METHOD FOR THE PRODUCTION OF STRETCHABLE ELECTRODES

• US 20120177934A1
• Filed: 01/14/2010
• Published: 07/12/2012
• Est. Priority Date: 07/22/2009
• Status: Abandoned Application

• Current Assignee: Bayer Materialscience AG (Covestro AG)
• Original Assignee: Bayer Materialscience AG (Covestro AG)
• Inventors: Vogel, Stephanie, Wagner, Joachim, Fussangel, Christel
• Application Number:
  US13/384,300
• Publication Number:
  US 20120177934A1
• Time in Patent Office: Days
• US Class Current: 428/457
• CPC Class Codes: H01G 11/32 Carbon-based
• CPC Class Codes: H01M 4/13 Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
• CPC Class Codes: H01M 4/139 Processes of manufacture
• CPC Class Codes: H01M 4/621 Binders
• CPC Class Codes: H01M 4/622 being polymers
• CPC Class Codes: H01M 4/625 Carbon or graphite
• CPC Class Codes: H01M 4/663 containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres
• CPC Class Codes: H10N 30/06 Forming electrodes or interconnections, e.g. leads or terminals
• CPC Class Codes: H10N 30/878 the principal material being non-metallic, e.g. oxide or carbon based
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/13 Energy storage using capacitors
• CPC Class Codes: Y10T 428/31678 Of metal

Abstract

The invention relates to a method for producing stretchable electrodes, where electrically conductive carbon particles, especially carbon nanotubes, are introduced into a coating comprising an elastomer. In said method, a preparation of non-aggregated carbon particles having an average particle diameter ranging from=0.3 nm to=3000 nm in a solvent acts upon a coating comprising an elastomer. The solvent can cause a coating comprising an elastomer to swell. The duration of the action is calculated so as to be insufficient to dissolve the elastomer. Optionally, another electrically conductive layer is applied. The invention also relates to a stretchable electrode obtained in said manner and to the use thereof.

Claims

1-15. -15. (canceled)

16. A process for producing extensible electrodes having a surface layer comprising electrically conductive carbon particles, which comprises the steps:

(A) provision of an elastomer which has a glass transition temperature T_g of from ≧

−

130°

C. to ≦

0°

C. and in which the stress σ

does not decrease with increasing elongation;

(B) provision of a preparation of unaggregated carbon particles having an average particle diameter of from ≧

0.3 nm to ≧

3000 nm in a solvent which is able to bring about swelling of a surface layer of the elastomer;

(C) contacting of the surface layer of the elastomer with the preparation of the carbon particles;

(D) acting of the preparation of the carbon particles on the surface layer of the elastomer for a time which is insufficient to bring the elastomer into solution; and

(E) ending of the action of the preparation of the carbon particles on the surface layer of the elastomer.

17. The process as claimed in claim 16, which further comprises the step:

(F) application of an additional electrically conductive layer to the surface layer comprising electrically conductive carbon particles obtained in steps (B) to (E), where the additional electrically conductive layer obtained breaks up or ruptures on elongation of the surface layer before the latter does.

18. The process as claimed in claim 16, wherein the acting of the preparation of the carbon particles on the surface layer of the elastomer in step (D) takes place using ultrasound and/or heat.

19. The process as claimed in claim 16, wherein the carbon particles are selected from the group consisting of carbon nanotubes, single-wall carbon nanotubes, multiwall carbon nanotubes, carbon nanohorns, carbon nanoonions, fullerenes, graphite, graphene, carbon fibers, carbon black and/or conductive carbon black.

20. The process as claimed in claim 16, wherein the solvent is selected from the group consisting of methanol, ethanol, isopropanol, butanol, ethylene glycol, propylene glycol, butylene glycol, glycerol, hydroquinone, acetone, ethyl acetate, trichloroethylene, trichloroethane, trichloromethane, methylene chloride, cyclohexanone, N,N-dimethylformamide, dimethyl sulfoxide, tetrahydrofuran, N-methyl-2-pyrrolidone, benzene, toluene, chlorobenzene, styrene, polyester polyols, polyether polyols, methyl ethyl ketone, ethylene glycol monobutyl ether, diethylene glycol, mixtures of the abovementioned solvents with one another and mixtures of the abovementioned solvents with water.

21. The process as claimed in claim 16, wherein the elastomer is selected from the group consisting of polyacrylate, acrylic ester rubber, polyacrylonitrile, poly(acrylonitrile-co-butadiene-co-styrene), poly(acrylonitrile-co-methyl methacrylate), polyamide, polyamideimide, polyester, polyether ether ketone, polyether ester, polyethylene, ethylene-propylene rubber, poly(ethylene-co-tetrafluoroethylene), poly(ethylene-co-vinyl acetate), poly(ethylene-co-vinyl alcohol), fluorosilicones, perfluoroalkoxy polymers, (natural) rubber, poly(methyl methacrylate-co-acrylonitrile-co-butadiene-co-styrene), poly(methyl methacrylate-co-butadiene-co-styrene), nitriles, olefins, polyphosphazenes, polypropylene, poly(methyl methacrylate), polyurethanes, polyvinyl chloride, polyvinyl fluorides and silicones.

22. The process as claimed in claim 16, wherein the surface layer of the elastomer is partly covered by a mask, at least in step (D).

23. An extensible electrode comprising an elastomer having a surface layer (1) which comprises electrically conductive carbon particles and can be obtained by a process as claimed in claim 16, wherein the elastomer has a glass transition temperature T_g of from ≧

−

130°

C. to ≦

0°

C. and, furthermore, the stress σ

does not decrease with increasing elongation in the elastomer.

24. The electrode as claimed in claim 23, wherein the carbon particles are present in the surface layer (1) to a depth of ≦

10 μ

m below the surface.

25. The electrode as claimed in claim 23, wherein the carbon particles are present within the elastomer material of the surface layer (1) surrounding them in a proportion of from ≧

0.1% by weight to ≦

10% by weight.

26. The electrode as claimed in claim 23 having a specific resistance to the surface layer (1) of from ≧

10<sup>−

3</sup> ohm cm to ≦

10⁸ ohm cm.

27. The electrode as claimed in claim 23 having a first (1) and a second (2) surface layer comprising electrically conductive carbon particles, wherein said first (1) and second (2) surface layers are arranged opposite one another and are separated from one another by an elastomer layer (3).

28. The electrode as claimed in claim 23 which further comprises an additional electrically conductive layer (4) arranged on the surface layer (1) comprising electrically conductive carbon particles, where the additional electrically conductive layer (4) breaks up or ruptures on elongation of the surface layer (1) before the latter does.

29. The electrode as claimed in claim 28, wherein the additional electrically conductive layer (4) comprises gold, silver, copper, indium-tin oxide, fluorine-doped tin(IV) oxide, aluminum-doped zinc oxide, antimony-doped tin(IV) oxide and/or poly(3,4-ethylenedioxythiophene).

30. The use of an electrode as claimed in claim 23 as electromechanical transducer, as electromechanical actuator and/or as electromechanical sensor.