HOLLOW-FIBER MEMBRANE CONTACTORS

• US 20120247327A1
• Filed: 09/26/2011
• Published: 10/04/2012
• Est. Priority Date: 09/27/2010
• Status: Abandoned Application

• Current Assignee: Phillips 66 Company
• Original Assignee: Conocophillips Company (ConocoPhillips)
• Inventors: Omole, Imona C.
• Application Number:
  US13/245,428
• Publication Number:
  US 20120247327A1
• Time in Patent Office: Days
• US Class Current: 95/51
• CPC Class Codes: B01D 2252/204 Amines
• CPC Class Codes: B01D 2252/30 Ionic liquids and zwitter-ions
• CPC Class Codes: B01D 2257/304 Hydrogen sulfide
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2258/0283 Flue gases
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1462 Removing mixtures of hydrogen sulfide and carbon dioxide
• CPC Class Codes: B01D 53/228 characterised by specific membranes
• CPC Class Codes: B01D 53/229 Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
• CPC Class Codes: B01D 61/246 Membrane extraction
• CPC Class Codes: B01D 69/08 Hollow fibre membranes manufacture of hollow fibres D01D5/24, D01F1/08
• CPC Class Codes: B01D 71/32 containing fluorine atoms
• CPC Class Codes: B01D 71/34 Polyvinylidene fluoride
• CPC Class Codes: B01D 71/76 Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74 rubbers in general B01D71/24
• CPC Class Codes: F23J 15/02 of purifiers, e.g. for removing noxious material traps for solid residues F23J3/04
• CPC Class Codes: F23J 2215/20 Sulfur; Compounds thereof
• CPC Class Codes: F23J 2215/50 Carbon dioxide
• CPC Class Codes: F23J 2219/40 Sorption with wet devices, e.g. scrubbers
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02E 20/32 Direct CO2 mitigation

Abstract

Methods and apparatus relate to recovery of carbon dioxide and/or hydrogen sulfide from a gas mixture. Separating of the carbon dioxide, for example, from the gas mixture utilizes a liquid sorbent for the carbon dioxide. The liquid sorbent contacts the gas mixture along asymmetric hollow-fiber membranes that enable transfer of the carbon dioxide from the gas mixture to the liquid sorbent.

Claims

1. A method, comprising:

passing a gas containing at least one of carbon dioxide and hydrogen sulfide through a contactor; and

passing a liquid sorbent for at least one of the carbon dioxide and the hydrogen sulfide through the contactor such that contacting of the gas and the liquid sorbent to treat the gas occurs across a membrane that has an asymmetric structure and forms walls of a hollow-fiber disposed within the contactor.

2. The method according to claim 1, wherein the membrane is made of a polymer able to be dissolved in a spinning solvent and compatible with the liquid sorbent.

3. The method according to claim 1, wherein the membrane is made by spinning a mixture of polymer and a spinning solvent and an non-solvent for the polymer to facilitate forming of the asymmetric structure on either side of the membrane for control of mass transfer through the membrane and wetting of the membrane by the liquid sorbent.

4. The method according to claim 1, wherein the membrane is made by spinning a mixture of polymer, solvent for the polymer and an additive that is more volatile than the solvent to facilitate forming of the asymmetric structure for control of mass transfer through the membrane and wetting of the membrane by the liquid sorbent.

5. The method according to claim 1, wherein the membrane is made by spinning a mixture of polymer, solvent for the polymer and between 1 and 15 weight percent of an additive that is more volatile than the solvent to facilitate forming of the asymmetric structure for control of mass transfer through the membrane and wetting of the membrane by the liquid sorbent.

6. The method according to claim 1, wherein the membrane is made by spinning a mixture of polymer, solvent for the polymer and an additive that is different than the solvent and selected from acetone, tetrahydrofuran and ethanol to facilitate forming of the asymmetric structure for control of mass transfer through the membrane and wetting of the membrane by the liquid sorbent.

7. The method according to claim 1, wherein the membrane is made by spinning a mixture of polymer, solvent for the polymer and an additive that has a boiling point below 100°

C. to facilitate forming of the asymmetric structure for control of mass transfer through the membrane and wetting of the membrane by the liquid sorbent.

8. The method according to claim 1, wherein the membrane is made from a mixture of polymer, solvent for the polymer and an additive that results in selective reduction in porosity on one side of the membrane relative to an opposite side of the membrane.

9. The method according to claim 1, wherein the membrane is made of a polymer that includes polyvinylidene fluoride (PVDF).

10. The method according to claim 1, wherein the membrane is made of a sulfone-based aromatic polymer.

11. The method according to claim 1, wherein the gas passes through an interior bore and/or exterior of the membrane defining a first flow path separate from a second flow path along an exterior of the membrane and/or an interior bore and through which the liquid sorbent passes.

12. The method according to claim 1, further comprising passing the liquid sorbent into contact with steam along a membrane interface after the liquid sorbent is contacted with the gas containing the carbon dioxide, wherein the carbon dioxide transferred to the liquid sorbent during contact with the gas desorbs from the liquid sorbent and transfers to the steam for recovery.

13. The method according to claim 1, wherein the liquid sorbent is an aqueous amine.

14. The method according to claim 1, wherein the liquid sorbent is an aqueous amine and the membrane is made of a polyvinylidene fluoride (PVDF) and hexafluoropropylene (HFP) copolymer.

15. A method, comprising:

transferring carbon dioxide from a gas mixture to a liquid sorbent through a first asymmetric hollow-fiber membrane;

transferring the carbon dioxide from the liquid sorbent to steam through a second asymmetric hollow-fiber membrane; and

condensing the steam to separate the carbon dioxide transferred to the steam.

16. The method according to claim 15, wherein formation of the first and second membranes is from a mixture of polymer, solvent for the polymer and an additive that is more volatile than the solvent to facilitate asymmetrical forming of the membrane for control of mass transfer through the membrane and liquid wetting of the membrane.

17. The method according to claim 15, wherein the first and second membranes are made of a polyvinylidene fluoride (PVDF) and hexafluoropropylene (HFP) copolymer.

18. A method, comprising:

forming a polyvinylidene fluoride (PVDF) and hexafluoropropylene (HFP) copolymer asymmetric hollow-fiber membrane;

disposing the membrane in a contactor system with an interior bore of the membrane defining a first flow path through a sorption unit separate from a second flow path along an exterior of the membrane through the sorption unit;

passing a gas containing carbon dioxide through the sorption unit along the first flow path; and

passing a liquid sorbent for the carbon dioxide through the sorption unit along the second flow path, wherein the carbon dioxide is transferred from the first flow path to the liquid sorbent in the second flow path at a contact interface across the membrane.

19. The method according to claim 18, wherein porosity of the membrane increases from the interior bore of the membrane toward the exterior of the membrane.

20. The method according to claim 18, wherein the forming of the membrane includes modifying asymmetrical forming of the membrane in order to control mass transfer through the membrane and liquid wetting of the membrane.

21. The method according to claim 18, further comprising:

passing the liquid sorbent through a third flow path along the exterior of the membrane within a desorption unit of the contactor system; and

passing steam through a fourth flow path defined by the interior bore of the membrane within the desorption unit, wherein the steam and liquid sorbent contact across the membrane and the carbon dioxide transferred to the liquid sorbent desorbs from the liquid sorbent and transfers to the steam for recovery of the carbon dioxide.