Bi-modal Poly-alpha-olefin Blend

• US 20120178333A1
• Filed: 01/06/2012
• Published: 07/12/2012
• Est. Priority Date: 01/07/2011
• Status: Abandoned Application

• Current Assignee: Rextac Llc
• Original Assignee: Rextac Llc
• Inventors: Fowler, James Nicholas, Buenacosa, Enrico, Haselman, James
• Application Number:
  US13/345,428
• Publication Number:
  US 20120178333A1
• Time in Patent Office: Days
• US Class Current: 442/398
• CPC Class Codes: B32B 2262/0253 Polyolefin fibres vinyl or acrylic copolymers B32B2262/0223 or B32B2262/0246
• CPC Class Codes: B32B 2270/00 Resin or rubber layer containing a blend of at least two different polymers
• CPC Class Codes: B32B 2307/54 Yield strength; Tensile strength
• CPC Class Codes: B32B 2307/702 Amorphous
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/12 next to a fibrous or filamentary layer
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 5/022 Non-woven fabric
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: C08L 2205/02 containing two or more polymers of the same C08L -group
• CPC Class Codes: C08L 23/145 Copolymers of propene with monomers having more than one C=C double bond
• CPC Class Codes: C08L 23/18 Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
• CPC Class Codes: C09J 123/145 Copolymers of propene with monomers having more than one C=C double bond
• CPC Class Codes: C09J 123/18 Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
• CPC Class Codes: Y10T 428/2826 Synthetic resin or polymer
• CPC Class Codes: Y10T 442/678 Olefin polymer or copolymer sheet or film [e.g., polypropylene, polyethylene, ethylene-butylene copolymer, etc.]

Abstract

A low viscosity, high tensile strength polymer having a bi-modal molecular weight distribution is produced using a combination of high molecular weight polymer and low molecular weight polymer. The polymer chains have a high content of meso dyads that results in a greater amount of crystalline regions when the polymer is solidified. The low molecular weight chains provide high flow characteristics when the polymer is molten. The process for producing the high content of meso dyads includes the use of an external donor catalyst during the reaction.

Claims

1. A blended polymer composition that is useful as a hot-melt adhesive consisting essentially of:

a) a high molecular weight, high tensile strength alpha-olefin polymer; and

;

b) a low molecular weight, high tensile strength polymer.

2. A blended polymer composition as recited in claim 1 wherein the alpha-olefin polymer is prepared by an atactic poly-alpha-olefin polymerization process that utilizes an external donor catalyst.

3. A composition comprising:

a polymer blend according to claim 1;

a compatible tackifier at a level of from about 0 to about 90% by weight;

a wax at a level of from about 0 to about 80% by weight; and

, at least one other olefin polymer at a level of from about 0 to about 90% by weight.

4. An adhesive comprising a polymer according to claim 1.

5. A bonded structure made by a process comprising:

applying an adhesive as recited in claim 4 to a first layer; and

,

bonding the adhesive-bearing first layer to a second layer.

6. A blended polymer composition as recited in claim 1 wherein the low molecular weight, high tensile strength polymer is prepared by vis-breaking a polymer in the presence of a peroxide to achieve a viscosity in the range of about 300 cps to about 800 cps.

7. A blended polymer composition as recited in claim 6 wherein the viscosity of the low molecular weight, high tensile strength polymer is about 625 cps.

8. A process for preparing a blended polymer composition comprising:

preparing a first propylene/1-butene copolymer characterized by a propylene content of 25 to 50 weigh percent, a 1-butene content of 75 to 50 weight percent and a tensile strength of at least 300 psig by reacting propylene and 1-butene monomers in the presence of a catalyst system comprising;

(a) a solid supported catalyst component is prepared by the method comprising;

(i) co-comminuting magnesium halide support base and aluminum trihalide in a molar ratio from about 8;

0.5 to about 8;

3 in the absence of added electron donor; and

(ii) then co-comminuting the product of step (i) in the absence of added electron donor with sufficient titanium tetrahalide to provide a molar ratio of magnesium halide to titanium tetrahalide from about 8;

0.1 to about 8;

1.0

(b) a trialkylaluminum co-catalyst, having from 1 to 9 carbon atoms in each alkyl group in an amount such that the Al/Ti ratio is between about 50;

1 and about 500;

1

(c) an alkoxy silane component of the formula R_n Si(OR′

)_4-n where n=1-3, R=aryl or alkyl and R′

=C_1-3 alkyl in a sufficient quantity such that the molar ratio of organoaluminum co-catalyst to alkoxy silane is in the range from about 20;

1 to about 45;

1

preparing a second propylene/1-butene copolymer by feeding a portion of the first copolymer to an extruder while simultaneously feeding a peroxide to a downstream port of the extruder; and

,

blending the first copolymer with the second copolymer.

9. A process as recited in claim 8 wherein the peroxide is 2,5 dimethyl 2,5-di-t-butylperoxy hexane.

10. A process as recited in claim 8 wherein the first copolymer is about 45% butane and about 55% propylene.

11. A process as recited in claim 8 wherein the first copolymer has a viscosity of about 8000 cps (at 375°

F.) and the second copolymer has a viscosity of about 625 cps (at 375°

F.).

12. A process as recited in claim 8 wherein the first copolymer and second copolymer are blended at a ratio of about 70% second copolymer to about 30% first copolymer.

13. A process as recited in claim 12 wherein the viscosity of the 70/30 blend is about 1235 cps (at 375°

F.).

14. A process as recited in claim 9 wherein the peroxide is fed to the extruder at a rate of about 10 milliliters per minute when the first copolymer is fed to the extruder at a rate of about 50 pounds per hour.

15. A lamination made by a process comprising:

melting a polymer blend prepared by a process according to claim 8 in a hot melt unit;

applying the melted polymer blend to a polyethylene film; and

,

thereafter laminating a polypropylene nonwoven fabric to the polyethylene film in the region of the applied melted polymer blend.

16. A lamination as recited in claim 15 wherein the melted polymer blend is applied to the polyethylene film through a controlled fiberization nozzle.

17. A process as recited in claim 8 further comprising adding a compatible tackifier at a level of from about 0 to about 90% by weight to the blended copolymers.

18. A process as recited in claim 8 further comprising adding a wax at a level of from about 0 to about 80% by weight to the blended copolymers.

19. A process as recited in claim 8 further comprising adding another olefin polymer at a level of from about 0 to about 90% by weight to the blended copolymers.

20. A process as recited in claim 8 further comprising adding at least one hot-melt adhesive additive to the blended copolymers.