ELECTRICAL TRACKING RESISTANCE COMPOSITIONS, METHODS & ARTICLES OF MANUFACTURE
First Claim
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1. A composition comprising:
- a polycarbonate that is not a polysiloxane block co-polycarbonate;
a polysiloxane block co-polycarbonate;
a transition metal oxide;
a brominated organic flame retardant or a halogen organic flame retardant compound;
optionally 0 to 3 wt % of a fluorinated polyolefin;
optionally an additive that imparts a desired performance property; and
optionally a carbon black containing material, wherein the composition has a notched izod impact at −
30°
C. of at least 35 kJ/m2 at a thickness of 3.0 mm according to ISO-180 standard with a 5.5J hammer and wherein the composition has a p(FTP) V0 flammability rating of at least 0.85 at 0.8 mm, 1.0 mm, and 1.5 mm according to the method of UL 94, and further wherein the composition does not show tracking through at least 50 drops of a 0.1% aqueous ammonium chloride solution at 250V according to ASTM D-3638.
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Abstract
This disclosure relates to polycarbonate compositions, methods, and articles of manufacture that at least meets certain electrical tracking resistance requirements. The compositions, methods, and articles of manufacture that meet these requirements contain at least a polycarbonate; a polysiloxane block co-polycarbonate; and a transition metal oxide, e.g. titanium dioxide.
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Citations
40 Claims
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1. A composition comprising:
- a polycarbonate that is not a polysiloxane block co-polycarbonate;
a polysiloxane block co-polycarbonate;
a transition metal oxide;
a brominated organic flame retardant or a halogen organic flame retardant compound;
optionally 0 to 3 wt % of a fluorinated polyolefin;
optionally an additive that imparts a desired performance property; and
optionally a carbon black containing material, wherein the composition has a notched izod impact at −
30°
C. of at least 35 kJ/m2 at a thickness of 3.0 mm according to ISO-180 standard with a 5.5J hammer and wherein the composition has a p(FTP) V0 flammability rating of at least 0.85 at 0.8 mm, 1.0 mm, and 1.5 mm according to the method of UL 94, and further wherein the composition does not show tracking through at least 50 drops of a 0.1% aqueous ammonium chloride solution at 250V according to ASTM D-3638. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 27, 28, 29, 30, 31, 32, 33, 34, 35, 38, 39, 40)
- a polycarbonate that is not a polysiloxane block co-polycarbonate;
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15. A composition comprising:
- a polycarbonate that is a not a polysiloxane block-co-polycarbonate;
5 to 45 wt % of a polysiloxane block co-polycarbonate;
3 to 40 wt % of a transitional metal oxide;
1 to 10 wt % of bromine atoms from a brominated organic flame retardant;
optionally 0 to 1 wt % of a fluorinated polyolefin;
optionally an additive that imparts a desired performance property; and
optionally a carbon black containing material, wherein the composition has a notched izod impact at −
30°
C. of at least 35 kJ/m2 at a thickness of 3.0 mm according to ISO-180 standard with a 5.5J hammer and wherein the composition has a p(FTP) V0 flammability rating if at least 0.85 0.8 mm, 1.0 mm, and 1.5 mm according to the method of UL 94, and further wherein the composition does not show tracking through at least 50 drops of a 0.1% aqueous ammonioum chloride solution at 250V according to ASTM D-3638. - View Dependent Claims (16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 36, 37)
- a polycarbonate that is a not a polysiloxane block-co-polycarbonate;
Specification