WHOLLY AROMATIC LIQUID CRYSTAL POLYESTER RESIN COMPOUND, PREPARATION METHOD THEREOF, PARTS FOR OPTICAL PICKUP, AND PREPARATION METHOD THEREOF

• US 20120199790A1
• Filed: 10/21/2010
• Published: 08/09/2012
• Est. Priority Date: 10/21/2009
• Status: Abandoned Application

• Current Assignee: Samsung Fine Chemicals Company Limited (Lotte Chemical Corporation)
• Original Assignee: Samsung Fine Chemicals Company Limited (Lotte Chemical Corporation)
• Inventors: Yun, Jong Hwa, Kim, Hyun Min, Kim, Mahn Jong
• Application Number:
  US13/501,955
• Publication Number:
  US 20120199790A1
• Time in Patent Office: Days
• US Class Current: 252/299.5
• CPC Class Codes: C08G 63/605 the hydroxy and carboxylic groups being bound to aromatic rings
• CPC Class Codes: C08L 101/12 characterised by physical features, e.g. anisotropy, viscosity or electrical conductivity liquid crystal materials or compositions C09K19/00
• CPC Class Codes: C08L 2205/02 containing two or more polymers of the same C08L -group
• CPC Class Codes: C08L 67/00 Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain of polyester-amides C08L77/12; of polyester-imides C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: G02B 1/04 made of organic materials, e.g. plastics G02B1/08 takes precedence

Abstract

Disclosed are a wholly aromatic liquid crystal polyester resin compound, a preparation method thereof, parts for optical pickup, and a preparation method thereof. The disclosed wholly aromatic liquid crystal polyester resin compound comprises two kinds of wholly aromatic liquid crystal polyester resins having different melting points and an additive, and most of the terminal groups in the resins having lower melting points among the resins comprise a carboxyl group.

Claims

1. A wholly aromatic liquid crystalline polyester resin compound comprising:

a first wholly aromatic liquid crystalline polyester resin having a higher melting point (T_m1);

a second wholly aromatic liquid crystalline polyester resin having a lower melting point (T_m2); and

an additive,

wherein the higher melting point T_m1 of the first wholly aromatic liquid crystalline polyester resin and the lower melting point T_m2 of the second wholly aromatic liquid crystalline polyester resin satisfy the following condition;

370°

C.≦

T_m1≦

440°

C.,

310°

C.≦

T_m2≦

380°

C., and

20°

C.≦

T_m1−

T_m2≦

80°

C.

2. The wholly aromatic liquid crystalline polyester resin compound of claim 1, wherein the second wholly aromatic liquid crystalline polyester resin comprises a repeating unit A derived from an aromatic hydroxycarboxylic acid, a repeating unit B derived from an aromatic diol, and a repeating unit C derived from an aromatic dicarboxylic acid:

wherein the repeating units A, B, and C satisfy the following condition;

40 mol %≦

repeating unit A/total repeating units≦

60 mol %,

10 mol %≦

repeating unit B/total repeating units≦

30 mol %,

80 mol %≦

repeating unit B/repeating unit C≦

100 mol %.

3. The wholly aromatic liquid crystalline polyester resin compound of claim 2, wherein the repeating unit A is derived from at least one compound selected from the group consisting of p-hydroxy benzoic acid and 2-hydroxy-6-naphthoic acid, the repeating unit B is derived from at least one compound selected from the group consisting of biphenol and hydroquinone, and the repeating unit C is derived from at least one compound selected from the group consisting of isophthalic acid, naphthalene dicarboxylic acid, and terephthalic acid.

4. The wholly aromatic liquid crystalline polyester resin compound of claim 3, wherein the repeating unit C of the second wholly aromatic liquid crystalline polyester resin satisfies the following condition:

15 mol %≦

repeating unit C₂ derived from isophthalic acid/(repeating unit C₁ derived from terephthalic acid+repeating unit C₂ derived from isophthalic acid)≦

35 mol %.

5. The wholly aromatic liquid crystalline polyester resin compound of claim 1, wherein the amount of the second wholly aromatic liquid crystalline polyester resin is in the range of 5 to 40 parts by weight based on 100 parts by weight of the first wholly aromatic liquid crystalline polyester resin.

6. The wholly aromatic liquid crystalline polyester resin compound of claim 1, wherein the additive comprises at least one additive selected from the group consisting of an inorganic additive comprising glass fiber, talc, calcium carbonate, mica, clay, or any mixture of at least two thereof and an organic additive comprising carbon fiber, and

the amount of the additive is in the range of 10 to 100 parts by weight based on 100 parts by weight of the total amount of the first wholly aromatic liquid crystalline polyester resin and the second wholly aromatic liquid crystalline polyester resin.

7. Parts for optical pick-up comprising a wholly aromatic liquid crystalline polyester resin compound according to claim 1.

9. Parts for optical pick-up comprising a wholly aromatic liquid crystalline polyester resin compound according to claim 2.

10. Parts for optical pick-up comprising a wholly aromatic liquid crystalline polyester resin compound according to claim 3.

11. Parts for optical pick-up comprising a wholly aromatic liquid crystalline polyester resin compound according to claim 4.

12. Parts for optical pick-up comprising a wholly aromatic liquid crystalline polyester resin compound according to claim 5.

13. Parts for optical pick-up comprising a wholly aromatic liquid crystalline polyester resin compound according to claim 6.

8. A method of preparing a wholly aromatic liquid crystalline polyester resin compound, the method comprising:

mixing 100 parts by weight of a first wholly aromatic liquid crystalline polyester resin having a higher melting point T_m1, 5 to 40 parts by weight of a second wholly aromatic liquid crystalline polyester resin having a lower melting point T_m2, and 10 to 100 parts by weight of an additive based on 100 parts by weight of the total amount of the first wholly aromatic liquid crystalline polyester resin and the second wholly aromatic liquid crystalline polyester resin, and melt-kneading the mixture,

wherein the higher melting point T_m1 of the first wholly aromatic liquid crystalline polyester resin and the lower melting point T_m2 of the second wholly aromatic liquid crystalline polyester resin satisfy the following condition;

370°

C.≦

T_m1≦

440°

C.,

310°

C.≦

T_m2≦

380°

C., and

20°

C.≦

T_m1−

T_m2≦

80°

C.