CHEMICAL OXIDATION OR ELECTROMAGNETIC TREATMENT IN SAGD OPERATIONS

• US 20120152546A1
• Filed: 12/17/2010
• Published: 06/21/2012
• Est. Priority Date: 12/17/2010
• Status: Active Grant

• Current Assignee: BL Technologies Inc. (Ashland Global Holdings, Inc.)
• Original Assignee: BL Technologies Inc. (Ashland Global Holdings, Inc.)
• Inventors: Polizzotti, David M., Neculaes, Vasile Bogdan, Khwaja, Abdul Rafi, Moore, Brian Christopher, Petersen, Matthew Alan
• Granted Patent: US 9,731,989 B2
• Time in Patent Office: Days
• US Class Current: 166/305.1
• CPC Class Codes: C02F 1/28 by sorption using ion-exchange C02F1/42; sorbent compositions B01J
• CPC Class Codes: C02F 1/302 with microwaves
• CPC Class Codes: C02F 1/42 by ion-exchange ion-exchange in general B01J
• CPC Class Codes: C02F 1/441 by reverse osmosis
• CPC Class Codes: C02F 1/442 by nanofiltration
• CPC Class Codes: C02F 1/46 by electrochemical methods
• CPC Class Codes: C02F 1/52 by flocculation or precipitation of suspended impurities C02F1/463 takes precedence
• CPC Class Codes: C02F 1/72 by oxidation C02F1/4672 takes precedence
• CPC Class Codes: C02F 2103/365 from petrochemical industry (e.g. refineries)
• CPC Class Codes: C02F 3/00 Biological treatment of water, waste water, or sewage C02F1/006 takes precedence
• CPC Class Codes: C02F 5/025 Hot-water softening devices
• CPC Class Codes: C02F 9/00 Multistage treatment of water, waste water or sewage
• CPC Class Codes: E21B 43/2406 Steam assisted gravity drainage [SAGD]
• CPC Class Codes: E21B 43/40 Separation associated with re-injection of separated materials E21B43/385 takes precedence

Abstract

A system for treating produced water, for example from a SAGD bitumen production operation, has a treatment unit using chemical oxidation (CO) or electromagnetic treatment (ET) to destroy or degrade organics in the produced water. The treatment module may use CO or ET in combination with biological treatment or sorption processes or both. When the treatment module is used upstream of a steam generator, it reduces fouling in the steam generator and in any blowdown water treatment device. A brine concentrator or a crystallizer may be used to treat the blowdown water. The treatment module may be used in combination with a nanofiltration (NF) or reverse osmosis (RO) membrane filter. Optionally, the produced water may be treated with an ET process such as microwaves directly upstream of a steam generator or upstream of a concentrator or crystallizer in a blowdown water stream.

Claims

1. A process for treating produced water for re-use comprising a step of degrading organics in the produced water by way of chemical oxidation or electromagnetic treatment.

2. The process of claim 1, further comprising a step of biodegrading the treated organics.

3. The process of claim 1, further comprising a step of passing the produced water with degraded organics through a sorption media.

4. The process of claim 1, further comprising a step of passing the produced water with degraded organics through a steam generator.

5. The process of claim 4, further comprising steps of:

separating a liquid blowdown from an output from the steam generator; and

treating the liquid blowdown in a crystallizer.

6. The process of claim 1, wherein the step of degrading organics in the produced water comprises treating the produced water with microwaves.

7. The process of claim 1, wherein the step of degrading organics in the produced water comprises adding an oxidant to the produced water.

8. The process of claim 1, further comprising steps of:

passing the produced water through a steam generator;

separating a liquid blowdown from an output from the steam generator; and

treating the liquid blowdown in a crystallizer,

wherein the step of degrading organics in the produced water by way of chemical oxidation or electromagnetic treatment is applied to the liquid blowdown upstream of the crystallizer.

9. The process of claim 8, wherein the step of degrading organics in the produced water comprises treating the blowdown with microwaves.

10. The process of claim 1, further comprising a step of passing the produced water through a nanofiltration or reverse osmosis membrane after the step of degrading organics in the produced water.

11. The process of claim 10, further comprising a step of treating the produced water by biodegredation or sorption between the steps of degrading organics in the produced water and passing the produced water through a nanofiltration or reverse osmosis membrane.

12. The process of claim 1, further comprising a step of passing the produced water through a resin exchange softener after the step of degrading organics in the produced water.

13. The process of claim 1, further comprising steps of:

passing the produced water through a steam generator; and

separating a liquid blowdown from an output from the steam generator,

wherein the step of degrading organics in the produced water by way of chemical oxidation or electromagnetic treatment comprises treating the liquid blowdown with microwaves to produce a dried solid and a vapor.

14. The process of claim 1, further comprising a step of:

biodegrading the treated organics or passing the produced water with treated organics through a sorption media; and

after the step above, passing the produced water through a steam generator.

15. The process of claim 1, comprising a step of lime softening the produced water prior to the step of degrading or mineralizing organics in the produced water by way of chemical oxidation or electromagnetic treatment.

16. The process of claim 1, wherein the produced water is drawn from a steam assisted gravity drainage production well, the produced water with degraded organics passes through a once through steam generator, and generated steam is injected into the ground above the production well.

17. A system for treating produced water from a steam assisted gravity drainage production well to produce steam for injection into the ground above the production well comprising:

a) a once through steam generator;

b) a crystallizer connected to receive blowdown water from the once through steam generator; and

,

c) a chemical oxidation or electromagnetic treatment module located upstream of the once through steam generator or so as to intercept the blowdown water upstream of the crystallizer.

18. The system of claim 17, further comprising a bioreactor or a sorption column downstream of the chemical oxidation or electromagnetic treatment module and located either upstream of the once through steam generator or so as to intercept the blowdown water upstream of the crystallizer.

19. A system for treating produced water from a steam assisted gravity drainage production well to produce steam for injection into the ground above the production well comprising:

a) a once through steam generator;

b) a chemical oxidation or electromagnetic treatment module located upstream of the once through steam generator or so as to intercept the blowdown water upstream of the crystallizer; and

,

c) a nanofiltration or reverse osmosis membrane filter downstream of the chemical oxidation or electromagnetic treatment module.

20. The system of claim 19, further comprising a bioreactor or a sorption column downstream of the chemical oxidation or electromagnetic treatment module and upstream of the membrane filter.