COMPOSITE ARMOR AND METHOD FOR MAKING COMPOSITE ARMOR

• US 20120291621A1
• Filed: 12/07/2010
• Published: 11/22/2012
• Est. Priority Date: 01/29/2010
• Status: Abandoned Application

• Current Assignee: Battelle Memorial Institute
• Original Assignee: Battelle Memorial Institute
• Inventors: Sayre, Jay, Valentine, Kary, Tuten, Jim
• Application Number:
  US13/522,587
• Publication Number:
  US 20120291621A1
• Time in Patent Office: Days
• US Class Current: 89/36.02
• CPC Class Codes: F41H 5/0421 Ceramic layers in combination with metal layers
• CPC Class Codes: F41H 5/0428 Ceramic layers in combination with additional layers made of fibres, fabrics or plastics

Abstract

A composite armor panel and a method for making the armor is disclosed. In one embodiment the armor consists of a plurality of ceramic tiles (21) individually edge-wrapped with fiber or edge-wrap fabric (52), which are further wrapped with a face-wrap fabric (53A,53B), and encapsulated in a hyperelastic polymer material (31) permeating the fabric and fibers, with a front plate (42) and back plate (41) adhered to the encapsulated tiles. In one embodiment the hyperelastic polymer is formed from a MDI-polyester or polyether prepolymer, at lease one long-chain polyester polyol comprising ethylene/butylene adipate diol, at least one short-chain diol comprising 1,4-butanediol, and a tin-based catalyst.

Claims

1. A composite armor panel comprising, one or more ceramic tiles having tile faces and tile edges, a layer of a permeable medium substantially covering the ceramic tile faces and a hyperelastic polymer permeating the permeable medium, bonded to the tile faces and substantially encapsulating the tiles;

wherein the hyperelastic polymer adheres the one or more ceramic tiles to a back plate on one side of the tiles, and a front plate on the opposite side of the one or more ceramic tiles.

2. The composite armor panel of claim 1, wherein more than one ceramic tiles are arrayed along a common surface.

3. The composite armor panel of claim 1, wherein the ceramic tiles are arrayed in a polygonal configuration.

4. The composite armor panel of claim 1, wherein the shape of the ceramic tiles is rectangular or hexagonal.

5. The composite armor panel of claim 1, wherein the ceramic tile edges are substantially covered by a layer of a permeable medium.

6. The composite armor panel of claim 1, wherein the ceramic tiles are selected from aluminum oxide, silicon carbide, aluminum nitride, and boron carbide, barium titanate, strotium titanate, calcium zirconate, magnesium zirconate, titanium diboride, silicon nitride, tungsten carbide, and metal-ceramic composites.

7. The composite armor panel of claim 1, wherein the permeable medium is an organic polymer.

8. The composite armor panel of claim 7, wherein the permeable medium is selected from aramid, carbon, polyamide, polybenzamidazole, liquid crystal, polyester, main chain aromatic polyester, main chain aromatic polyesteramide, polyolefin, ultra-high molecular weight polyolefin, poly(p-phenylene-2,6-benzobisoxazole), and poly(pyridobisimidazole).

9. The composite armor panel of claim 7, wherein the permeable medium is a liquid crystal polyester-polyarylate.

10. The composite armor panel of claim 1, wherein the permeable medium is inorganic.

11. The composite armor panel of claim 10, wherein the permeable medium is selected from alumina, aluminum, magnesium, titanium, basalt, boron, glass, ceramic, quartz, silicon carbide, and steel.

12. The composite armor panel of claim 1, wherein the hyperelastic polymer is a polyurethane.

13. The composite armor panel of claim 12, wherein the hyperelastic polymer is formed from a mixture of an MDI-polyester or polyether prepolymer, at lease one long-chain polyester or polyether polyol, at least one short-chain diol, and a catalyst.

14. The composite armor panel of claim 12, wherein the hyperelastic polymer is formed from a mixture of an MDI-polyester or polyether prepolymer, at lease one long-chain polyester polyol comprising ethylene/butylene adipate diol, at least one short-chain diol comprising 1,4-butanediol, and a catalyst.

15. The composite armor panel of claim 13, wherein the hyperelastic polymer is formed from a mixture of an MDI-polyester or polyether prepolymer having a free isocyanate content of about 5-25%,

at least one long-chain polyester polyol comprising ethylene/butylene adipate diol with an OH# of about 25-115,

at least one short-chain diol comprising 1,4-butanediol that accounts for about 10-20% by weight of the total hydroxyl-containing components of the mixture, and

at least one catalyst comprised of a tertiary amine catalyst and a tin-based catalyst in a ratio of about 1:

1 to 10;

1, wherein the total catalyst loading is about 0.02-0.03% by weight,

the reactive components are combined in a proportion that provides about 5% excess of isocyanate groups in the total mixture.

