PROCESS FOR RECOVERY OF PROPYLENE AND LPG FROM FCC FUEL GAS USING STRIPPED MAIN COLUMN OVERHEAD DISTILLATE AS ABSORBER OIL

• US 20120172649A1
• Filed: 06/09/2010
• Published: 07/05/2012
• Est. Priority Date: 07/02/2009
• Status: Active Grant

• Current Assignee: Reliance Industries Limited
• Original Assignee: Reliance Industries Limited
• Inventors: Yadav, Manoj, Mandal, Sukumar, Das, Asit Kumar, Gupta, Yogesh, Makhania, Minaz, Tulsi, Gobind, Arora, Shailendra, Jaguste, Shubhangi
• Granted Patent: US 8,618,344 B2
• Time in Patent Office: Days
• US Class Current: 585/809
• CPC Class Codes: C10G 11/18 according to the "fluidised-bed" technique
• CPC Class Codes: C10G 2300/301 Boiling range
• CPC Class Codes: C10G 2400/20 C2-C4 olefins
• CPC Class Codes: C10G 2400/26 Fuel gas
• CPC Class Codes: C10G 2400/28 Propane and butane
• CPC Class Codes: C10G 31/06 by heating, cooling, or pressure treatment
• CPC Class Codes: C10G 5/04 with liquid absorbents
• CPC Class Codes: C10G 5/06 by cooling or compressing
• CPC Class Codes: C10G 53/08 including at least one sorption step
• CPC Class Codes: C10G 55/06 including at least one catalytic cracking step
• CPC Class Codes: C10G 7/02 Stabilising gasoline by removing gases by fractioning
• CPC Class Codes: C10G 70/06 by gas-liquid contact

Abstract

A process is disclosed for enhanced recovery of propylene and LPG from the fuel gas produced in Fluid catalytic cracking unit by contacting a heavier hydrocarbon feed with FCC catalyst. In the conventional process, the product mixture from FCC main column overhead comprising naphtha, LPG and fuel gas, are first condensed and gravity separated to produce unstabilized naphtha, which is subsequently used in the absorber to absorb propylene and LPG from fuel gas. However, the recovery of propylene beyond 97 wt % is difficult in this process since unstabilized naphtha already contains propylene of 5 mol % or above. In the present invention, C₄ and lighter components from unstabilized naphtha are first stripped off in a separate column to obtain a liquid fraction almost free from propylene (<0.1 mol %) and other LPG components. Such a stripped liquid fraction, after cooling to 20° C. to 30° C., is used in the absorber to absorb higher amounts of propylene and LPG from fuel gas, leading to improved recovery of propylene.

Claims

1. An improved process for the recovery of propylene and C₄s from a product mixture obtained by contacting a hydrocarbon feed with a catalyst in a fluid catalytic cracking process, wherein said recovery is achieved by following sequence of steps:

(i) distilling the above said product mixture in main fractionator to obtain heavier liquid products as side/bottom draws and a gaseous top product consisting of components boiling below 215°

C.,

(ii) cooling and condensing the gaseous top product and thereafter, separating the obtained gas-liquid mixture in a receiver cum separator to obtain a liquid fraction referred to as ‘

Unstabilized naphtha’ and

a lighter gaseous fraction,

(iii) sequentially compressing, cooling and separating in a two stage Wet Gas compressor train said gaseous fraction obtained from step (ii) to finally obtain gaseous and liquid fractions from a high pressure separator,

(iv) feeding the liquid fraction obtained in step (iii) to a de-ethanizer wherein Ethane and lighter components stripped off from the feed are recycled back to high pressure receiver in step (iii) whereas the de-ethanized liquid product is fed to debutanizer column,

(v) separating butane and lighter components present in the debutanizer feed as overhead gaseous fraction and obtaining heavier fraction as bottom product referred to as debutanizer bottoms,

(vi) feeding unstabilized naphtha obtained in step (ii) to a naphtha stripper wherein lighters stripped off from feed are recycled to step (ii) and heavier liquid fraction, after cooling to about 30°

C. to 40°

C., is used as lean oil in the absorber in step (vii),

(vii) contacting gaseous fraction obtained from high pressure separator in step (iii) in an absorber with the liquid fraction as obtained in step (vi) and a part of the debutanizer bottoms as obtained in step (v),

(viii) feeding the rich oil from the absorber bottom liquid to de-ethanizer via high pressure receiver,

characterized by further stripping of the unstabilized naphtha as obtained in step (ii), said stripping achieved by feeding the said unstabilized naphtha as obtained in step (ii) to an intermediate stripper column, wherein lighter components present in the feed are stripped off to obtain a heavier liquid fraction having an initial boiling point of between from about 25°

C. to about 50°

C. and said heavier fraction, after cooing to about 20°

C. to 30°

C., is used as lean oil in the absorber in step (vii) and the lighters stripped off from unstabilized naphtha are recycled back to main fractionator overhead condensers in step (ii).

2. The process as claimed in claim 1, wherein the main fractionator overhead condenser pressure is from about 10 psig and above, preferably 25 psig and above.

3. The process as claimed in claim 1 wherein the stripped naphtha is supplied to the absorber at lower temperatures preferably between from about 20°

C. to about 30°

C. using chilled water as an indirect cooling media wherein recovery of propylene and other C₃-C₄ components is further improved.

4. The process as claimed in claim 1, wherein the debut bottom recycle and absorber oil from external inter-stage coolers is supplied to absorber at about 20°

C. to 30°

C. by using chilled water as cooling media in cooling exchangers.

5. A process as claimed in claim 1, wherein the gaseous fraction from the absorber optionally further treated before leaving the FCC gas concentration section as Fuel gas.

6. (canceled)