ION SELECTIVE ELECTRODE CARTRIDGE

• US 20120175254A1
• Filed: 09/17/2010
• Published: 07/12/2012
• Est. Priority Date: 09/18/2009
• Status: Abandoned Application

• Current Assignee: Hitachi Chemical Company Limited (Resonac Holdings Corp.)
• Original Assignee: Hitachi Chemical Company Limited (Resonac Holdings Corp.)
• Inventors: Uchida, Tsuyoshi, Kobayashi, Teruyuki
• Application Number:
  US13/496,595
• Publication Number:
  US 20120175254A1
• Time in Patent Office: Days
• US Class Current: 204/403.02
• CPC Class Codes: G01N 27/27 Association of two or more measuring systems or cells, each measuring a different parameter, where the measurement results may be either used independently, the systems or cells being physically associated, or combined to produce a value for a further parameter
• CPC Class Codes: G01N 27/283 Means for supporting or introducing electrochemical probes
• CPC Class Codes: G01N 27/333 Ion-selective electrodes or membranes glass electrodes G01N27/36
• CPC Class Codes: G01N 27/4035 Combination of a single ion-sensing electrode and a single reference electrode G01N27/406 and G01N27/413 take precedence

Abstract

Ion concentration measurement requires a calibration before the start of the measurement, and thus the start of the measurement is delayed for the calibration period. Hence, an ion selective electrode cartridge including an ion selective electrode for measuring the concentration of particular ions dissolved in a test solution is provided with a storage means storing therein an electrode slope value specific to the ion selective electrode.

Claims

1. An ion selective electrode cartridge equipped with an ion selective electrode for measuring a concentration of particular ions in a test solution, the ion selective electrode cartridge comprising:

a storage means for storing an electrode slope value specific to the ion selective electrode.

2. The ion selective electrode cartridge according to claim 1, wherein the storage means includes one or more storage means selected from a one-dimensional barcode, a two-dimensional barcode, and an IC tag.

3. The ion selective electrode cartridge according to claim 1, wherein

the storage means comprises a readable and writable storage medium, and

the total number of uses of the ion selective electrode cartridge is recorded at every measurement of the concentration of the particular ions.

4. The ion selective electrode cartridge according to claim 1, wherein the electrode slope value is calculated from the following expression:

(E_H−

E_L)/Log(C_H/C_L),

(where E_H represents an electromotive force in measuring a high-concentration reference solution, E_L represents an electromotive force in measuring a low-concentration reference solution, C_H represents a particular ion concentration in the high-concentration reference solution, and C_L represents a particular ion concentration in the low-concentration reference solution).

5. The ion selective electrode cartridge according to claim 1, wherein

the storage means stores a percentage change of the electrode slope value, and

the percentage change is used for correcting the electrode slope value every predetermined number of measurements.

6. The ion selective electrode cartridge according to claim 1, comprising:

a container into which the test solution is infused;

a reference electrode; and

one or more of the ion selective electrodes which each form an electrical path with the reference electrode when the test solution is infused, and wherein

the ion selective electrode and the reference electrode are arranged to surround the container.

7. The ion selective electrode cartridge according to claim 1, comprising a positioning mechanism configured to define a positional relationship between the electrodes.

8. The ion selective electrode cartridge according to claim 6, wherein

the container is arranged in the center of a casing, and

the ion selective electrode and the reference electrode are arranged at regular intervals on concentric circles around the center of the container.

9. The ion selective electrode cartridge according to claim 8, comprising two or more of the ion selective electrodes, and wherein

the reference electrode and the ion selective electrodes are arranged evenly spaced on concentric circles around the center of the container.

10. The ion selective electrode cartridge according to claim 8, wherein the casing has a cylindrical shape or a polygonal columnar shape.

11. The ion selective electrode cartridge according to claim 6, comprising a discharge hole for a reference solution in a bottom portion of the container.

12. The ion selective electrode cartridge according to claim 1, wherein the particular ions include one or more species of ions selected from the group of sodium ions, potassium ions, chloride ions, calcium ions, magnesium ions, bicarbonate ions, lithium ions, zinc ions, copper ions, and iron ions.

13. The ion selective electrode cartridge according to claim 1, wherein the test solution is a solution derived from any of blood, urine, soil and water.

14. A method for manufacturing the ion selective electrode cartridge according to claim 1, the method comprising:

forming at least one electrode film corresponding to the ion selective electrode over an electrode film formation hole of the ion selective electrode cartridge, and wherein

the forming includes;

cooling a mixed solution containing a composition material for the electrode film to a predetermined temperature at or below freezing point;

casting the mixed solution into the electrode film formation hole; and

forming the electrode film by drying the mixed solution after the casting in an atmosphere maintained at a temperature of 6 degrees C. to 8 degrees C. and at a humidity of 70% or lower.