COEXTRUSION DIE AND SYSTEM, METHOD OF MAKING COEXTRUDED ARTICLES AND COEXTRUDED ARTICLES MADE THEREBY

• US 20120263906A1
• Filed: 12/15/2010
• Published: 10/18/2012
• Est. Priority Date: 12/29/2009
• Status: Abandoned Application

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Ausen, Ronald W., Kopecky, William J., Fleming, Danny L., Yarusso, David J., Emslander, Jeffrey O., Jonza, James M., Batch, Gibson L.
• Application Number:
  US13/518,187
• Publication Number:
  US 20120263906A1
• Time in Patent Office: Days
• US Class Current: 428/41.8
• CPC Class Codes: B29C 48/0018 combined with shaping by orienting, stretching or shrinking, e.g. film blowing B29C48/0017 takes precedence
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/21 the layers being joined at their surfaces
• CPC Class Codes: B29C 48/22 with means connecting the layers, e.g. tie layers or undercuts
• CPC Class Codes: B29C 48/23 with means for avoiding adhesion of the layers, e.g. for forming peelable layers
• CPC Class Codes: B29C 48/305 having a wide opening, e.g. for forming sheets
• CPC Class Codes: B29C 48/307 specially adapted for bringing together components, e.g. melts within the die
• CPC Class Codes: B29C 48/495 Feed-blocks extrusion moulding of multi-component articles B29C48/16
• CPC Class Codes: B29C 48/914 cooling drums
• CPC Class Codes: B29C 48/919 using a bath, e.g. extruding into an open bath to coagulate or cool the material
• CPC Class Codes: B29K 2909/02 Ceramics
• CPC Class Codes: B29L 2007/008 Wide strips, e.g. films, webs
• CPC Class Codes: C09J 2433/00 Presence of (meth)acrylic polymer
• CPC Class Codes: C09J 2453/00 Presence of block copolymer
• CPC Class Codes: C09J 7/38 Pressure-sensitive adhesives [PSA]
• CPC Class Codes: C09J 7/40 characterised by release liners
• CPC Class Codes: Y10T 428/1476 Release layer
• CPC Class Codes: Y10T 428/28 Web or sheet containing structurally defined element or component and having an adhesive outermost layer

Abstract

An extrusion die (20) and method for co-extruding a first molten polymeric material and a second molten polymeric material. The die includes a first die portion (20), a second die portion and a shim separating the first die portion and the second die portion. The shim has a first side and a second side, the first side of the shim forming a boundary of the first die portion and defining a first die cavity (38), the second side of the shim forming a boundary of the second die portion and defining a second die cavity (40). A dispensing edge (36) is provided having a plurality of first and second extrusion openings, a plurality of first feed channels connecting the first die cavity to the first extrusion openings along the dispensing edge, and a plurality of second feed channels connecting the second die cavity to the second extrusion openings along the dispensing edge. The first and second extrusion openings arranged along the dispensing edge to provide an interfacial zone having portions of the first extrusion openings disposed between portions of the second extrusion openings. The die is used in an extrusion system and a method for making a multilayered article.

Claims

1. An extrusion die for co-extruding a first molten polymeric material and a second molten polymeric material, the die comprising:

a first die portion;

a second die portion; and

a shim separating the first die portion and the second die portion, the shim having a first side and a second side, the first side of the shim forming a boundary of the first die portion and defining a first die cavity, the second side of the shim forming a boundary of the second die portion and defining a second die cavity, a dispensing edge comprising a plurality of first and second extrusion openings, a plurality of first feed channels connecting the first die cavity to the first extrusion openings along the dispensing edge, and a plurality of second feed channels connecting the second die cavity to the second extrusion openings along the dispensing edge, the first and second extrusion openings arranged along the dispensing edge to provide;

(a) an interfacial zone comprising portions of first extrusion openings disposed between portions of second extrusion openings,

(b) a first continuous zone comprising portions of the first extrusion openings arranged in side-by-side relation to each other, and

(c) a second continuous zone comprising portions of the second extrusion openings arranged in side-by-side relation to each other,

wherein, the interfacial zone is disposed between the first continuous zone and the second continuous zone.

2. The die according to claim 1, wherein the shim comprises a metallic material.

3. The die according to claim 1, wherein the shim comprises a ceramic material.

5. The die according to claim 1, wherein the interfacial zone along the dispensing edge is configured to provide an extrudate comprised of a structured interface or a microstructured interface between the first and second molten polymeric materials.

