereof.

12. The process for making a hypochlorite-releasing substrate according to claim 10, wherein at least one of the fibrous material layers is selected from the group consisting of:

spunbond, meltblown, SMS, carded, wetlaid, airlaid, thermalbonded, hydroentangled, through-air bonded, needled, chemical bonded, and combinations thereof.

13. The process for making a hypochlorite-releasing substrate according to claim 10, wherein the fibers from at least one of the fibrous layers are selected from the group consisting of:

polypropylene, polyethylene, polyester and any mixtures or combinations thereof including bicomponent and multicomponent fibers.

15. The process for making a hypochlorite-releasing substrate according to claim 10 further comprising the step of adding an additive selected from the group consisting of:

emulsifiers, pH adjusters, silicones, non-ionic surfactants, cationic surfactants, amphoteric surfactants, zwitterionic surfactants, anionic surfactants, soil release agents, soil release polymers, antistatic agents, fragrances, fragrance extenders, antimicrobial actives, preservatives, dyes, colorants, viscosity control agents, antifoaming agents, pearlizing agents, opacifying agents, antioxidants, sunscreens, dye transfer inhibitors, dye fixative agents, dispersants, chlorine scavengers, wetting agents, electrolytes, enzymes, brighteners, heavy metal chelating agents, fabric softener actives, soil suspending agents, soil release agents, and mixtures thereof.

16. A process for making a hypochlorite-releasing substrate comprising the steps of:

a. providing at least one layer of fibrous material comprising synthetic fibers;

b. treating the fibrous layer to an effective amount of an aqueous alkaline earth salt solution,

c. treating the fibrous layer with an effective amount of a hypochlorite solution, and

d. allowing the aqueous alkaline earth salt solution combine with the hypochlorite solution to form a solid hypochlorite precipitate around the fibers in the fibrous material and a liquid phase, and

e. adding at least one surfactant to the substrate.

17. The process of making a hypochlorite-releasing substrate according to claim 16, wherein the substrate comprises two or more layers of materials.

18. The process of making a hypochlorite-releasing substrate according to claim 16, wherein the surfactant is added to the substrate as a liquid solution which co-precipitates as the hypochlorite precipitates forms on the substrate.

19. The process of making a hypochlorite-releasing substrate according to claim 17, wherein the hypochlorite precipitate resides in a fibrous layer and the surfactant resides in a separate layer of the substrate.

20. The process of making a hypochlorite-releasing substrate according to claim 16, wherein the surfactant is selected from the group consisting of:

secondary alkyl sulfates, amine oxides, caustic neutralized fatty acids, caustic neutralized lauric acid, and any combinations thereof.