ELECTROCHEMICAL CELL SYSTEM WITH SHUNT CURRENT INTERRUPT

• US 20120202127A1
• Filed: 01/31/2012
• Published: 08/09/2012
• Est. Priority Date: 02/04/2011
• Status: Active Grant

• Current Assignee: Form Energy, Inc.
• Original Assignee: Fluidic, Inc.
• Inventors: Friesen, Cody A., Krishnan, Ramkumar, Hayes, Joel R., Friesen, Grant, Mihalka, Michael John
• Granted Patent: US 9,105,910 B2
• Time in Patent Office: Days
• US Class Current: 429/406
• CPC Class Codes: B01F 23/23412 using liquid falling from orifices in a gaseous atmosphere, the orifices being exits from perforations, tubes or chimneys
• CPC Class Codes: B01F 23/237611 Air
• CPC Class Codes: H01M 10/4214 Arrangements for moving electrodes or electrolyte
• CPC Class Codes: H01M 12/065 with plate-like electrodes or stacks of plate-like electrodes
• CPC Class Codes: H01M 12/08 composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
• CPC Class Codes: H01M 2200/00 Safety devices for primary or secondary batteries
• CPC Class Codes: H01M 2300/0002 Aqueous electrolytes
• CPC Class Codes: H01M 2300/0005 Acid electrolytes
• CPC Class Codes: H01M 2300/0008 Phosphoric acid-based
• CPC Class Codes: H01M 2300/0011 Sulfuric acid-based
• CPC Class Codes: H01M 2300/0014 Alkaline electrolytes
• CPC Class Codes: H01M 50/70 Arrangements for stirring or circulating the electrolyte
• CPC Class Codes: H01M 50/77 with external circulating path
• CPC Class Codes: H01M 8/184 Regeneration by electrochemical means
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

An electrochemical cell system is configured to utilize an ionically conductive medium flowing through a plurality of electrochemical cells. One or more disperser chambers are provided to disrupt or minimize electrical current flowing between the electrochemical cells, such as between the cathode of one cell and the anode of a subsequent cell by dispersing the ionically conductive medium. Air is introduced into the disperser chamber to prevent the formation of foamed ionically conductive medium, which may reconnect the dispersed ionically conductive medium, allowing the current to again flow therethrough.

Claims

1. A dispersing system for an ionically conductive medium comprising:

a fluid inlet configured to receive the ionically conductive medium therethrough;

a disperser configured to separate the ionically conductive medium into a plurality of discrete droplets;

a chamber for receiving the plurality of discrete droplets, and collecting the plurality of discrete droplets to recombine into recombined ionically conductive medium;

a fluid outlet configured to provide an outlet for the recombined ionically conductive medium;

an air inlet communicated to the chamber; and

an air pump configured to pump an amount of air into the chamber through the air inlet.

2. The dispersing system of claim 1, wherein the air pump is configured to pump the amount of air sufficient to provide a positive pressure on the recombined ionically conductive medium in the chamber.

3. The dispersing system of claim 1, wherein the disperser comprises one or more openings of approximately 0.1-5 mm in diameter.

4. The dispersing system of claim 1, wherein the fluid inlet is configured to receive the ionically conductive medium at a rate of approximately 0.1-2 liters per minute.

5. The dispersing system of claim 1, wherein the air pump is configured to pump between approximately 1-100 ml of air per minute through the air inlet per liter per minute of ionically conductive medium.

6. The dispersing system of claim 1, wherein the air pump is configured to pump dry air through the air inlet.

7. The dispersing system of claim 6, wherein the introduction of the dry air reduces a humidity level inside the chamber by at least 10%.

8. The dispersing system of claim 1, wherein the air pump is configured to pump ambient air through the air inlet.

9. The dispersing system of claim 1, integrated into a housing for an electrochemical cell comprising:

(i) a fuel electrode comprising a metal fuel; and

(ii) an oxidant electrode spaced from the fuel electrode;

wherein the ionically conductive medium conducts ions between the fuel and oxidant electrodes to support electrochemical reactions at the fuel and oxidant electrodes.

10. An electrochemical cell system comprising:

one or more electrochemical cells, each comprising;

(i) a fuel electrode comprising a metal fuel; and

(ii) an oxidant electrode spaced from the fuel electrode;

an ionically conductive medium for conducting ions between the fuel and oxidant electrodes to support electrochemical reactions at the fuel and oxidant electrodes;

a circulation path for flowing the ionically conductive medium through and among the cells;

wherein the fuel electrode and the oxidant electrode are configured to, during discharge, oxidize the metal fuel at the fuel electrode and reduce an oxidant at the oxidant electrode to generate a discharge potential difference therebetween for application to a load; and

one or more dispersing systems positioned along the circulation path and configured to disrupt an electrical shunt current in the ionically conductive medium between at least two of the electrochemical cells, each dispersing system comprising;

(a) a disperser configured to separate the ionically conductive medium into a plurality of discrete droplets; and

(b) a chamber for receiving the plurality of discrete droplets, and collecting the plurality of discrete droplets to recombine into recombined ionically conductive medium;

wherein at least one of the one or more dispersing systems further comprises an air inlet configured to allow air into the chamber; and

an air pump configured to pump an amount of air into the chamber through the air inlet.