16. The composite armor panel of claim 13, wherein the hyperelastic polymer is formed from a mixture of an MDI-polyester or polyether prepolymer having a free isocyanate content of about 19%,

at least one long-chain polyester polyol comprising ethylene/butylene adipate diol with an OH# of about 56,

at least one short-chain diol comprising 1,4-butanediol that accounts for about 18% by weight of the total hydroxyl-containing components of the mixture, and

at least one catalyst comprised of a tertiary amine catalyst and a tin-based catalyst in a ratio of about 4:

1, wherein the total catalyst loading is about 0.026% by weight,

the reactive components are combined in a proportion that provides about 5% excess of isocyanate groups in the total mixture.

17. The composite armor panel of claim 14, wherein the hyperelastic polymer behaves in a hyperelastic manner at strain rates up to about 10⁴ s⁻

1.

18. The composite armor panel of claim 1, wherein the hyperelastic polymer comprises at least one energy absorbing material that has an elongation at break ranging greater than about 400%.

19. The composite armor panel of claim 1, wherein the hyperelastic polymer comprises at least one energy absorbing material that has at least the properties of:

a Shore A hardness value of at least about 90, elongation at break ranging from about 500 to about 700%, and Young'"'"'s modulus ranging from about 4000 to about 6000 psi; and

at least withstands;

strain rates of up to at least about 10⁴ s<sup>−

1</sup>, and tensile stresses ranging from at least about 4000 to at least about 7000 psi.

20. The composite armor panel of claim 1, wherein the hyperelastic polymer comprises an energy absorbing material that behaves in a rate-independent hyperelastic manner wherein its permanent set is minimized so that the energy absorbing material maintains consistent force-displacement characteristics over a wide range of impact velocities while remaining fully recoverable.

21. The composite armor panel of claim 1, wherein the front plate comprises a metal or metal alloy.

22. The composite armor panel of claim 1, wherein the front plate is aluminum.

23. The composite armor panel of claim 1, wherein the back plate comprises a metal or metal alloy.

24. The composite armor panel of claim 1, wherein the back plate is aluminum.

25. The composite armor panel of claim 1, wherein the back plate behaves in a ductile manner at strain rates up to about 10⁴ s⁻

1.

26. The composite armor panel of claim 1, wherein the back plate is reinforced with permeable medium.

27. The composite armor panel of claim 1, wherein the thickness of the hyperelastic polymer between the back plate and the ceramic tiles is less than 2 mm in thickness.

28. The composite armor panel of claim 1, wherein the hyperelastic polymer comprises an energy absorbing material that behaves in a rate-independent hyperelastic manner wherein its permanent set is minimized so that the energy absorbing material maintains consistent force-displacement characteristics over a wide range of impact velocities while remaining fully recoverable.

29. A method of making a composite armor panel comprising, substantially covering one or more ceramic tiles with a layer of a permeable medium, and substantially encapsulating the tiles and permeable medium in a hyperelastic polymer which permeates the permeable medium and bonds to the ceramic tiles;

wherein the hyperelastic polymer adheres the one or more ceramic tiles to a back plate on one side of the tiles, and a front plate on the opposite side of the one or more ceramic tiles.

30. The method of making a composite armor panel of claim 29, wherein the hyperelastic polymer is a polyurethane

31. The method of making a composite armor panel of claim 29, wherein the hyperelastic polymer is formed from a mixture of an MDI-polyester or polyether prepolymer, at lease one long-chain polyester or polyether polyol, at least one short-chain diol, and a catalyst.

32. A method of making a composite armor panel comprising:

(A) providing an array of ceramic tiles having substantially parallel tile faces,

(B) substantially covering the faces of the ceramic tiles with a layer of a permeable medium,

(C) applying a back plate to one side of the ceramic tile faces in contact with at least a portion of the permeable medium,

(C) infiltrating the permeable medium with a liquid polymer so as to substantially encapsulate the ceramic tile and the back plate,

(D) applying a front plate to the ceramic tiles on the side opposite the back plate,

(E) curing the liquid polymer into a hyperelastic, energy-absorbing material and bonding it to the ceramic tiles and the backing plate,

wherein the liquid polymer and the curing are chosen such that the hyperelastic, energy-absorbing material behaves in a rate-independent hyperelastic manner wherein its permanent set is minimized and so that the energy-absorbing material maintains consistent force-displacement characteristics over a wide range of impact velocities while remaining fully recoverable.

33. A method for specifying the materials for the front and back faces that comprises selection criteria for balancing the strains on the internal components when the panels are made according to claim 32 so that the panels remain flat.

34. A method for manufacture of the panels that comprise procedures for controlling the process parameters in claim 32 so that the resultant armor panel has internal compressive stresses that enhance its ballistic performance.