CARBON NANOTUBE SHEET AND PROCESS FOR PRODUCTION THEREOF

• US 20120315459A1
• Filed: 02/15/2011
• Published: 12/13/2012
• Est. Priority Date: 02/15/2010
• Status: Abandoned Application

• Current Assignee: Taiyo Nippon Sanso Corporation (Mitsubishi Chemical Group Corp.), National University Corporation Hokkaido University
• Original Assignee: Taiyo Nippon Sanso Corporation (Mitsubishi Chemical Group Corp.), National University Corporation Hokkaido University
• Inventors: Fugetsu, Bunshi, Yajima, Takeru, Abe, Toshiyuki, Sakai, Toru
• Application Number:
  US13/578,879
• Publication Number:
  US 20120315459A1
• Time in Patent Office: Days
• US Class Current: 428/299.1
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: B82Y 40/00 Manufacture or treatment of nanostructures
• CPC Class Codes: C01B 2202/08 Aligned nanotubes
• CPC Class Codes: C01B 32/15 Nano-sized carbon materials
• CPC Class Codes: C01B 32/16 Preparation
• CPC Class Codes: Y10T 428/249945 Carbon or carbonaceous fiber

Abstract

A carbon nanotube sheet of the present invention includes carbon nanotubes and a polymeric material, wherein the carbon nanotubes are present in an isolated state, the axis directions of the carbon nanotubes are aligned m a thickness direction of the carbon nanotube sheet, and the space between the carbon nanotubes is filled with the polymeric material.

Claims

1. A carbon nanotube sheet comprising carbon nanotubes and a polymeric material, wherein

the carbon nanotubes are present in an isolated state,

the axis directions of the carbon nanotubes are aligned in a thickness direction of the carbon nanotube sheet, and

the space between the carbon nanotubes is filled with the polymeric material.

2. The carbon nanotube sheet according to claim 1, wherein the end of the carbon nanotube protrudes from a front surface and/or a rear surface of the carbon nanotube sheet.

3. The carbon nanotube sheet according to claim 1, wherein the end of the carbon nanotube is embedded in the polymeric material, and the carbon nanotube does not protrude from any of front and rear surfaces of the carbon nanotube sheet.

4. The carbon nanotube sheet according to claim 1, wherein the occupancy of a carbon nanotube in a plane direction of the carbon nanotube sheet is 0.001% or more.

5. The carbon nanotube sheet according to claim 1, wherein a ratio ρ

_l/ρ

_t of volume resistivity (ρ

_l) in a thickness direction to volume resistivity (ρ

_t) in a plane direction of the carbon nanotube sheet is 50 or more.

6. The carbon nanotube sheet according to claim 1, wherein the carbon nanotube has a length of 10 μ

m or more.

7. The carbon nanotube sheet according to claim 6, wherein the thickness of the polymeric material filled accounts for 0.5% to 150% of the length of the carbon nanotube.

8. A method for producing a carbon nanotube sheet, which comprises:

immersing an aligned carbon nanotube base material including a substrate, and the group of carbon nanotubes in which a plurality of carbon nanotubes are vertically aligned in the form of a bundle to the substrate, in an amphiphilic molecule-containing solution;

drying the immersed aligned carhop nanotube base material;

impregnating the dried aligned carbon nanotube base material with a monomer;

polymerizing the monomer thereby to form a carbon nanotube sheet, in which the space between carbon nanotubes is filled with the polymer, on the substrate; and

peeling the carbon nanotube sheet from the substrate.

10. The method for producing a carbon nanotube sheet according to claim 8, wherein the amphiphilic molecule is selected from the group consisting of a polymer of 2-methacryloyloxyethylphosphorylcholine, polypeptides, 3-(N,N-dimethylstearylammonio)propane sulfonate, 3-(N,N-dimethylmyristylammonmio)propane sulfonate, 3-[(3-cholamidepropyl)dimethylammonio]-1-propane sulfonate (CHAPS), 3-[(3-cholamidepropyl)dimethylammonio]-2-hydroxypropane sulfonate (CHAPSO), n-dodecyl-N,N′

-dimethyl-3-ammonio-1-propane sulfonate, n-hexadecyl-N,N′

-dimethyl-3-ammonio-1-propane sulfonate, n-octylphosphocholine, n-dodecylphosphocholine, n-tetradecylphosphocholine, n-hexadecylphosphocholine, dimethylalkylbetaine, perfluoroalkylbetaine and lecithin.

11. The method for producing a carbon nanotube sheet according to claim 8, wherein the occupancy of vertically aligned carbon nanotubes in a plane direction of the aligned carbon nanotube base material is 0.001% or more.

9. A method for producing a carbon nanotube sheet, which comprises:

immersing an aligned carbon, nanotube base material including a substrate, and the group of carbon nanotubes in which a plurality of carbon nanotubes are vertically aligned in the form of a bundle to the substrate, in an amphiphilic molecule-containing solution;

washing the aligned carbon nanotube base material with a washing solvent;

impregnating the aligned carbon nanotube base material, which is made to be present in a vertically downward state, with a monomer;

polymerizing the monomer thereby to form a carbon nanotube sheet on the substrate; and

peeling the carbon nanotube sheet from the substrate;

wherein

the aligned carbon nanotube base material is prevented from drying in a range from immersion in the amphiphilic molecule-containing solution to impregnation with the monomer.