11. The electrochemical cell system of claim 10, wherein each electrochemical cell further comprises a charging electrode selected from the group consisting of (a) the oxidant electrode, (b) a separate charging electrode spaced from the fuel and oxidant electrodes, and (c) a portion of the fuel electrode.

12. The electrochemical cell system of claim 10, wherein the fuel electrode and the charging electrode are configured to, during re-charge, reduce a reducible species of the metal fuel to electrodeposit the metal fuel on the fuel electrode and oxidize an oxidizable species of the oxidant by application of a re-charge potential difference therebetween from a power source.

13. The electrochemical cell system of claim 12, wherein the fuel electrode comprises a series of permeable electrode bodies arranged in spaced apart relation;

wherein the spaced apart relation of the permeable electrode bodies enables the re-charge potential difference to be applied between the charging electrode and at least one of the permeable electrode bodies, with the charging electrode functioning as the anode and the at least one permeable electrode body functioning as the cathode, such that the reducible fuel species are reduced and electrodeposited as the metal fuel in oxidizable form on the at least one permeable electrode body, whereby the electrodeposition causes growth of the metal fuel among the permeable electrode bodies such that the electrodeposited metal fuel establishes an electrical connection between the permeable electrode bodies.

14. The electrochemical cell system of claim 11, wherein the reducible species of the metal fuel comprises ions of zinc, iron, aluminum, magnesium, or lithium, and wherein the metal fuel is zinc, iron, aluminum, magnesium, or lithium.

15. The electrochemical cell system of claim 10, wherein the ionically conductive medium comprises an aqueous electrolyte solution.

16. The electrochemical cell system of claim 15, wherein the aqueous electrolyte solution comprises sulfuric acid, phosphoric acid, triflic acid, nitric acid, potassium hydroxide, sodium hydroxide, sodium chloride, potassium nitrate, or lithium chloride.

17. The electrochemical cell system of claim 10, wherein the disperser system is contained within a housing for at least one of the one or more electrochemical cells.

18. The electrochemical cell system of claim 10, wherein the air pump is configured to pump the amount of air sufficient to provide a positive pressure on the recombined ionically conductive medium in the chamber.

19. A method for disrupting electrical current in an ionically conductive medium, the method comprising:

dispersing, in a chamber, the ionically conductive medium into a plurality of discrete droplets;

permitting, in the chamber, the plurality of discrete droplets to recombine into recombined ionically conductive medium;

adding an amount of air into the chamber to inhibit growth of ionically conductive foam on the recombined ionically conductive medium.

20. The method of claim 19, wherein dispersing the ionically conductive medium into a plurality of discrete droplets comprises passing the ionically conductive medium through a plurality of apertures.

21. The method of claim 19, wherein adding the amount of air into the chamber comprises pressurizing the chamber.

22. The method of claim 19, wherein adding the amount of air into the chamber comprises pumping the air into the chamber.

23. The method of claim 19, wherein the air is dry air configured to reduce a humidity level in the chamber.

24. The method of claim 19, wherein the amount of air includes ambient air.

25. A housing for one or more electrochemical cells, wherein each of the one or more electrochemical cells comprise:

(i) a fuel electrode comprising a metal fuel; and

(ii) an oxidant electrode spaced from the fuel electrode; and

wherein an ionically conductive medium conducts ions between the fuel and oxidant electrodes to support electrochemical reactions at the fuel and oxidant electrodes;

the housing comprising;

a circulation path for flowing the ionically conductive medium through the one or more electrochemical cells;

a first dispersion chamber positioned on the circulation path before the one or more electrochemical cells, and configured to disperse the ionically conductive medium before its flowing through the one or more electrochemical cells;

a second dispersion chamber positioned on the circulation path after the one or more electrochemical cells, and configured to disperse the ionically conductive medium after its flowing through the one or more electrochemical cells;

wherein each of the first dispersion chamber and the second dispersion chamber comprises;

(a) a disperser configured to separate the ionically conductive medium into a plurality of discrete droplets; and

(b) a lower portion for receiving the plurality of discrete droplets, and collecting the plurality of discrete droplets to recombine into recombined ionically conductive medium.

26. The housing of claim 25, further comprising an air inlet configured to selectively permit the addition of air into the lower portion of the first dispersion chamber.

27. The housing of claim 25, further comprising one or more removable sidewalls which, when sealed to the housing, contain the ionically conductive medium to the circulation path.

28. The housing of claim 27, wherein the one or more removable sidewalls are configured to hold the oxidant electrode.