6. An extrusion system for the manufacture of a multilayered film, comprising:

the extrusion die according to claim 1;

a source of first molten polymeric material connected to the extrusion die to feed the first molten polymeric material into the first die cavity;

a source of second molten polymeric material connected to the extrusion die to feed the second molten polymeric material into the second die cavity; and

cooling apparatus positioned to receive a multilayered molten sheet from the extrusion die, the multilayered molten sheet comprising the first and second molten polymeric materials, the cooling apparatus being at a temperature sufficient to at least partially solidify the multilayered molten sheet.

7. The extrusion system according to claim 6 wherein the source of first molten polymeric material is a first extruder and the source of second molten polymeric material is a second extruder, the first and second extruders being selected from single screw extruders and twin screw extruders.

8. The extrusion system according to claim 6 wherein the cooling apparatus comprises a chill roll.

9. The extrusion system according to claim 6 wherein the cooling apparatus comprises a series of cooling rolls.

10. The extrusion system according to claim 6 wherein the cooling apparatus comprises a water bath.

11. A method of producing an extruded article, the method comprising:

providing an extrusion system according to claim 1;

feeding the first molten polymeric material from the source of first molten polymeric material into the first die cavity and through the plurality of first extrusion channels, the first molten polymeric material comprising a layer of pressure sensitive adhesive material having first and second major surfaces;

extruding the second molten polymeric material from the source of second molten polymeric material through the second die cavity and through the second extrusion channels, the second molten polymeric material comprising a polymer release material having first and second major surfaces;

the pressure sensitive adhesive material and the polymer release material exiting the extrusion die through the first and second extrusion openings along the dispensing edge of the die to provide a multilayered extrudate wherein the first major surface of the pressure sensitive adhesive overlays the first major surface of the polymer release material, the multilayered extrudate having a structured interface between the pressure sensitive adhesive and the polymer release material; and

cooling the multilayered extrudate to provide the extruded article in the form of a pressure sensitive adhesive layer having a release liner removably affixed to the adhesive layer.

12. The method according to claim 11 further comprising adding a support layer to the second major surface of the pressure sensitive adhesive material.

13. The method according to claim 1 further comprising adding a support layer to the second major surface of the polymer release material.

14. The method according to claim 1, wherein cooling the multilayered extrudate comprises contacting the extrudate on a chill roll.

15. The method according to claim 1, wherein cooling the multilayered extrudate comprises contacting the extrudate on a series of cooling rolls.

16. The method according to claim 1, wherein cooling the multilayered extrudate comprises contacting the extrudate with a water bath.

17. The method according to claim 1, wherein the pressure sensitive adhesive is selected from the group consisting of acrylate, block copolymer, silicone and combinations thereof.

18. The method according to claim 17 wherein the block copolymer is a styrene-isoprene block copolymer.

19. The method according to claim 17 wherein the acrylate is the reaction product of acrylic acid and one or both of 2-ethylhexyl acrylate and isooctylacrylate.

20. The method according to claim 1, wherein the polymer release material is selected from the group consisting of polyolefin homo and copolymers, fluoropolymers, silicone polymers and combinations of two or more of the foregoing.

21. The method according to claim 20, wherein the polyolefin is selected from high density polyethylene, low density polyethylene, ultra-low density polyethylene and combinations thereof.

22. The method according to claim 20, wherein the polyolefin is selected from random or block copolymers of ethylene/propylene, ethylene/butene, ethylene/hexene, or ethylene/octene and combinations thereof.

23. An adhesive article made according to the method of claim 1.

4. (canceled)

24. An adhesive article, comprising:

an extruded pressure sensitive adhesive material layer having a first major surface and a second major surface, the second major surface having a microstructure provided by an extrusion die; and

an extruded release liner comprising a polymeric material layer having a first major surface and a second major surface, the first major surface of the release liner being releasably affixed to the second major surface of the pressure sensitive adhesive material and the first major surface of the release liner having a microstructure complimentary to the microstructure of the second major surface of the pressure sensitive adhesive material layer;

wherein, the microstructure on the first major surface of the extruded release liner will retain its microstructure when heated to the melting temperature of the first polymeric material.

25-32. -32. (canceled)